Synthesis and X-ray structural studies of new spiro-cyclotriphosphazenes
The series of four cyclotriphosphazenes containing biphenyl and phenyl groups, [N3P3(C12H8)(3-n)Ph(2n)], where n = 0-3, (1-4 respectively), has been completed by the synthesis of two new C-bonded spiro- cyclotriphosphazenes, [N3P3(C12H8)(2)Ph(2)] 2 and [N3P3(C12H8)Ph(4)] 3, They have been fully char...
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Published in | Journal of the Chemical Society, Perkin Transactions 2 no. 1; pp. 15 - 18 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
CAMBRIDGE
Royal Soc Chemistry
01.01.1997
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Subjects | |
Online Access | Get full text |
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Summary: | The series of four cyclotriphosphazenes containing biphenyl and phenyl groups, [N3P3(C12H8)(3-n)Ph(2n)], where n = 0-3, (1-4 respectively), has been completed by the synthesis of two new C-bonded spiro- cyclotriphosphazenes, [N3P3(C12H8)(2)Ph(2)] 2 and [N3P3(C12H8)Ph(4)] 3, They have been fully characterised and X-ray structural analysis shows that both compounds have a planar cyclotriphosphazene ring with less overall molecular rigidity compared to the trispirocyclic analogue, 1. |
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ISSN: | 0300-9580 1364-5471 |
DOI: | 10.1039/a604907i |