Selective Oxidation of Olefins to Aldehydes/ Ketones/ Carboxylic Acids with an Efficient and Practical Polyoxometalate‐based Iron Catalyst

Herein, we reported the efficient method for synthesis of aldehydes, ketones and carboxylic acids from olefins catalyzed by inorganic‐ligand Fe (III) catalyst, (NH4)3[FeMo6O18(OH)6]. This transformation features sustainable conditions and utilizes commercially available H2O2 as the sole oxidant and...

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Bibliographic Details
Published inChemCatChem Vol. 14; no. 16
Main Authors Chang, Yalin, Xie, Ya, Zhao, Chengchun, Ren, Jingjing, Su, Wei, Zhao, Wenshu, Wu, Linke, Yu, Han
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 19.08.2022
Subjects
Aldehydes
Alkenes
Carboxylic acids
Catalysts
Chemical synthesis
environment-friendly
Hydrogen peroxide
Industrial applications
industrial-scale
Iron
Ketones
Oxidation
Oxidizing agents
polyoxometalate
Polyoxometallates
The oxidation of olefins
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Summary:Herein, we reported the efficient method for synthesis of aldehydes, ketones and carboxylic acids from olefins catalyzed by inorganic‐ligand Fe (III) catalyst, (NH4)3[FeMo6O18(OH)6]. This transformation features sustainable conditions and utilizes commercially available H2O2 as the sole oxidant and CH3CN/ AcOH as the solvent. The simple synthesized catalyst has high efficiency towards the reactions under mild conditions and can be recycled at least six times with keeping stable activity. At the same time, the controllable products in the reaction have the potential for industrial application. Using (NH4)3[FeMo6O18(OH)6] as the catalyst, oxidative cleavage of alkenes to carbonyl compounds under mild conditions. A series of aldehydes, ketones and carboxylic acids are prepared in high yields.
Bibliography:These authors contributed equally to this work
ISSN:1867-3880
1867-3899
DOI:10.1002/cctc.202200209