MOF-derived porous NiO-Co3O4 for high performance ultrafast pulse generation
•The nonlinear optical properties of metal–organic framework derivatives porous NiO-Co3O4 were investigated for the first time.•For the first time, traditional soliton ultrafast pulse output was realized in an erbium-doped fiber laser (EDFL) by using the metal–organic framework derivative porous NiO...
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Published in | Optics and laser technology Vol. 155; p. 108358 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier Ltd
01.11.2022
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Abstract | •The nonlinear optical properties of metal–organic framework derivatives porous NiO-Co3O4 were investigated for the first time.•For the first time, traditional soliton ultrafast pulse output was realized in an erbium-doped fiber laser (EDFL) by using the metal–organic framework derivative porous NiO-Co3O4 as a SA.•For the first time, dual-wavelength mode locking has been achieved in an EDFL by using the metal–organic framework derivative porous NiO-Co3O4 as a SA.•Harmonic mode locking up to 1.04 GHz (corresponding to the 211th harmonic pulse) is achieved for the first time in an EDFL by using metal–organic framework derivative porous NiO-Co3O4 as a SA.
Porous NiO-Co3O4 architectures, as one kind of novel metal organic frameworks (MOFs), have attracted extensive attention in the field of electrocatalysis and optoelectronics thanks to its large specific surface area, porous and adjustable pore size, structural and functional diversity. Although MOFs have made great achievements in many fields, the research on their ultrafast photonics fields is still in its infancy. Therefore, in this paper, NiO-Co3O4 polyhedra were synthesized by using zeolitic imidazolate framework (ZIF-67) as the metal source and sacrificial template. In addition, combining NiO-Co3O4 polyhedra with the microstructure fiber, nonlinear optical (NLO) absorption of the saturable absorber (SA) structure was characterized by two arm measurement technique. The experimental determination of the saturable intensity and modulation depth of NiO-Co3O4 polyhedra were 9.1 MW/cm2 and 5.6%, which indicates that NiO-Co3O4 polyhedra possess excellent NLO absorption properties. Here, for the first time, it is proved that NiO-Co3O4 polyhedra can be served as an efficient SA to readily generate dual-wavelength mode-locking and high repetition rate output pulses up to 1.04 GHz (corresponding to 211th harmonic pulse) in erbium-doped fiber laser (EDFL), which is much higher than previous research results based on MOFs and their derivatives as SAs for ultrafast photonics. These experimental results demonstrate that the NiO-Co3O4 polyhedra SA derived from ZIF-67 is a new star which plays an important role in the field of ultrafast photonics. |
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AbstractList | •The nonlinear optical properties of metal–organic framework derivatives porous NiO-Co3O4 were investigated for the first time.•For the first time, traditional soliton ultrafast pulse output was realized in an erbium-doped fiber laser (EDFL) by using the metal–organic framework derivative porous NiO-Co3O4 as a SA.•For the first time, dual-wavelength mode locking has been achieved in an EDFL by using the metal–organic framework derivative porous NiO-Co3O4 as a SA.•Harmonic mode locking up to 1.04 GHz (corresponding to the 211th harmonic pulse) is achieved for the first time in an EDFL by using metal–organic framework derivative porous NiO-Co3O4 as a SA.
Porous NiO-Co3O4 architectures, as one kind of novel metal organic frameworks (MOFs), have attracted extensive attention in the field of electrocatalysis and optoelectronics thanks to its large specific surface area, porous and adjustable pore size, structural and functional diversity. Although MOFs have made great achievements in many fields, the research on their ultrafast photonics fields is still in its infancy. Therefore, in this paper, NiO-Co3O4 polyhedra were synthesized by using zeolitic imidazolate framework (ZIF-67) as the metal source and sacrificial template. In addition, combining NiO-Co3O4 polyhedra with the microstructure fiber, nonlinear optical (NLO) absorption of the saturable absorber (SA) structure was characterized by two arm measurement technique. The experimental determination of the saturable intensity and modulation depth of NiO-Co3O4 polyhedra were 9.1 MW/cm2 and 5.6%, which indicates that NiO-Co3O4 polyhedra possess excellent NLO absorption properties. Here, for the first time, it is proved that NiO-Co3O4 polyhedra can be served as an efficient SA to readily generate dual-wavelength mode-locking and high repetition rate output pulses up to 1.04 GHz (corresponding to 211th harmonic pulse) in erbium-doped fiber laser (EDFL), which is much higher than previous research results based on MOFs and their derivatives as SAs for ultrafast photonics. These experimental results demonstrate that the NiO-Co3O4 polyhedra SA derived from ZIF-67 is a new star which plays an important role in the field of ultrafast photonics. |
ArticleNumber | 108358 |
Author | Han, Yueheng Chen, Enci Zhang, Yani Li, Xiaohui Li, Gang Song, Zhuoying An, Mingqi Hu, Jiyi Lu, Hongbing Huang, Xiangzhen |
Author_xml | – sequence: 1 givenname: Yani surname: Zhang fullname: Zhang, Yani email: zhangyn@sust.edu.cn organization: Shaanxi University of Science & Technology, Department of Physics, Xi’an, Shaanxi 710021, China – sequence: 2 givenname: Zhuoying surname: Song fullname: Song, Zhuoying organization: Shaanxi University of Science & Technology, Department of Physics, Xi’an, Shaanxi 710021, China – sequence: 3 givenname: Xiaohui surname: Li fullname: Li, Xiaohui email: lixiaohui0523@163.com organization: Shaanxi Normal University, College of Physics and Information Technology, Xi'an, Shaanxi 710119, PR China – sequence: 4 givenname: Mingqi surname: An fullname: An, Mingqi organization: Shaanxi Normal University, College of Physics and Information Technology, Xi'an, Shaanxi 710119, PR China – sequence: 5 givenname: Yueheng surname: Han fullname: Han, Yueheng organization: Shaanxi Normal University, College of Physics and Information Technology, Xi'an, Shaanxi 710119, PR China – sequence: 6 givenname: Enci surname: Chen fullname: Chen, Enci organization: Guangxi University of Science and Technology, School of Computer Science and Communication Engineering, Liuzhou, Guangxi 545006, PR China – sequence: 7 givenname: Jiyi surname: Hu fullname: Hu, Jiyi organization: Shaanxi Normal University, College of Physics and Information Technology, Xi'an, Shaanxi 710119, PR China – sequence: 8 givenname: Xiangzhen surname: Huang fullname: Huang, Xiangzhen organization: Shaanxi Normal University, College of Physics and Information Technology, Xi'an, Shaanxi 710119, PR China – sequence: 9 givenname: Gang surname: Li fullname: Li, Gang organization: Shaanxi Normal University, College of Physics and Information Technology, Xi'an, Shaanxi 710119, PR China – sequence: 10 givenname: Hongbing surname: Lu fullname: Lu, Hongbing email: hblu@snnu.edu.cn organization: Shaanxi Normal University, College of Physics and Information Technology, Xi'an, Shaanxi 710119, PR China |
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Keywords | NiO-Co3O4 polyhedra Ultrafast photonics Metal organic frameworks (MOFs) High-order harmonic mode locking Dual-wavelength mode locking |
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SubjectTerms | Dual-wavelength mode locking High-order harmonic mode locking Metal organic frameworks (MOFs) NiO-Co3O4 polyhedra Ultrafast photonics |
Title | MOF-derived porous NiO-Co3O4 for high performance ultrafast pulse generation |
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