Visible‐Light Photoredox‐Catalyzed Hydrodecarboxylation and Deuterodecarboxylation of Fatty Acids
Comprehensive Summary We develop an efficient visible‐light photoreodox‐catalyzed hydrodecarboxylation and deuterodecarboxylation of fatty acids for alkanes and deuterium alkanes. The key to the efficient transformation should attribute to the co‐catalysis of the suitable methoxy substituted acridin...
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| Published in | Chinese journal of chemistry Vol. 40; no. 16; pp. 1903 - 1908 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY‐VCH Verlag GmbH & Co. KGaA
15.08.2022
Wiley Subscription Services, Inc |
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| Abstract | Comprehensive Summary
We develop an efficient visible‐light photoreodox‐catalyzed hydrodecarboxylation and deuterodecarboxylation of fatty acids for alkanes and deuterium alkanes. The key to the efficient transformation should attribute to the co‐catalysis of the suitable methoxy substituted acridine photocatalyst (Mes‐1,3,6,8‐tetramethoxy‐Acr‐3”,5”‐dimethoxy‐Ph) and the hydrogen atom transfer catalyst 4′,4′‐dimethyl diphenyldisulfane, possibly via facilitating of quenching the active alkyl radicals to overcome the competitive homocoupling products, olefins via the disproportionation, cracking products via the C—C bond β‐scission.
Highly efficient hydrodecarboxylation and deuterodecarboxylation of fatty acids for alkanes and deuterium alkanes are developed, by co‐catalysis of the methoxy substituted acridine photocatalyst and the HAT catalyst under visible‐light irradiation. |
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| AbstractList | Comprehensive Summary
We develop an efficient visible‐light photoreodox‐catalyzed hydrodecarboxylation and deuterodecarboxylation of fatty acids for alkanes and deuterium alkanes. The key to the efficient transformation should attribute to the co‐catalysis of the suitable methoxy substituted acridine photocatalyst (Mes‐1,3,6,8‐tetramethoxy‐Acr‐3”,5”‐dimethoxy‐Ph) and the hydrogen atom transfer catalyst 4′,4′‐dimethyl diphenyldisulfane, possibly via facilitating of quenching the active alkyl radicals to overcome the competitive homocoupling products, olefins via the disproportionation, cracking products via the C—C bond β‐scission. Comprehensive Summary We develop an efficient visible‐light photoreodox‐catalyzed hydrodecarboxylation and deuterodecarboxylation of fatty acids for alkanes and deuterium alkanes. The key to the efficient transformation should attribute to the co‐catalysis of the suitable methoxy substituted acridine photocatalyst (Mes‐1,3,6,8‐tetramethoxy‐Acr‐3”,5”‐dimethoxy‐Ph) and the hydrogen atom transfer catalyst 4′,4′‐dimethyl diphenyldisulfane, possibly via facilitating of quenching the active alkyl radicals to overcome the competitive homocoupling products, olefins via the disproportionation, cracking products via the C—C bond β‐scission. Highly efficient hydrodecarboxylation and deuterodecarboxylation of fatty acids for alkanes and deuterium alkanes are developed, by co‐catalysis of the methoxy substituted acridine photocatalyst and the HAT catalyst under visible‐light irradiation. Comprehensive SummaryWe develop an efficient visible‐light photoreodox‐catalyzed hydrodecarboxylation and deuterodecarboxylation of fatty acids for alkanes and deuterium alkanes. The key to the efficient transformation should attribute to the co‐catalysis of the suitable methoxy substituted acridine photocatalyst (Mes‐1,3,6,8‐tetramethoxy‐Acr‐3”,5”‐dimethoxy‐Ph) and the hydrogen atom transfer catalyst 4′,4′‐dimethyl diphenyldisulfane, possibly via facilitating of quenching the active alkyl radicals to overcome the competitive homocoupling products, olefins via the disproportionation, cracking products via the C—C bond β‐scission. |
| Author | Hu, Rong‐Gui Tan, Fang‐Fang Li, Yang Sun, Yuan‐Li Hu, Chun‐Hong |
| Author_xml | – sequence: 1 givenname: Yuan‐Li surname: Sun fullname: Sun, Yuan‐Li organization: Center for Organic Chemistry, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an – sequence: 2 givenname: Fang‐Fang surname: Tan fullname: Tan, Fang‐Fang organization: Center for Organic Chemistry, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an – sequence: 3 givenname: Rong‐Gui surname: Hu fullname: Hu, Rong‐Gui organization: Center for Organic Chemistry, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an – sequence: 4 givenname: Chun‐Hong surname: Hu fullname: Hu, Chun‐Hong organization: Center for Organic Chemistry, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an – sequence: 5 givenname: Yang surname: Li fullname: Li, Yang email: liyang79@mail.xjtu.edu.cn organization: Center for Organic Chemistry, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an |
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| Snippet | Comprehensive Summary
We develop an efficient visible‐light photoreodox‐catalyzed hydrodecarboxylation and deuterodecarboxylation of fatty acids for alkanes... Comprehensive SummaryWe develop an efficient visible‐light photoreodox‐catalyzed hydrodecarboxylation and deuterodecarboxylation of fatty acids for alkanes and... |
| SourceID | proquest crossref wiley |
| SourceType | Aggregation Database Publisher |
| StartPage | 1903 |
| SubjectTerms | Alkanes Alkenes Catalysis Catalysts Cleavage Deuterium Deuterodecarboxylation Disproportionation Fatty acids Hydrodecarboxylation Hydrogen atoms Photocatalysis |
| Title | Visible‐Light Photoredox‐Catalyzed Hydrodecarboxylation and Deuterodecarboxylation of Fatty Acids |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fcjoc.202200143 https://www.proquest.com/docview/2689514828 |
| Volume | 40 |
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