Correlation anisotropy driven Kosterlitz-Thouless-type quantum phase transition in a Kondo simulator

• Published in: Physical chemistry chemical physics : PCCP Vol. 24; no. 34; pp. 24 - 249
• Main Authors: Zhou, Wang-Huai, Zhang, Jun, Nan, Nan, Li, Wei, He, Ze-Dong, Zhu, Zhan-Wu, Wu, Yun-Pei, Xiong, Yong-Chen
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 31.08.2022
• Subjects: Anisotropy; Data processing; Kondo effect; Magnetic anisotropy; Magnetic moments; Metal phthalocyanines; Metal surfaces; Phase transitions; Quantum phenomena; Zeeman effect
• DOI: 10.1039/d2cp01668k
• ISSN: 1463-9076

The precise manipulation of the quantum states of individual atoms/molecules adsorbed on metal surfaces is one of the most exciting frontiers in nanophysics, enabling us to realize novel single molecular logic devices and quantum information processing. Herein, by modeling an iron phthalocyanine molecule adsorbed on the Au(111) surface with a two-impurity Anderson model, we demonstrate that the quantum states of such a system could be adjusted by the uniaxial magnetic anisotropy D z . For negative D z , the ground state is dominated by a parallel configuration of the z component of local spins, whereas it turns to be an antiparallel one when D z becomes positive. Interestingly, we found that these two phases are separated by a Kosterlitz-Thouless-type quantum phase transition, which is confirmed by the critical behaviors of the transmission coefficient and the local magnetic moment. Both phases are associated with spin correlation anisotropy, thus move against the Kondo effect. When the external magnetic field is applied, it first plays a role in compensating for the effect of D z , and then it contributes significantly to the Zeeman effect for positive D z , accompanied by the reappearance and the splitting of the Kondo peak, respectively. For fixed negative D z , only the Zeeman behavior is revealed. Our results provide deep insights into the manipulation of the quantum phase within a single molecular junction. Insights into the correlation anisotropy driven Kosterlitz-Thouless-type quantum phase transition, by modeling an FePc molecule adsorbed on the Au(111) surface with an Anderson model.