An Ultra‐Robust and 3D Proton Transport Pathways iHOF with Single‐Crystal Superprotonic Conductivity Around 0.4 S cm−1

• Published in: Advanced functional materials Vol. 34; no. 49
• Main Authors: Cao, Xiao‐Jie, Cao, Li‐Hui, Bai, Xiang‐Tian, Hou, Xiao‐Ying, Li, Hai‐Yang
• Format: Journal Article
• Language: English
• Published: Hoboken Wiley Subscription Services, Inc 01.12.2024
• Subjects: anisotropic; Bonding strength; Charge materials; Chemical bonds; Density functional theory; density functional theory calculations; Hydrogen; Hydrogen bonding; Intermolecular forces; ionic hydrogen‐bonded organic frameworks; Protons; Robustness; Self-assembly; Single crystals; superprotonic conductivity

The weak intermolecular forces of hydrogen‐bonded organic frameworks (HOFs) make it relatively difficult to synthesize and design HOFs with superprotonic conductivity and robustness. The self‐assembly of ionic hydrogen bonding organic frameworks (iHOFs) through acid–base pairing strategies are possi...