Cation exchange properties of LiTi2(PO4)3 and synthesis of its microporous materials via glass

• Published in: Journal of the Electrochemical Society Vol. 140; no. 1; pp. L7 - L9
• Main Authors: HOSONO, H, IMAI, K, ABE, Y
• Format: Journal Article
• Language: English
• Published: Pennington, NJ Electrochemical Society 1993
• Subjects: Chemistry; Exact sciences and technology; General and physical chemistry; Ion-exchange; Surface physical chemistry; Cation exchange; Alkali metal Compounds; Sodium Ions; Lithium Titanium Phosphates Mixed; Electrolyte solution; Transition metal Compounds; Silver I Ions; Experimental study; X ray diffraction; Microporosity; Transition metal Ions; Alkali metal Ions; Aqueous solution; Glass ceramics; Ceramic materials

Bulk microporous ceramics comprising a skeleton of LiTi2(PO4)3 and continuous pores were prepared by a controlled crystallisation of glasses in the LiTi2(PO4)3-Ca3(PO4)2 system, followed by acid leaching of the Ca3(PO4)2 phases. The product had a specific surface area of approximately 30 m2. Excelle...