Electrochemical performance optimization of the polyaniline electrodeposited on ITO substrate

We have elaborated polyaniline films on ITO substrate (indium tin oxide), by electrochemical process in different electrolytes (HCl, H SO , HNO , and H BO ), which allowed us to study the effect of the counter ion on electrochemical energy storage performances of polyaniline as electrode material in...

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Published inEnvironmental science and pollution research international
Main Authors Aynaou, Aziz, Youbi, Boubaker, Lghazi, Youssef, Himi, Mohammed Ait, Haimer, Chaimaa El, Bahar, Jihane, Sahlaoui, Ahmed, Bimaghra, Itto
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Published Germany 06.03.2023
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Abstract We have elaborated polyaniline films on ITO substrate (indium tin oxide), by electrochemical process in different electrolytes (HCl, H SO , HNO , and H BO ), which allowed us to study the effect of the counter ion on electrochemical energy storage performances of polyaniline as electrode material in supercapacitors. The study of the different obtained films performances was carried out by cyclic voltammetry and galvanostatic charge-discharge method and is interpreted by the SEM technique. We found that there is a clear dependence on the specific capacitance of the counter ion. Justified by its porous structure, the PANI/ITO electrode doped with SO has the highest specific capacitance, 57.3 mF/cm at a current density of 0.2 mA/cm and 64.8 mF/cm at 5 mV/s. The deep analysis by Dunn's method allowed us to conclude that the faradic process dominates the energy storage in the case of PANI/ITO electrode elaborated in boric acid (99%). On the contrary, the capacitive character is the most contributory in the case of electrodes elaborated in H SO , HCl, and HNO . The study at different potentials (0.80, 0.85, 0.90, 0.95, and 1.0 V/SCE) from 0.2 M monomer aniline showed that the deposition at 0.95 V/SCE leads to higher specific capacitance (24.3 mF/cm at scan rate 5 mV/s and 23.6 mF/cm at 0.2 mA/cm ) with a coulombic efficiency of 94%. By varying the concentration of the monomer while keeping a potential fixed at 0.95 V/SCE, we also found that the specific capacitance increases with monomeric concentration.
AbstractList We have elaborated polyaniline films on ITO substrate (indium tin oxide), by electrochemical process in different electrolytes (HCl, H2SO4, HNO3, and H3BO3), which allowed us to study the effect of the counter ion on electrochemical energy storage performances of polyaniline as electrode material in supercapacitors. The study of the different obtained films performances was carried out by cyclic voltammetry and galvanostatic charge-discharge method and is interpreted by the SEM technique. We found that there is a clear dependence on the specific capacitance of the counter ion. Justified by its porous structure, the PANI/ITO electrode doped with SO42- has the highest specific capacitance, 57.3 mF/cm2 at a current density of 0.2 mA/cm2 and 64.8 mF/cm2 at 5 mV/s. The deep analysis by Dunn's method allowed us to conclude that the faradic process dominates the energy storage in the case of PANI/ITO electrode elaborated in boric acid (99%). On the contrary, the capacitive character is the most contributory in the case of electrodes elaborated in H2SO4, HCl, and HNO3. The study at different potentials (0.80, 0.85, 0.90, 0.95, and 1.0 V/SCE) from 0.2 M monomer aniline showed that the deposition at 0.95 V/SCE leads to higher specific capacitance (24.3 mF/cm2 at scan rate 5 mV/s and 23.6 mF/cm2 at 0.2 mA/cm2) with a coulombic efficiency of 94%. By varying the concentration of the monomer while keeping a potential fixed at 0.95 V/SCE, we also found that the specific capacitance increases with monomeric concentration.
We have elaborated polyaniline films on ITO substrate (indium tin oxide), by electrochemical process in different electrolytes (HCl, H SO , HNO , and H BO ), which allowed us to study the effect of the counter ion on electrochemical energy storage performances of polyaniline as electrode material in supercapacitors. The study of the different obtained films performances was carried out by cyclic voltammetry and galvanostatic charge-discharge method and is interpreted by the SEM technique. We found that there is a clear dependence on the specific capacitance of the counter ion. Justified by its porous structure, the PANI/ITO electrode doped with SO has the highest specific capacitance, 57.3 mF/cm at a current density of 0.2 mA/cm and 64.8 mF/cm at 5 mV/s. The deep analysis by Dunn's method allowed us to conclude that the faradic process dominates the energy storage in the case of PANI/ITO electrode elaborated in boric acid (99%). On the contrary, the capacitive character is the most contributory in the case of electrodes elaborated in H SO , HCl, and HNO . The study at different potentials (0.80, 0.85, 0.90, 0.95, and 1.0 V/SCE) from 0.2 M monomer aniline showed that the deposition at 0.95 V/SCE leads to higher specific capacitance (24.3 mF/cm at scan rate 5 mV/s and 23.6 mF/cm at 0.2 mA/cm ) with a coulombic efficiency of 94%. By varying the concentration of the monomer while keeping a potential fixed at 0.95 V/SCE, we also found that the specific capacitance increases with monomeric concentration.
Author Youbi, Boubaker
Sahlaoui, Ahmed
Lghazi, Youssef
Haimer, Chaimaa El
Bimaghra, Itto
Bahar, Jihane
Aynaou, Aziz
Himi, Mohammed Ait
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Keywords Cyclic voltammetry
Specific capacitance
Electrodeposition
Polyaniline
Energy storage
Language English
License 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
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Snippet We have elaborated polyaniline films on ITO substrate (indium tin oxide), by electrochemical process in different electrolytes (HCl, H SO , HNO , and H BO ),...
We have elaborated polyaniline films on ITO substrate (indium tin oxide), by electrochemical process in different electrolytes (HCl, H2SO4, HNO3, and H3BO3),...
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Title Electrochemical performance optimization of the polyaniline electrodeposited on ITO substrate
URI https://www.ncbi.nlm.nih.gov/pubmed/36872403
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