Strong exciton coupling and circularly polarised luminescence in rigid complexes of chiral macrocyclic tetranaphthylamides
Strong exciton coupling occurs between adjacent pairs of naphthyl chromophores in the chiral sodium and europium complexes of L-1; in the constitutionally isomeric complexes of L-2, intramolecular excimer formation is observed and both sets of Eu complexes give a well defined, metal-based circularly...
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Published in | Chemical communications (Cambridge, England) no. 18; pp. 1747 - 1748 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
CAMBRIDGE
Royal Soc Chemistry
1997
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Abstract | Strong exciton coupling occurs between adjacent pairs of naphthyl chromophores in the chiral sodium and europium complexes of L-1; in the constitutionally isomeric complexes of L-2, intramolecular excimer formation is observed and both sets of Eu complexes give a well defined, metal-based circularly polarised emission. |
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AbstractList | Strong exciton coupling occurs between adjacent pairs of naphthyl chromophores in the chiral sodium and europium complexes of L-1; in the constitutionally isomeric complexes of L-2, intramolecular excimer formation is observed and both sets of Eu complexes give a well defined, metal-based circularly polarised emission. |
Author | Peacock, RD Moloney, JM Siligardi, G Parker, D Dickins, RS Howard, JAK |
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References | SISIDO, M (WOS:A1983QQ61100074) 1983; 105 Beeby, A (WOS:A1996VC21400007) 1996 Aime, S (WOS:A1997XA48000025) 1997; 119 PLATT, JR (WOS:A1949UB80400010) 1949; 17 PARKER, D (WOS:A1995RJ36900010) 1995 UENO, A (WOS:A1975V857300008) 1975; 14 Dickins, RS (WOS:A1997WV55600020) 1997; 36 Parker, D (WOS:A1996VL31700001) 1996 Beeby, A (WOS:A1997XP04700033) 1997 |
References_xml | – start-page: 1401 year: 1997 ident: WOS:A1997XP04700033 article-title: Luminescence from ytterbium(III) and its complexes in solution publication-title: CHEMICAL COMMUNICATIONS contributor: fullname: Beeby, A – start-page: 1565 year: 1996 ident: WOS:A1996VC21400007 article-title: Photochemical investigations of functionalised 1,4,7,10-tetraazacyclododecane ligands incorporating naphthyl chromophores publication-title: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 contributor: fullname: Beeby, A – volume: 36 start-page: 521 year: 1997 ident: WOS:A1997WV55600020 article-title: Structural rigidity and luminescence of chiral lanthanide tetraamide complexes based on 1,4,7,10-tetraazacyclododecane publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH contributor: fullname: Dickins, RS – start-page: 3613 year: 1996 ident: WOS:A1996VL31700001 article-title: Getting excited about lanthanide complexation chemistry publication-title: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS contributor: fullname: Parker, D – volume: 105 start-page: 3351 year: 1983 ident: WOS:A1983QQ61100074 article-title: CIRCULARLY POLARIZED FLUORESCENCE OF AROMATIC POLY(ALPHA-AMINO ACIDS) publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: SISIDO, M – volume: 14 start-page: 353 year: 1975 ident: WOS:A1975V857300008 article-title: CONFORMATIONAL STUDIES OF POLY-BETA-1-NAPHTHYLMETHYL-L-ASPARTATE publication-title: BIOPOLYMERS contributor: fullname: UENO, A – volume: 119 start-page: 4767 year: 1997 ident: WOS:A1997XA48000025 article-title: Prototropic vs whole water exchange contributions to the solvent relaxation enhancement in the aqueous solution of a cationic Gd3+ macrocyclic complex publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: Aime, S – start-page: 1305 year: 1995 ident: WOS:A1995RJ36900010 article-title: LUMINESCENCE BEHAVIOR OF CADMIUM, LEAD, ZINC, COPPER, NICKEL AND LANTHANIDE COMPLEXES OF OCTADENTATE MACROCYCLIC LIGANDS BEARING NAPHTHYL CHROMOPHORES publication-title: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 contributor: fullname: PARKER, D – volume: 17 start-page: 484 year: 1949 ident: WOS:A1949UB80400010 article-title: CLASSIFICATION OF SPECTRA OF CATA-CONDENSED HYDROCARBONS publication-title: JOURNAL OF CHEMICAL PHYSICS contributor: fullname: PLATT, JR |
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Title | Strong exciton coupling and circularly polarised luminescence in rigid complexes of chiral macrocyclic tetranaphthylamides |
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