Hetero-bi- and tri-metallic complexes containing both electron releasing and electron accepting redox centres
The new complexes [M(η 5-C 5H 4CH 2O) 2Mo(NO)L ★]; M = Fe or Ru and L ★ = (hydro)tris(3,5-dimethylpyrazolyl)borate, which contain a chelating metallocene ligand, have been prepared and characterised along with the related trimetallic complex [{Fe(η 5-C 5H 5)(η 5-C 5H 4CH 2O)} 2Mo(NO)L ★]. Their elec...
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| Published in | Journal of organometallic chemistry Vol. 325; no. 1; pp. C19 - C22 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Lausanne
Elsevier B.V
12.05.1987
Elsevier Science |
| Subjects | |
| Online Access | Get full text |
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| Abstract | The new complexes [M(η
5-C
5H
4CH
2O)
2Mo(NO)L
★]; M = Fe or Ru and L
★ = (hydro)tris(3,5-dimethylpyrazolyl)borate, which contain a chelating metallocene ligand, have been prepared and characterised along with the related trimetallic complex [{Fe(η
5-C
5H
5)(η
5-C
5H
4CH
2O)}
2Mo(NO)L
★]. Their electrochemical properties are reported, and the reduction potentials for the {Mo(NO)}
4+ redox centre in the chelated species are 100 mV more anodic than for that in the trimetallic non-chelated complex. |
|---|---|
| AbstractList | The new complexes [M(η
5-C
5H
4CH
2O)
2Mo(NO)L
★]; M = Fe or Ru and L
★ = (hydro)tris(3,5-dimethylpyrazolyl)borate, which contain a chelating metallocene ligand, have been prepared and characterised along with the related trimetallic complex [{Fe(η
5-C
5H
5)(η
5-C
5H
4CH
2O)}
2Mo(NO)L
★]. Their electrochemical properties are reported, and the reduction potentials for the {Mo(NO)}
4+ redox centre in the chelated species are 100 mV more anodic than for that in the trimetallic non-chelated complex. |
| Author | Sidebotham, R.Peter McCleverty, Jon A. Jones, Christopher J. Beer, Paul D. |
| Author_xml | – sequence: 1 givenname: Paul D. surname: Beer fullname: Beer, Paul D. – sequence: 2 givenname: Christopher J. surname: Jones fullname: Jones, Christopher J. – sequence: 3 givenname: Jon A. surname: McCleverty fullname: McCleverty, Jon A. – sequence: 4 givenname: R.Peter surname: Sidebotham fullname: Sidebotham, R.Peter |
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| Cites_doi | 10.1021/jo01355a001 10.1007/BF00621516 10.1021/ic00141a042 10.1016/0022-328X(86)80482-X 10.1039/cs9831200331 10.1016/S0022-328X(00)80600-2 |
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| Copyright | 1987 1987 INIST-CNRS |
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| Keywords | Iron Molybdenum Nitrosyl Complexes Trinuclear complex Organic ligand Metallocene Iron Organic compounds Electrochemical properties Molybdenum Ruthenium Nitrosyl Complexes Transition metal Nitrosyl Complexes Preparation Heteronuclear complex Dinuclear complex Boron Organic compounds Platinoid Complexes Chemical properties |
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| PublicationTitle | Journal of organometallic chemistry |
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| References | Beer, Charsley, Jones, McCleverty (BIB8) 1986; 307 Lindsay, Hauser (BIB11) 1957; 22 Dowling, Henry (BIB9) 1982; 21 Denti, Jones, McCleverty, Neaves, Reynolds (BIB3) 1983 N. AlObaidi, S.M. Charsley, W. Hussain, C.J. Jones, J.A. McCleverty, B.D. Neaves and S.J. Reynolds, Transition Metal Chem., in press. S.M. Charsley, C.J. Jones, J.A. McCleverty, B.D. Neaves and S.J. Reynolds, J. Chem. Soc., Dalton Trans., submitted. S.M. Charsley, C.J. Jones, J.A. McCleverty, B.D. Neaves and S.J. Reynolds and G. Denti, J. Chem. Soc., Dalton Trans., submitted. McCleverty (BIB1) 1983; 12 N. AlObaidi, D. Clague, M. Chaudhury, C.J. Jones, J.A. McCleverty, J.C. Pearson and S.S. Salam, J. Chem. Soc., Dalton Trans., in press. Charsley, Jones, McCleverty, Neaves, Reynolds (BIB7) 1986; 11 Sonoda, Moritani (BIB10) 1971; 26 Denti (10.1016/0022-328X(87)80415-1_BIB3) 1983 Lindsay (10.1016/0022-328X(87)80415-1_BIB11) 1957; 22 Dowling (10.1016/0022-328X(87)80415-1_BIB9) 1982; 21 McCleverty (10.1016/0022-328X(87)80415-1_BIB1) 1983; 12 10.1016/0022-328X(87)80415-1_BIB6 10.1016/0022-328X(87)80415-1_BIB4 10.1016/0022-328X(87)80415-1_BIB5 Beer (10.1016/0022-328X(87)80415-1_BIB8) 1986; 307 10.1016/0022-328X(87)80415-1_BIB2 Sonoda (10.1016/0022-328X(87)80415-1_BIB10) 1971; 26 Charsley (10.1016/0022-328X(87)80415-1_BIB7) 1986; 11 |
| References_xml | – volume: 21 start-page: 4088 year: 1982 ident: BIB9 publication-title: Inorg. Chem. contributor: fullname: Henry – start-page: 474 year: 1983 ident: BIB3 publication-title: J. Chem. Soc. contributor: fullname: Reynolds – volume: 26 start-page: 133 year: 1971 ident: BIB10 publication-title: J. Organomet. Chem. contributor: fullname: Moritani – volume: 12 start-page: 331 year: 1983 ident: BIB1 publication-title: Chem. Soc. Rev. contributor: fullname: McCleverty – volume: 11 start-page: 329 year: 1986 ident: BIB7 publication-title: Transition Metal Chem. contributor: fullname: Reynolds – volume: 22 start-page: 355 year: 1957 ident: BIB11 publication-title: J. Org. Chem. contributor: fullname: Hauser – volume: 307 start-page: C19 year: 1986 ident: BIB8 publication-title: J. Organomet. Chem. contributor: fullname: McCleverty – start-page: 474 year: 1983 ident: 10.1016/0022-328X(87)80415-1_BIB3 publication-title: J. Chem. Soc. contributor: fullname: Denti – ident: 10.1016/0022-328X(87)80415-1_BIB2 – volume: 22 start-page: 355 year: 1957 ident: 10.1016/0022-328X(87)80415-1_BIB11 publication-title: J. Org. Chem. doi: 10.1021/jo01355a001 contributor: fullname: Lindsay – volume: 11 start-page: 329 year: 1986 ident: 10.1016/0022-328X(87)80415-1_BIB7 publication-title: Transition Metal Chem. doi: 10.1007/BF00621516 contributor: fullname: Charsley – volume: 21 start-page: 4088 year: 1982 ident: 10.1016/0022-328X(87)80415-1_BIB9 publication-title: Inorg. Chem. doi: 10.1021/ic00141a042 contributor: fullname: Dowling – ident: 10.1016/0022-328X(87)80415-1_BIB6 – ident: 10.1016/0022-328X(87)80415-1_BIB4 – ident: 10.1016/0022-328X(87)80415-1_BIB5 – volume: 307 start-page: C19 year: 1986 ident: 10.1016/0022-328X(87)80415-1_BIB8 publication-title: J. Organomet. Chem. doi: 10.1016/0022-328X(86)80482-X contributor: fullname: Beer – volume: 12 start-page: 331 year: 1983 ident: 10.1016/0022-328X(87)80415-1_BIB1 publication-title: Chem. Soc. Rev. doi: 10.1039/cs9831200331 contributor: fullname: McCleverty – volume: 26 start-page: 133 year: 1971 ident: 10.1016/0022-328X(87)80415-1_BIB10 publication-title: J. Organomet. Chem. doi: 10.1016/S0022-328X(00)80600-2 contributor: fullname: Sonoda |
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| Snippet | The new complexes [M(η
5-C
5H
4CH
2O)
2Mo(NO)L
★]; M = Fe or Ru and L
★ = (hydro)tris(3,5-dimethylpyrazolyl)borate, which contain a chelating metallocene... |
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| SubjectTerms | Carbonyl and nitrosyl metals Chemistry Exact sciences and technology Inorganic chemistry and origins of life Preparations and properties |
| Title | Hetero-bi- and tri-metallic complexes containing both electron releasing and electron accepting redox centres |
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