Cation exchange properties of LiTi2(PO4)3 and synthesis of its microporous materials via glass
Bulk microporous ceramics comprising a skeleton of LiTi2(PO4)3 and continuous pores were prepared by a controlled crystallisation of glasses in the LiTi2(PO4)3-Ca3(PO4)2 system, followed by acid leaching of the Ca3(PO4)2 phases. The product had a specific surface area of approximately 30 m2. Excelle...
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| Published in | Journal of the Electrochemical Society Vol. 140; no. 1; pp. L7 - L9 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Pennington, NJ
Electrochemical Society
1993
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Bulk microporous ceramics comprising a skeleton of LiTi2(PO4)3 and continuous pores were prepared by a controlled crystallisation of glasses in the LiTi2(PO4)3-Ca3(PO4)2 system, followed by acid leaching of the Ca3(PO4)2 phases. The product had a specific surface area of approximately 30 m2. Excellent cation-exchange properties were achieved, Li+ ions readily exchanging with Na+ and Ag+ at room temperature, but not with other monovalent and divalent ions. 14 refs. |
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| AbstractList | Bulk microporous ceramics comprising a skeleton of LiTi2(PO4)3 and continuous pores were prepared by a controlled crystallisation of glasses in the LiTi2(PO4)3-Ca3(PO4)2 system, followed by acid leaching of the Ca3(PO4)2 phases. The product had a specific surface area of approximately 30 m2. Excellent cation-exchange properties were achieved, Li+ ions readily exchanging with Na+ and Ag+ at room temperature, but not with other monovalent and divalent ions. 14 refs. |
| Author | ABE, Y IMAI, K HOSONO, H |
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| CitedBy_id | crossref_primary_10_1006_jssc_1999_8465 crossref_primary_10_1016_0025_5408_94_90185_6 crossref_primary_10_1016_j_materresbull_2009_04_007 crossref_primary_10_1016_0022_3093_93_91248_2 crossref_primary_10_1016_S1566_7367_02_00141_3 crossref_primary_10_1149_1945_7111_ac6390 crossref_primary_10_1557_JMR_1994_0755 crossref_primary_10_1016_S0022_3697_01_00017_8 crossref_primary_10_1016_j_jpowsour_2006_10_009 crossref_primary_10_1016_S0013_4686_96_00321_0 crossref_primary_10_1021_am800228s crossref_primary_10_1002_chin_199314015 crossref_primary_10_1016_S1003_6326_14_63135_6 crossref_primary_10_1016_j_jnoncrysol_2011_09_026 crossref_primary_10_1002_fuce_202000070 crossref_primary_10_1149_2_0101514jes crossref_primary_10_1016_0022_3093_95_00309_6 crossref_primary_10_1021_ic971345u crossref_primary_10_5229_JKES_2013_16_4_191 crossref_primary_10_1021_jp072244c crossref_primary_10_1021_jp9082079 crossref_primary_10_1557_JMR_2000_0113 |
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| Keywords | Cation exchange Alkali metal Compounds Sodium Ions Lithium Titanium Phosphates Mixed Electrolyte solution Transition metal Compounds Silver I Ions Experimental study X ray diffraction Microporosity Transition metal Ions Alkali metal Ions Aqueous solution Glass ceramics Ceramic materials |
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| Title | Cation exchange properties of LiTi2(PO4)3 and synthesis of its microporous materials via glass |
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