Kinetics of Ultrasound-Assisted Dissolution of a LiCoO2 Powder in the Deep Eutectic Solvent Choline Chloride–Sulfosalicylic Acid
Ultrasound is used to enhance the dissolution of lithium cobalt(III) oxide in the deep eutectic solvent choline chloride–sulfosalicylic acid by the mechanism of liquid stirring by acoustic flows and accelerated penetration of the liquid into the pores and cracks of a metal oxide. Formulas are derive...
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| Published in | Theoretical foundations of chemical engineering Vol. 56; no. 6; pp. 997 - 1002 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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Moscow
Pleiades Publishing
01.12.2022
Springer Nature B.V |
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| Abstract | Ultrasound is used to enhance the dissolution of lithium cobalt(III) oxide in the deep eutectic solvent choline chloride–sulfosalicylic acid by the mechanism of liquid stirring by acoustic flows and accelerated penetration of the liquid into the pores and cracks of a metal oxide. Formulas are derived to describe the kinetics of the process and establish the relationship between its main parameters and characteristics. The conditions for the most efficient use of ultrasound are identified. Experimental data are obtained on the dissolution kinetics of LiCoO
2
powder in the deep eutectic solvent choline chloride–sulfosalicylic acid. The experimental data and the results of theoretical calculations are in good agreement, which confirms the adequacy of the developed ideas about the actual physicochemical essence of the studied processes. |
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| AbstractList | Ultrasound is used to enhance the dissolution of lithium cobalt(III) oxide in the deep eutectic solvent choline chloride–sulfosalicylic acid by the mechanism of liquid stirring by acoustic flows and accelerated penetration of the liquid into the pores and cracks of a metal oxide. Formulas are derived to describe the kinetics of the process and establish the relationship between its main parameters and characteristics. The conditions for the most efficient use of ultrasound are identified. Experimental data are obtained on the dissolution kinetics of LiCoO
2
powder in the deep eutectic solvent choline chloride–sulfosalicylic acid. The experimental data and the results of theoretical calculations are in good agreement, which confirms the adequacy of the developed ideas about the actual physicochemical essence of the studied processes. Ultrasound is used to enhance the dissolution of lithium cobalt(III) oxide in the deep eutectic solvent choline chloride–sulfosalicylic acid by the mechanism of liquid stirring by acoustic flows and accelerated penetration of the liquid into the pores and cracks of a metal oxide. Formulas are derived to describe the kinetics of the process and establish the relationship between its main parameters and characteristics. The conditions for the most efficient use of ultrasound are identified. Experimental data are obtained on the dissolution kinetics of LiCoO2 powder in the deep eutectic solvent choline chloride–sulfosalicylic acid. The experimental data and the results of theoretical calculations are in good agreement, which confirms the adequacy of the developed ideas about the actual physicochemical essence of the studied processes. |
| Author | Voshkin, A. A. Zinov’eva, I. V. Zakhodyaeva, Yu. A. Gradov, O. M. |
| Author_xml | – sequence: 1 givenname: O. M. surname: Gradov fullname: Gradov, O. M. email: lutt.plm@igic.ras.ru organization: Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences – sequence: 2 givenname: I. V. surname: Zinov’eva fullname: Zinov’eva, I. V. organization: Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences – sequence: 3 givenname: Yu. A. surname: Zakhodyaeva fullname: Zakhodyaeva, Yu. A. organization: Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences – sequence: 4 givenname: A. A. surname: Voshkin fullname: Voshkin, A. A. organization: Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences |
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| Cites_doi | 10.1016/j.hydromet.2014.01.015 10.1016/j.cep.2017.04.017 10.3390/molecules24193549 10.1063/1.1715904 10.1121/1.1907081 10.1016/j.cep.2018.07.011 10.1039/C9RA06423K 10.1016/B978-0-12-395662-0.50015-1 10.1121/1.1907161 10.1121/1.1907009 10.3390/met11121964 10.1002/cey2.29 10.1103/PhysRev.73.68 10.1134/S0040579517030150 10.1134/S0040579517050116 10.1007/978-3-642-91486-7_2 10.3390/pr9010015 |
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| Copyright | Pleiades Publishing, Ltd. 2022. ISSN 0040-5795, Theoretical Foundations of Chemical Engineering, 2022, Vol. 56, No. 6, pp. 997–1002. © Pleiades Publishing, Ltd., 2022. Russian Text © The Author(s), 2022, published in Teoreticheskie Osnovy Khimicheskoi Tekhnologii, 2022, Vol. 56, No. 6, pp. 705–711. |
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| Keywords | deep eutectic solvent wave propagation lithium cobalt(III) oxide acoustics enhancement ultrasound frequency spatial field distribution |
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| SubjectTerms | Adequacy Chemistry Chemistry and Materials Science Chlorides Choline Cobalt oxides Dissolution Eutectics Industrial Chemistry/Chemical Engineering Kinetics Lithium compounds Metal oxides Solvents |
| Title | Kinetics of Ultrasound-Assisted Dissolution of a LiCoO2 Powder in the Deep Eutectic Solvent Choline Chloride–Sulfosalicylic Acid |
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