Hydrothermal synthesis of titanosilicate ETS-10 using Ti(SO 4) 2
The ternary reaction composition diagram in the SiO 2–Na 2O–TiO 2–KF–H 2SO 4–H 2O system was developed for static ETS-10 synthesis at 473 K utilizing Ti(SO 4) 2 and N-brand sodium silicate solutions as sources of Ti and Si, respectively. For KF/TiO 2 = 1.5 and H 2O/TiO 2 = 300, pure, crystalline (⩾9...
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Published in | Microporous and mesoporous materials Vol. 81; no. 1; pp. 1 - 10 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
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Amsterdam
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06.06.2005
Elsevier |
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Abstract | The ternary reaction composition diagram in the SiO
2–Na
2O–TiO
2–KF–H
2SO
4–H
2O system was developed for static ETS-10 synthesis at 473
K utilizing Ti(SO
4)
2 and N-brand sodium silicate solutions as sources of Ti and Si, respectively. For KF/TiO
2
=
1.5 and H
2O/TiO
2
=
300, pure, crystalline (⩾95%) ETS-10 products were obtained in a narrow reaction composition zone (Na
2O/SiO
2
=
0.790–0.825, SiO
2/TiO
2
=
5.30–5.90, initial pH
=
10.22–10.95). The presence of islands and terraces with heights of ∼1.2–1.7
nm suggests a layer growth mechanism via two-dimensional surface nucleation. The aspect ratio
R
=
c/
a of typical ETS-10 crystals (
c is the axial length of the bi-pyramid and
a is the linear dimension of the square basal plane shared by the two pyramids) and the roughness of crystal pyramidal side surface decreased with increasing initial synthesis mixture pH. The Si/Ti ratios in the ETS-10 products were close to the theoretical value of 5. The crystallization curves for this pure ETS-10 showed that the induction time decreased substantially from 36 to 19
h, whereas crystallization rate increased only slightly from 19% to 27% h
−1 upon increasing initial pH. Increasing dilution of the initial synthesis mixture with water (5.50SiO
2:4.46Na
2O:1.00TiO
2:1.5KF:3.35H
2SO
4:450–750H
2O) resulted in progressively longer crystallizations, producing bi-pyramidal crystals of monotonically increasing dimensions. The results of experiments using NaF instead of either KF or KOH (i.e., conducted without K
+ and F
+) suggested that in unseeded, organic-free ETS-10 syntheses, K
+ was necessary for the nucleation of ETS-10, while F
− was not. |
---|---|
AbstractList | The ternary reaction composition diagram in the SiO
2–Na
2O–TiO
2–KF–H
2SO
4–H
2O system was developed for static ETS-10 synthesis at 473
K utilizing Ti(SO
4)
2 and N-brand sodium silicate solutions as sources of Ti and Si, respectively. For KF/TiO
2
=
1.5 and H
2O/TiO
2
=
300, pure, crystalline (⩾95%) ETS-10 products were obtained in a narrow reaction composition zone (Na
2O/SiO
2
=
0.790–0.825, SiO
2/TiO
2
=
5.30–5.90, initial pH
=
10.22–10.95). The presence of islands and terraces with heights of ∼1.2–1.7
nm suggests a layer growth mechanism via two-dimensional surface nucleation. The aspect ratio
R
=
c/
a of typical ETS-10 crystals (
c is the axial length of the bi-pyramid and
a is the linear dimension of the square basal plane shared by the two pyramids) and the roughness of crystal pyramidal side surface decreased with increasing initial synthesis mixture pH. The Si/Ti ratios in the ETS-10 products were close to the theoretical value of 5. The crystallization curves for this pure ETS-10 showed that the induction time decreased substantially from 36 to 19
h, whereas crystallization rate increased only slightly from 19% to 27% h
−1 upon increasing initial pH. Increasing dilution of the initial synthesis mixture with water (5.50SiO
2:4.46Na
2O:1.00TiO
2:1.5KF:3.35H
2SO
4:450–750H
2O) resulted in progressively longer crystallizations, producing bi-pyramidal crystals of monotonically increasing dimensions. The results of experiments using NaF instead of either KF or KOH (i.e., conducted without K
+ and F
+) suggested that in unseeded, organic-free ETS-10 syntheses, K
+ was necessary for the nucleation of ETS-10, while F
− was not. |
Author | Sacco, Albert Yilmaz, Bilge Ji, Zhaoxia Warzywoda, Juliusz |
Author_xml | – sequence: 1 givenname: Zhaoxia surname: Ji fullname: Ji, Zhaoxia – sequence: 2 givenname: Bilge surname: Yilmaz fullname: Yilmaz, Bilge – sequence: 3 givenname: Juliusz surname: Warzywoda fullname: Warzywoda, Juliusz – sequence: 4 givenname: Albert surname: Sacco fullname: Sacco, Albert email: asacco@coe.neu.edu |
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Cites_doi | 10.1016/j.micromeso.2003.12.020 10.1016/j.micromeso.2004.03.030 10.1016/S1387-1811(00)00275-4 10.1016/S1387-1811(01)00267-0 10.1016/0021-9797(91)90438-E 10.1016/S1387-1811(02)00459-6 10.1021/ie00001a050 10.1021/cm021199c 10.1016/S1387-1811(02)00489-4 10.1016/S1387-1811(98)00120-6 10.1080/01418639508243589 10.1039/cc9960001105 10.1016/j.micromeso.2004.03.029 10.1016/S1387-1811(99)00022-0 10.1016/S1293-2558(01)01200-6 10.1023/A:1018591312000 10.1016/0927-6513(95)00005-T 10.1039/cc9960001435 |
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Keywords | Synthesis Titanosilicates ETS-10 Crystallization kinetics Surface structure Crystallization Kinetics Hydrothermal condition Titanium Silicates |
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References | Yilmaz, Miraglia, Warzywoda, Sacco (bib16) 2004; 71 Tiller (bib22) 1991 Rocha, Ferreira, Lin, Anderson (bib8) 1998; 23 Bazzana, Dumrul, Warzywoda, Hsiao, Klass, Knapp, Rains, E.M., Sullivan, West, Woo, Sacco (bib14) 2002; vol. 142, Part A Southon, Howe (bib23) 2002; 14 P.W. Blosser, S.M. Kuznicki, US Patent 5,453,263, 1995 den Ouden, Thompson (bib25) 1991; 143 Anderson, Agger, Hanif, Terasaki, Ohsuna (bib21) 2001; 3 den Ouden, Thompson (bib26) 1992; 31 S.M. Kuznicki, US Patent 4,853,202, 1989 Warzywoda, Yilmaz, Miraglia, Sacco (bib17) 2004; 71 Mihailova, Valtchev, Mintova, Konstantinov (bib19) 1997; 16 Barrer (bib24) 1982 Das, Chandwadkar, Budhkar, Belhekar, Sivasanker (bib27) 1995; 4 Yang, Paillaud, vanBreukelen, Kessler, Duprey (bib9) 2001; 46 Anderson, Agger, Pervaiz, Weigel, Cheetham (bib20) 1998 Pavel, Vuono, Nastro, Nagy, Bilba (bib6) 2002; vol. 142, Part A Pavel, Vuono, Catanzaro, De Luca, Bilba, Nastro, Nagy (bib5) 2002; 56 Anderson, Terasaki, Ohsuna, Malley, Philippou, MacKay, Ferreira, Rocha, Lidin (bib18) 1995; 71 Kim, Kim, Jung, Hayhurst (bib13) 2002; 56 Lamberti (bib2) 1999; 30 Das, Chandwadkar, Sivasanker (bib4) 1996 Liu, Thomas (bib7) 1996 Kim, Lee, Yoo, Hayhurst (bib12) 2000; 41 Miraglia, Yilmaz, Warzywoda, Bazzana, Sacco (bib15) 2004; 69 C.C. Pavel, I.V. Asaftei, Gh. Iofcea, P. DeLuca, D. Vuono, J.B. Nagy, A. Nastro, N. Bilba, in: E.W.J. vanSteen, L.H. Callanan, M. Claeys, C.T. O’Connor (Eds.), Proceedings: 14th International Zeolite Conference, ISBN: 0-958-46636-X, p. 770 Kuznicki, Thrush, Allen, Levine, Hamil, Hayhurst, Mansour (bib3) 1992 Mihailova (10.1016/j.micromeso.2005.01.006_bib19) 1997; 16 Rocha (10.1016/j.micromeso.2005.01.006_bib8) 1998; 23 Yilmaz (10.1016/j.micromeso.2005.01.006_bib16) 2004; 71 Anderson (10.1016/j.micromeso.2005.01.006_bib20) 1998 Tiller (10.1016/j.micromeso.2005.01.006_bib22) 1991 Miraglia (10.1016/j.micromeso.2005.01.006_bib15) 2004; 69 Bazzana (10.1016/j.micromeso.2005.01.006_bib14) 2002; vol. 142, Part A Lamberti (10.1016/j.micromeso.2005.01.006_bib2) 1999; 30 Kuznicki (10.1016/j.micromeso.2005.01.006_bib3) 1992 Anderson (10.1016/j.micromeso.2005.01.006_bib21) 2001; 3 Pavel (10.1016/j.micromeso.2005.01.006_bib6) 2002; vol. 142, Part A Southon (10.1016/j.micromeso.2005.01.006_bib23) 2002; 14 Barrer (10.1016/j.micromeso.2005.01.006_bib24) 1982 Das (10.1016/j.micromeso.2005.01.006_bib27) 1995; 4 den Ouden (10.1016/j.micromeso.2005.01.006_bib25) 1991; 143 Das (10.1016/j.micromeso.2005.01.006_bib4) 1996 Yang (10.1016/j.micromeso.2005.01.006_bib9) 2001; 46 Kim (10.1016/j.micromeso.2005.01.006_bib12) 2000; 41 10.1016/j.micromeso.2005.01.006_bib11 Liu (10.1016/j.micromeso.2005.01.006_bib7) 1996 10.1016/j.micromeso.2005.01.006_bib10 Pavel (10.1016/j.micromeso.2005.01.006_bib5) 2002; 56 Anderson (10.1016/j.micromeso.2005.01.006_bib18) 1995; 71 den Ouden (10.1016/j.micromeso.2005.01.006_bib26) 1992; 31 10.1016/j.micromeso.2005.01.006_bib1 Warzywoda (10.1016/j.micromeso.2005.01.006_bib17) 2004; 71 Kim (10.1016/j.micromeso.2005.01.006_bib13) 2002; 56 |
References_xml | – volume: vol. 142, Part A start-page: 117 year: 2002 ident: bib14 publication-title: Impact of Zeolites and Other Porous Materials on the New Technologies at the Beginning of the New Millenium contributor: fullname: Sacco – volume: 71 start-page: 813 year: 1995 ident: bib18 publication-title: Philos. Mag. B contributor: fullname: Lidin – volume: vol. 142, Part A start-page: 295 year: 2002 ident: bib6 publication-title: Impact of Zeolites and Other Porous Materials on the New Technologies at the Beginning of the New Millenium contributor: fullname: Bilba – year: 1982 ident: bib24 article-title: Hydrothermal Chemistry of Zeolites contributor: fullname: Barrer – start-page: 1487 year: 1998 ident: bib20 publication-title: Proceedings of 12th International Zeolite Conference, vol. 3 contributor: fullname: Cheetham – start-page: 427 year: 1992 ident: bib3 publication-title: Synthesis of Microporous Materials, Vol. I, Molecular Sieves contributor: fullname: Mansour – volume: 23 start-page: 253 year: 1998 ident: bib8 publication-title: Micropor. Mesopor. Mater. contributor: fullname: Anderson – volume: 69 start-page: 71 year: 2004 ident: bib15 publication-title: Micropor. Mesopor. Mater. contributor: fullname: Sacco – volume: 71 start-page: 167 year: 2004 ident: bib16 publication-title: Micropor. Mesopor. Mater. contributor: fullname: Sacco – volume: 14 start-page: 4209 year: 2002 ident: bib23 publication-title: Chem. Mater. contributor: fullname: Howe – volume: 71 start-page: 177 year: 2004 ident: bib17 publication-title: Micropor. Mesopor. Mater. contributor: fullname: Sacco – volume: 41 start-page: 79 year: 2000 ident: bib12 publication-title: Micropor. Mesopor. Mater. contributor: fullname: Hayhurst – volume: 31 start-page: 369 year: 1992 ident: bib26 publication-title: Ind. Eng. Chem. Res. contributor: fullname: Thompson – start-page: 1105 year: 1996 ident: bib4 publication-title: Chem. Commun. contributor: fullname: Sivasanker – volume: 46 start-page: 1 year: 2001 ident: bib9 publication-title: Micropor. Mesopor. Mater. contributor: fullname: Duprey – volume: 16 start-page: 1303 year: 1997 ident: bib19 publication-title: J. Mater. Sci. Lett. contributor: fullname: Konstantinov – start-page: 1435 year: 1996 ident: bib7 publication-title: Chem. Commun. contributor: fullname: Thomas – volume: 4 start-page: 195 year: 1995 ident: bib27 publication-title: Micropor. Mater. contributor: fullname: Sivasanker – volume: 30 start-page: 155 year: 1999 ident: bib2 publication-title: Micropor. Mesopor. Mater. contributor: fullname: Lamberti – volume: 3 start-page: 809 year: 2001 ident: bib21 publication-title: Solid State Sci. contributor: fullname: Ohsuna – volume: 143 start-page: 77 year: 1991 ident: bib25 publication-title: J. Coll. Interf. Sci. contributor: fullname: Thompson – volume: 56 start-page: 227 year: 2002 ident: bib5 publication-title: Micropor. Mesopor. Mater. contributor: fullname: Nagy – year: 1991 ident: bib22 article-title: The Science of Crystallization: Microscopic Interfacial Phenomena contributor: fullname: Tiller – volume: 56 start-page: 89 year: 2002 ident: bib13 publication-title: Micropor. Mesopor. Mater. contributor: fullname: Hayhurst – volume: 69 start-page: 71 year: 2004 ident: 10.1016/j.micromeso.2005.01.006_bib15 publication-title: Micropor. Mesopor. Mater. doi: 10.1016/j.micromeso.2003.12.020 contributor: fullname: Miraglia – start-page: 1487 year: 1998 ident: 10.1016/j.micromeso.2005.01.006_bib20 contributor: fullname: Anderson – volume: 71 start-page: 167 year: 2004 ident: 10.1016/j.micromeso.2005.01.006_bib16 publication-title: Micropor. Mesopor. Mater. doi: 10.1016/j.micromeso.2004.03.030 contributor: fullname: Yilmaz – volume: 41 start-page: 79 year: 2000 ident: 10.1016/j.micromeso.2005.01.006_bib12 publication-title: Micropor. Mesopor. Mater. doi: 10.1016/S1387-1811(00)00275-4 contributor: fullname: Kim – year: 1982 ident: 10.1016/j.micromeso.2005.01.006_bib24 contributor: fullname: Barrer – volume: 46 start-page: 1 year: 2001 ident: 10.1016/j.micromeso.2005.01.006_bib9 publication-title: Micropor. Mesopor. Mater. doi: 10.1016/S1387-1811(01)00267-0 contributor: fullname: Yang – volume: 143 start-page: 77 year: 1991 ident: 10.1016/j.micromeso.2005.01.006_bib25 publication-title: J. Coll. Interf. Sci. doi: 10.1016/0021-9797(91)90438-E contributor: fullname: den Ouden – volume: 56 start-page: 89 year: 2002 ident: 10.1016/j.micromeso.2005.01.006_bib13 publication-title: Micropor. Mesopor. Mater. doi: 10.1016/S1387-1811(02)00459-6 contributor: fullname: Kim – ident: 10.1016/j.micromeso.2005.01.006_bib10 – volume: 31 start-page: 369 year: 1992 ident: 10.1016/j.micromeso.2005.01.006_bib26 publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie00001a050 contributor: fullname: den Ouden – volume: 14 start-page: 4209 year: 2002 ident: 10.1016/j.micromeso.2005.01.006_bib23 publication-title: Chem. Mater. doi: 10.1021/cm021199c contributor: fullname: Southon – volume: 56 start-page: 227 year: 2002 ident: 10.1016/j.micromeso.2005.01.006_bib5 publication-title: Micropor. Mesopor. Mater. doi: 10.1016/S1387-1811(02)00489-4 contributor: fullname: Pavel – volume: 23 start-page: 253 year: 1998 ident: 10.1016/j.micromeso.2005.01.006_bib8 publication-title: Micropor. Mesopor. Mater. doi: 10.1016/S1387-1811(98)00120-6 contributor: fullname: Rocha – volume: 71 start-page: 813 year: 1995 ident: 10.1016/j.micromeso.2005.01.006_bib18 publication-title: Philos. Mag. B doi: 10.1080/01418639508243589 contributor: fullname: Anderson – year: 1991 ident: 10.1016/j.micromeso.2005.01.006_bib22 contributor: fullname: Tiller – start-page: 1105 year: 1996 ident: 10.1016/j.micromeso.2005.01.006_bib4 publication-title: Chem. Commun. doi: 10.1039/cc9960001105 contributor: fullname: Das – ident: 10.1016/j.micromeso.2005.01.006_bib1 – volume: 71 start-page: 177 year: 2004 ident: 10.1016/j.micromeso.2005.01.006_bib17 publication-title: Micropor. Mesopor. Mater. doi: 10.1016/j.micromeso.2004.03.029 contributor: fullname: Warzywoda – volume: vol. 142, Part A start-page: 117 year: 2002 ident: 10.1016/j.micromeso.2005.01.006_bib14 contributor: fullname: Bazzana – volume: 30 start-page: 155 year: 1999 ident: 10.1016/j.micromeso.2005.01.006_bib2 publication-title: Micropor. Mesopor. Mater. doi: 10.1016/S1387-1811(99)00022-0 contributor: fullname: Lamberti – ident: 10.1016/j.micromeso.2005.01.006_bib11 – volume: 3 start-page: 809 year: 2001 ident: 10.1016/j.micromeso.2005.01.006_bib21 publication-title: Solid State Sci. doi: 10.1016/S1293-2558(01)01200-6 contributor: fullname: Anderson – start-page: 427 year: 1992 ident: 10.1016/j.micromeso.2005.01.006_bib3 contributor: fullname: Kuznicki – volume: 16 start-page: 1303 year: 1997 ident: 10.1016/j.micromeso.2005.01.006_bib19 publication-title: J. Mater. Sci. Lett. doi: 10.1023/A:1018591312000 contributor: fullname: Mihailova – volume: 4 start-page: 195 year: 1995 ident: 10.1016/j.micromeso.2005.01.006_bib27 publication-title: Micropor. Mater. doi: 10.1016/0927-6513(95)00005-T contributor: fullname: Das – volume: vol. 142, Part A start-page: 295 year: 2002 ident: 10.1016/j.micromeso.2005.01.006_bib6 contributor: fullname: Pavel – start-page: 1435 year: 1996 ident: 10.1016/j.micromeso.2005.01.006_bib7 publication-title: Chem. Commun. doi: 10.1039/cc9960001435 contributor: fullname: Liu |
SSID | ssj0017121 |
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Snippet | The ternary reaction composition diagram in the SiO
2–Na
2O–TiO
2–KF–H
2SO
4–H
2O system was developed for static ETS-10 synthesis at 473
K utilizing Ti(SO
4)... |
SourceID | crossref pascalfrancis elsevier |
SourceType | Aggregation Database Index Database Publisher |
StartPage | 1 |
SubjectTerms | Chemistry Colloidal state and disperse state Crystallization kinetics ETS-10 Exact sciences and technology General and physical chemistry Porous materials Surface structure Synthesis Titanosilicates |
Title | Hydrothermal synthesis of titanosilicate ETS-10 using Ti(SO 4) 2 |
URI | https://dx.doi.org/10.1016/j.micromeso.2005.01.006 |
Volume | 81 |
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