Arylimido zirconium and titanium complexes: characteristic structures and application in ethylene polymerization

• Published in: Zeitschrift für Naturforschung. B, A journal of chemical sciences Vol. 71; no. 10; pp. 1019 - 1023
• Main Authors: Yuan, Shifang, Wang, Lijing, Hua, Yupeng, Zhang, Jing, Sun, Wen-Hua
• Format: Journal Article
• Language: English
• Published: De Gruyter 01.10.2016
• Subjects: arylimido complex; ethylene polymerization; titanium; zirconium

Dimeric anilidolithium (ArHNLi·Et O) (Ar=2,6- Pr ) reacted with zirconium tetrachloride in THF to give the heterometallic zirconium–lithium complex [(Et O) Li(μ-Cl) (ArHN)(ArN=)Zr(μ-Cl)] ( ) and with titanium tetrachloride in toluene to give the titanium complex [(ArN=)TiCl ·(Et O) ] ( ) each in goo...