Chemical dynamics study on the gas-phase reaction of the D1-silylidyne radical (SiD; XΠ) with deuterium sulfide (DS) and hydrogen sulfide (HS)

• Published in: Physical chemistry chemical physics : PCCP Vol. 23; no. 24; pp. 13647 - 13661
• Main Authors: Goettl, Shane J, Doddipatla, Srinivas, Yang, Zhenghai, He, Chao, Kaiser, Ralf I, Silva, Mateus X, Galvão, Breno R. L, Millar, Tom J
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 23.06.2021
• Subjects: Decomposition reactions; Deep space; Deuteration; Deuterium; Electronic structure; Hydrogen; Hydrogen sulfide; Interstellar matter; Isomerization; Molecular beams; Orion nebula; Radicals; Silicon; Sulfur

The reactions of the D1-silylidyne radical (SiD; X 2 Π) with deuterium sulfide (D 2 S; X 1 A 1 ) and hydrogen sulfide (H 2 S; X 1 A 1 ) were conducted utilizing a crossed molecular beams machine under single collision conditions. The experimental work was carried out in conjunction with electronic s...