Electrochemical Corrosion Behavior of Iron Aluminides in Sulfuric Acid
In the present work, samples of a binary intermetallic alloy (Fe3Al) with 26at.%Al were submitted to electrochemical corrosion evaluation in a 0.5M H2SO4 solution containing naturally dissolved oxygen. The corrosion resistance was evaluated by applying linear polarization, electrochemical impedance...
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Published in | Materials science forum Vol. 1012; pp. 395 - 400 |
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Format | Journal Article |
Language | English |
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Trans Tech Publications Ltd
27.10.2020
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Abstract | In the present work, samples of a binary intermetallic alloy (Fe3Al) with 26at.%Al were submitted to electrochemical corrosion evaluation in a 0.5M H2SO4 solution containing naturally dissolved oxygen. The corrosion resistance was evaluated by applying linear polarization, electrochemical impedance spectroscopy and potentiodynamic polarization at 22 and 35°C. The results obtained revealed that in both conditions the material exhibits active-passive behavior. Heating to 35°C did not alter the passivity characteristics of the alloy (passivation range and passive current density), but elevated the corrosion current density and the critical current density. The polarization resistance of the samples was also decreased with temperature, following the trend observed for the corrosion current density. |
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AbstractList | In the present work, samples of a binary intermetallic alloy (Fe
3
Al) with 26at.%Al were submitted to electrochemical corrosion evaluation in a 0.5M H
2
SO
4
solution containing naturally dissolved oxygen. The corrosion resistance was evaluated by applying linear polarization, electrochemical impedance spectroscopy and potentiodynamic polarization at 22 and 35°C. The results obtained revealed that in both conditions the material exhibits active-passive behavior. Heating to 35°C did not alter the passivity characteristics of the alloy (passivation range and passive current density), but elevated the corrosion current density and the critical current density. The polarization resistance of the samples was also decreased with temperature, following the trend observed for the corrosion current density. In the present work, samples of a binary intermetallic alloy (Fe3Al) with 26at.%Al were submitted to electrochemical corrosion evaluation in a 0.5M H2SO4 solution containing naturally dissolved oxygen. The corrosion resistance was evaluated by applying linear polarization, electrochemical impedance spectroscopy and potentiodynamic polarization at 22 and 35°C. The results obtained revealed that in both conditions the material exhibits active-passive behavior. Heating to 35°C did not alter the passivity characteristics of the alloy (passivation range and passive current density), but elevated the corrosion current density and the critical current density. The polarization resistance of the samples was also decreased with temperature, following the trend observed for the corrosion current density. |
Author | de Andrade Oliveira, Gabriela de Carvalho Filho, Carlos Trivellato Brito, Pedro Paiva |
Author_xml | – givenname: Gabriela surname: de Andrade Oliveira fullname: de Andrade Oliveira, Gabriela email: gabiao26@hotmail.com organization: Pontifícia Universidade Católica de Minas Gerais (PUC-Minas) : Department of Mechanical Engineering – givenname: Carlos Trivellato surname: de Carvalho Filho fullname: de Carvalho Filho, Carlos Trivellato email: carlos.trivellato.filho@gmail.com organization: Pontifical Catholic University of Minas Gerais – givenname: Pedro Paiva surname: Brito fullname: Brito, Pedro Paiva email: pbrito@pucminas.br organization: Pontifícia Universidade Católica de Minas Gerais (PUC-Minas) : Department of Mechanical Engineering |
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Cites_doi | 10.1016/j.actamat.2011.11.033 10.1016/j.electacta.2011.12.031 10.1016/S0010-938X(71)80015-X 10.1016/j.corsci.2016.01.007 10.1016/j.corsci.2004.07.025 10.1002/maco.201608854 10.1016/j.corsci.2007.12.012 10.1016/j.msea.2005.10.083 10.1016/j.jmrt.2013.12.002 10.1016/j.intermet.2005.02.003 10.1016/S1452-3981(23)14071-5 10.5006/2208 10.1016/j.scriptamat.2011.04.039 10.1016/j.matchemphys.2010.11.020 10.1016/j.intermet.2013.01.001 10.1524/zpch.2005.219.11.1489 10.1149/1.2715312 10.1016/j.actamat.2006.01.008 10.1016/j.corsci.2017.05.029 |
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Keywords | Electrochemical Impedance Spectroscopy Corrosion Potentiodynamic Polarization Iron Aluminide |
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Title | Electrochemical Corrosion Behavior of Iron Aluminides in Sulfuric Acid |
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