Visible light photocatalysis for aerobic oxidative cleavage of alkenes

[Display omitted] Aerobic oxidative cleavage of alkenes is presented to give aldehydes and ketones under visible light photocatalysis. A series of aryl substituted alkenes were tested to be suitable substrates in this strategy. Evidence proved that the initiation step undergoes an energy transfer pa...

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Bibliographic Details
Published inTetrahedron letters Vol. 125; p. 154624
Main Authors Li, Huili, Fu, Jundong, Fu, Jianmin, Wei, Donglei, Chen, Hou, Bai, Liangjiu, Wang, Wenxiang, Yang, Lixia, Yang, Huawei, Wang, Weili
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 28.07.2023
Subjects
Aerobic oxidative cleavage
Alkene
Energy transfer
Visible light photocatalysis
Alkene
Visible light photocatalysis
Aerobic oxidative cleavage
Energy transfer
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Summary:[Display omitted] Aerobic oxidative cleavage of alkenes is presented to give aldehydes and ketones under visible light photocatalysis. A series of aryl substituted alkenes were tested to be suitable substrates in this strategy. Evidence proved that the initiation step undergoes an energy transfer pathway, which may help simplify the reaction condition and exhibit high tolerance of the substrate scope.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2023.154624