Trichloroacetylhydrazones: new highly reactive alkylating agents

The behavior of trichloroacylhydrazones as new highly reactive alkylating agents is disclosed; various secondary amines are alkylated within a few minutes at room temperature, and similar alkylating reductions were found with malonates.

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Published inChemical communications (Cambridge, England) no. 18; pp. 1893 - 1894
Main Authors Atlan, El Kaim, L, Lacroix, S, Morgentin, R
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 21.09.1999
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
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Abstract The behavior of trichloroacylhydrazones as new highly reactive alkylating agents is disclosed; various secondary amines are alkylated within a few minutes at room temperature, and similar alkylating reductions were found with malonates.
AbstractList The behavior of trichloroacylhydrazones as new highly reactive alkylating agents is disclosed; various secondary amines are alkylated within a few minutes at room temperature, and similar alkylating reductions were found with malonates.
Author Morgentin, R
Lacroix, S
Atlan
El Kaim, L
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References Attanasi, OA (WOS:A1997YG33000002) 1997
KELLOGG RM (WOS:000082585000057.6) 1991; 8
YIANNIOS, CN (WOS:A1968B098800080) 1968; 33
El Kaim, L (WOS:000075693500028) 1998; 39
HUTCHINS RO (WOS:000082585000057.5) 1991; 8
ESCHENMOSER, A (WOS:A19679035600031) 1967; 50
TAYLOR, EC (WOS:A1981MW20200009) 1981; 103
ADLINGTON, RM (WOS:A1983QE51800006) 1983; 16
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  article-title: Trichloroacetic acid hydrazones I: New formation of 1,3,4-oxadiazoles from aldehydes
  publication-title: TETRAHEDRON LETTERS
  contributor:
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  article-title: Working twenty years on conjugated azo-alkenes (and environs) to find new entries in organic synthesis
  publication-title: SYNLETT
  contributor:
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Snippet The behavior of trichloroacylhydrazones as new highly reactive alkylating agents is disclosed; various secondary amines are alkylated within a few minutes at...
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Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
Title Trichloroacetylhydrazones: new highly reactive alkylating agents
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