Trichloroacetylhydrazones: new highly reactive alkylating agents

The behavior of trichloroacylhydrazones as new highly reactive alkylating agents is disclosed; various secondary amines are alkylated within a few minutes at room temperature, and similar alkylating reductions were found with malonates.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 18; pp. 1893 - 1894
Main Authors Atlan, El Kaim, L, Lacroix, S, Morgentin, R
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 21.09.1999
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
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Summary:The behavior of trichloroacylhydrazones as new highly reactive alkylating agents is disclosed; various secondary amines are alkylated within a few minutes at room temperature, and similar alkylating reductions were found with malonates.
ISSN:1359-7345
1364-548X
DOI:10.1039/a905946f