Waste glass as a precursor in alkali‐activated materials: Mechanical, durability, and microstructural properties

The long‐term characteristics and durability of alkali‐activated mortars based on waste glass are crucial to better understand their performance in aggressive environments. In this regard, the performance of waste glass as a building material and its characteristics such as mechanical (compressive,...

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Published inStructural concrete : journal of the FIB Vol. 23; no. 6; pp. 3651 - 3671
Main Authors Mobasheri, Fatemeh, Mirvalad, Sajjad, Shirzadi Javid, Ali Akbar, Azizi, Shahab, Ghoroqi, Mahyar
Format Journal Article
LanguageEnglish
Published Weinheim WILEY‐VCH Verlag GmbH & Co. KGaA 01.12.2022
Wiley Subscription Services, Inc
Subjects
alkali‐activated waste glass
Aluminum
Calcium silicate hydrate
Chloride resistance
Drying
drying shrinkage
Durability
embodied CO2
Fourier transforms
Gels
mechanical characteristic
microstructural properties
Mortars (material)
Portland cements
Relative humidity
Room temperature
Scanning electron microscopy
Shrinkage
Silica
Silicon dioxide
Sodium aluminum silicates
Sulfate resistance
Thermal expansion
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Abstract The long‐term characteristics and durability of alkali‐activated mortars based on waste glass are crucial to better understand their performance in aggressive environments. In this regard, the performance of waste glass as a building material and its characteristics such as mechanical (compressive, flexural, and tensile strengths), durability (chloride migration coefficient, sulfate resistance, and drying shrinkage), and microstructural properties [x‐ray diffraction (XRD), Fourier transform infrared (FTIR), and scanning electron microscopy (SEM) with energy dispersive x‐ray analysis (SEM/EDX)] were evaluated. For this purpose, the specimens with different amounts of silica modulus and Na2O content were prepared. The specimens were cured at 95°C for 20 h and then kept at a relative humidity of 50% at room temperature until testing. The specimen with 10% Na2O and a silica modulus of 1.5 demonstrated the highest compressive, flexural, and tensile strengths. The specimens illustrated a lower chloride migration coefficient and lower expansion than the Portland cement one. By increasing both silica modulus and Na2O contents, the drying shrinkage of the specimens increased due to the presence of more free water. The microstructural results indicated that amorphous gels such as sodium aluminum silicate hydrate (N‐A‐S‐H) and sodium (calcium) silicate aluminum hydrate [N‐(C)‐A‐S‐H] were formed. The results of this study signify the utilization possibility of waste glass as an eco‐friendly material with desirable characteristics.
AbstractList The long‐term characteristics and durability of alkali‐activated mortars based on waste glass are crucial to better understand their performance in aggressive environments. In this regard, the performance of waste glass as a building material and its characteristics such as mechanical (compressive, flexural, and tensile strengths), durability (chloride migration coefficient, sulfate resistance, and drying shrinkage), and microstructural properties [x‐ray diffraction (XRD), Fourier transform infrared (FTIR), and scanning electron microscopy (SEM) with energy dispersive x‐ray analysis (SEM/EDX)] were evaluated. For this purpose, the specimens with different amounts of silica modulus and Na2O content were prepared. The specimens were cured at 95°C for 20 h and then kept at a relative humidity of 50% at room temperature until testing. The specimen with 10% Na2O and a silica modulus of 1.5 demonstrated the highest compressive, flexural, and tensile strengths. The specimens illustrated a lower chloride migration coefficient and lower expansion than the Portland cement one. By increasing both silica modulus and Na2O contents, the drying shrinkage of the specimens increased due to the presence of more free water. The microstructural results indicated that amorphous gels such as sodium aluminum silicate hydrate (N‐A‐S‐H) and sodium (calcium) silicate aluminum hydrate [N‐(C)‐A‐S‐H] were formed. The results of this study signify the utilization possibility of waste glass as an eco‐friendly material with desirable characteristics.
Abstract The long‐term characteristics and durability of alkali‐activated mortars based on waste glass are crucial to better understand their performance in aggressive environments. In this regard, the performance of waste glass as a building material and its characteristics such as mechanical (compressive, flexural, and tensile strengths), durability (chloride migration coefficient, sulfate resistance, and drying shrinkage), and microstructural properties [x‐ray diffraction (XRD), Fourier transform infrared (FTIR), and scanning electron microscopy (SEM) with energy dispersive x‐ray analysis (SEM/EDX)] were evaluated. For this purpose, the specimens with different amounts of silica modulus and Na 2 O content were prepared. The specimens were cured at 95°C for 20 h and then kept at a relative humidity of 50% at room temperature until testing. The specimen with 10% Na 2 O and a silica modulus of 1.5 demonstrated the highest compressive, flexural, and tensile strengths. The specimens illustrated a lower chloride migration coefficient and lower expansion than the Portland cement one. By increasing both silica modulus and Na 2 O contents, the drying shrinkage of the specimens increased due to the presence of more free water. The microstructural results indicated that amorphous gels such as sodium aluminum silicate hydrate (N‐A‐S‐H) and sodium (calcium) silicate aluminum hydrate [N‐(C)‐A‐S‐H] were formed. The results of this study signify the utilization possibility of waste glass as an eco‐friendly material with desirable characteristics.
Author Azizi, Shahab
Shirzadi Javid, Ali Akbar
Ghoroqi, Mahyar
Mobasheri, Fatemeh
Mirvalad, Sajjad
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crossref_primary_10_1016_j_conbuildmat_2022_129076
crossref_primary_10_1002_suco_202201220
crossref_primary_10_1002_suco_202400026
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Snippet The long‐term characteristics and durability of alkali‐activated mortars based on waste glass are crucial to better understand their performance in aggressive...
Abstract The long‐term characteristics and durability of alkali‐activated mortars based on waste glass are crucial to better understand their performance in...
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SubjectTerms alkali‐activated waste glass
Aluminum
Calcium silicate hydrate
Chloride resistance
Drying
drying shrinkage
Durability
embodied CO2
Fourier transforms
Gels
mechanical characteristic
microstructural properties
Mortars (material)
Portland cements
Relative humidity
Room temperature
Scanning electron microscopy
Shrinkage
Silica
Silicon dioxide
Sodium aluminum silicates
Sulfate resistance
Thermal expansion
Title Waste glass as a precursor in alkali‐activated materials: Mechanical, durability, and microstructural properties
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fsuco.202100671
https://www.proquest.com/docview/2758982567
Volume 23
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