A new BEDT-TTF salt and polypyrrole films containing the chiral polyoxometalate [H 4Co 2Mo 10O 38] 6

The chiral polyoxometalate [H 4Co 2Mo 10O 38] 6− has been used in the preparation of hybrid materials in the form of crystals or polymeric films. A new radical salt of the donor bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF or ET) containing the two enantiomers of this polyoxometalate has been obt...

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Published inSynthetic metals Vol. 154; no. 1; pp. 241 - 244
Main Authors Coronado, E., Curreli, S., Giménez-Saiz, C., Gómez-García, C.J., Roth, J.
Format Journal Article Conference Proceeding
LanguageEnglish
Published Lausanne Elsevier B.V 01.09.2005
Amsterdam Elsevier Science
New York, NY
Subjects
Applied sciences
Bis(ethylenedithio)tetrathiafulvalene
Chiral polyoxometalates
Electrical properties
Exact sciences and technology
Hybrid materials
Physicochemistry of polymers
Polymerization
Polymers and radiations
Polypyrrole
Radical salts
Radical salts
Electrical properties
Hybrid materials
Bis(ethylenedithio)tetrathiafulvalene
Polypyrrole
Chiral polyoxometalates
Heteropolysalt
Electrical conductivity
Bis(ethylenedithio)tetrathiafulvalene; Polypyrrole; Chiral polyoxometalates; Hybrid materials; Radical salts
Temperature effect
Chiral compound
Cobalt complex
Experimental study
Electrochemical polymerization
Free radical
Conducting polymers
BEDT-TTF
Morphology
Preparation
Doped polymer
Charge transfer compound
Molybdenum complex
Pyrrole polymer
Crystalline structure
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Abstract The chiral polyoxometalate [H 4Co 2Mo 10O 38] 6− has been used in the preparation of hybrid materials in the form of crystals or polymeric films. A new radical salt of the donor bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF or ET) containing the two enantiomers of this polyoxometalate has been obtained by electrocrystallization. This radical salt shows semiconducting behavior with room temperature conductivity of 9 S.cm −1 and activation energy of 40 meV. Polypyrrole films doped with a racemic mixture of polyoxometalates and also the enantiomerically pure (+) 589-[H 4Co 2Mo 10O 38] 6− have been prepared electrochemically. Circular dichroism experiments suggest that the chiral polyoxometalates do not induce macroasymmetry into the polypyrrole chains during polymerization. Conductivities at room temperature of these polymer films range between 36 and 49 S.cm −1.
AbstractList The chiral polyoxometalate [H 4Co 2Mo 10O 38] 6− has been used in the preparation of hybrid materials in the form of crystals or polymeric films. A new radical salt of the donor bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF or ET) containing the two enantiomers of this polyoxometalate has been obtained by electrocrystallization. This radical salt shows semiconducting behavior with room temperature conductivity of 9 S.cm −1 and activation energy of 40 meV. Polypyrrole films doped with a racemic mixture of polyoxometalates and also the enantiomerically pure (+) 589-[H 4Co 2Mo 10O 38] 6− have been prepared electrochemically. Circular dichroism experiments suggest that the chiral polyoxometalates do not induce macroasymmetry into the polypyrrole chains during polymerization. Conductivities at room temperature of these polymer films range between 36 and 49 S.cm −1.
Author Curreli, S.
Gómez-García, C.J.
Roth, J.
Giménez-Saiz, C.
Coronado, E.
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  surname: Giménez-Saiz
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  fullname: Gómez-García, C.J.
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  surname: Roth
  fullname: Roth, J.
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Cites_doi 10.1016/S0379-6779(97)81007-7
10.1002/anie.200453985
10.1103/PhysRevLett.87.236602
10.1071/CH99105
10.1021/cr970471c
10.1007/s100080000181
10.1016/S0379-6779(99)00170-8
10.1246/bcsj.43.2654
10.1021/ja960393v
10.1021/jp014340y
10.1103/PhysRevB.50.5196
10.1016/0032-3861(94)90427-8
10.1021/cm010378b
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Issue 1
Keywords Radical salts
Electrical properties
Hybrid materials
Bis(ethylenedithio)tetrathiafulvalene
Polypyrrole
Chiral polyoxometalates
Heteropolysalt
Electrical conductivity
Bis(ethylenedithio)tetrathiafulvalene; Polypyrrole; Chiral polyoxometalates; Hybrid materials; Radical salts
Temperature effect
Chiral compound
Cobalt complex
Experimental study
Electrochemical polymerization
Free radical
Conducting polymers
BEDT-TTF
Morphology
Preparation
Doped polymer
Charge transfer compound
Molybdenum complex
Pyrrole polymer
Crystalline structure
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Snippet The chiral polyoxometalate [H 4Co 2Mo 10O 38] 6− has been used in the preparation of hybrid materials in the form of crystals or polymeric films. A new radical...
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SubjectTerms Applied sciences
Bis(ethylenedithio)tetrathiafulvalene
Chiral polyoxometalates
Electrical properties
Exact sciences and technology
Hybrid materials
Physicochemistry of polymers
Polymerization
Polymers and radiations
Polypyrrole
Radical salts
Title A new BEDT-TTF salt and polypyrrole films containing the chiral polyoxometalate [H 4Co 2Mo 10O 38] 6
URI https://dx.doi.org/10.1016/j.synthmet.2005.07.063
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