Trichloroacetylhydrazones: new highly reactive alkylating agents
The behavior of trichloroacylhydrazones as new highly reactive alkylating agents is disclosed; various secondary amines are alkylated within a few minutes at room temperature, and similar alkylating reductions were found with malonates.
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Published in | Chemical communications (Cambridge, England) no. 18; pp. 1893 - 1894 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
CAMBRIDGE
Royal Soc Chemistry
21.09.1999
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Subjects | |
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Abstract | The behavior of trichloroacylhydrazones as new highly reactive alkylating agents is disclosed; various secondary amines are alkylated within a few minutes at room temperature, and similar alkylating reductions were found with malonates. |
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AbstractList | The behavior of trichloroacylhydrazones as new highly reactive alkylating agents is disclosed; various secondary amines are alkylated within a few minutes at room temperature, and similar alkylating reductions were found with malonates. |
Author | Morgentin, R Lacroix, S Atlan El Kaim, L |
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References | Attanasi, OA (WOS:A1997YG33000002) 1997 KELLOGG RM (WOS:000082585000057.6) 1991; 8 YIANNIOS, CN (WOS:A1968B098800080) 1968; 33 El Kaim, L (WOS:000075693500028) 1998; 39 HUTCHINS RO (WOS:000082585000057.5) 1991; 8 ESCHENMOSER, A (WOS:A19679035600031) 1967; 50 TAYLOR, EC (WOS:A1981MW20200009) 1981; 103 ADLINGTON, RM (WOS:A1983QE51800006) 1983; 16 |
References_xml | – volume: 16 start-page: 55 year: 1983 ident: WOS:A1983QE51800006 article-title: RECENT APPLICATIONS OF THE SHAPIRO REACTION publication-title: ACCOUNTS OF CHEMICAL RESEARCH contributor: fullname: ADLINGTON, RM – volume: 33 start-page: 2076 year: 1968 ident: WOS:A1968B098800080 article-title: REACTION OF CHLORAL WITH HYDRAZINE publication-title: JOURNAL OF ORGANIC CHEMISTRY contributor: fullname: YIANNIOS, CN – volume: 50 start-page: 708 year: 1967 ident: WOS:A19679035600031 article-title: EINE NEUARTIGE FRAGMENTIERUNG CYCLISCHER ALPHA BETA-UNGESATTIGTER CARBONYLSYSTEME - SYNTHESE VON EXALTON UND RAC-MUSCON AUS CYCLODODECANON publication-title: HELVETICA CHIMICA ACTA contributor: fullname: ESCHENMOSER, A – volume: 8 start-page: 84 year: 1991 ident: WOS:000082585000057.6 publication-title: COMPREHENSIVE ORGANI contributor: fullname: KELLOGG RM – volume: 103 start-page: 7743 year: 1981 ident: WOS:A1981MW20200009 article-title: SYNTHESIS AND PROPERTIES OF 3-OXO-1,2-DIAZETIDINIUM YLIDES publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: TAYLOR, EC – volume: 8 start-page: 327 year: 1991 ident: WOS:000082585000057.5 publication-title: COMPREHENSIVE ORGANI contributor: fullname: HUTCHINS RO – volume: 39 start-page: 6885 year: 1998 ident: WOS:000075693500028 article-title: Trichloroacetic acid hydrazones I: New formation of 1,3,4-oxadiazoles from aldehydes publication-title: TETRAHEDRON LETTERS contributor: fullname: El Kaim, L – start-page: 1128 year: 1997 ident: WOS:A1997YG33000002 article-title: Working twenty years on conjugated azo-alkenes (and environs) to find new entries in organic synthesis publication-title: SYNLETT contributor: fullname: Attanasi, OA |
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Snippet | The behavior of trichloroacylhydrazones as new highly reactive alkylating agents is disclosed; various secondary amines are alkylated within a few minutes at... |
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Title | Trichloroacetylhydrazones: new highly reactive alkylating agents |
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