Raman and Infrared Spectroscopy of Aqueous Corrosion Films on Lead in 0.1M Chloride Solutions

• Published in: Journal of the Electrochemical Society Vol. 127; no. 8; pp. 1702 - 1706
• Main Authors: Thibeau, Richard J., Brown, Chris W., Goldfarb, Arnon Z., Heidersbach, Robert H.
• Format: Journal Article
• Language: English
• Published: 01.08.1980

The Pb--H2O--Cl Pourbaix diagram was investigated by examining potentiostatically oxidized Pb samples using Raman and infrared spectroscopy. The surface films formed in 0.1M HCl solution were those predicted by the potential pH diagram. In neutral and basic solutions, the film compositions were not...