Measurments of High-Resolution Mass Spectra, Collisional Activation and Metastable Ion Spectra on a “Reversed” Nier-Johnson Geometry Mass Spectrometer

The geometry of a Hitachi RMU-7M double-focusing mass spectrometer was reversed by interchanging the positions of ion source and electron multiplier. The high resolution comparable to the “normal”instrument having Nier-Johnson type geometry can beobtained by using the modified instrument. This resul...

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Published inJournal of the Mass Spectrometry Society of Japan Vol. 26; no. 2; pp. 187 - 196
Main Authors Tajima, Eiji, Kato, Tatsuo, Ogawa, Tadayuki, Yoshii, Kazuo, Sakai, Ikuo
Format Journal Article
LanguageEnglish
Published Tokyo The Mass Spectrometry Society of Japan 1978
Japan Science and Technology Agency
Subjects
Acetophenon
C8H80+ ion
Collisional activation spectrum
McLafferty rearrangement
Metastable ion spectrum
Reversed geometry mass spectrometer
Valerophenon
Online AccessGet full text
ISSN1340-8097
1880-4225
1884-3271
DOI10.5702/massspec1953.26.187

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Abstract The geometry of a Hitachi RMU-7M double-focusing mass spectrometer was reversed by interchanging the positions of ion source and electron multiplier. The high resolution comparable to the “normal”instrument having Nier-Johnson type geometry can beobtained by using the modified instrument. This result makes it possible to measure metastable ion(MI)and collisional activation(CA)spectra and high resolution mass spectra on the same instrument by simple modification of the commercial instrument. The CA and MI spectra of the isomeric C8H8O+ ions generated from valerophenone and acetophenone were measured and discussed from a point of view of the ion structures.
AbstractList The geometry of a Hitachi RMU-7M double-focusing mass spectrometer was reversed by interchanging the positions of ion source and electron multiplier. The high resolution comparable to the "normal"instrument having Nier-Johnson type geometry can beobtained by using the modified instrument. This result makes it possible to measure metastable ion(MI)and collisional activation(CA)spectra and high resolution mass spectra on the same instrument by simple modification of the commercial instrument. The CA and MI spectra of the isomeric C8H8O+ ions generated from valerophenone and acetophenone were measured and discussed from a point of view of the ion structures.
Author Yoshii, Kazuo
Ogawa, Tadayuki
Sakai, Ikuo
Tajima, Eiji
Kato, Tatsuo
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References R. G. Cooks, J. H. Beynon, R. M. Caprioli and G. R. Lester, “Metastable Ions”, Elsevier, Amsterdam, The Netherlands, 1973.
T. Wachs, P. F. Bente, III, I. Sakai and F. W. McLafferty, The20th Annual Conference on Mass Spectrometry and Allied Topics, Dallas, U. S. A., 1972.
10)例えば(a)F. W. McLafferty, “Advances in Mass Spectrometry”, Vol. 4, Ed. E. Kendrick, London, Institute of Petroleum, 1968. (b)F. W. McLafferty, “Topics in Organic Mass Spectrometry”, Ed. A. L. Burlingame, Wiley-Interscience, New York, 1970. などを参照.
吉井一男, 横田水江, 酒井郁男, 第12回有機化合物のマススペクトロメトリー討論会講演予稿集,p.82,東京,1977.
F. W. McLafferty, P. F. Bente, III, R. Kornfeld, S. -C. Tsai and I. Howe, J. Am. Chem. Soc., 95, 2120(1973).
T. Wachs, P. F. Bente, III and F. W. McLafferty, Int. J. Mass Spectrom. Ion Phys., 9, 333(1972).
酒井郁男, 第9回有機化合物のマススペクトロメトリー討論会,講演予稿集,p.147,仙台,1974.
F. W. McLafferty, R. Kornfeld, W. F. Haddon, K. Levsen, I. Sakai, P. F. Bente, III, S. -C. Tsai and H. D. R. Schuddemage, J. Am. Chem. Soc., 95, 3886(1973).
M. Barber and R. M. Elliott, The12th Annual Conference on Mass Spectrometry and Allied Topics, Montreal, Canada, 1964.
F. W. McLafferty, J. Okamoto, H. Tsuyama, N. Nakajima, T. Noda and H. W. Major, Org. Mass Spectrom., 2, 751(1969).
F. W. McLafferty and I. Sakai, Org. Mass Spectrom., 7, 971(1973).
References_xml – reference: F. W. McLafferty, J. Okamoto, H. Tsuyama, N. Nakajima, T. Noda and H. W. Major, Org. Mass Spectrom., 2, 751(1969).
– reference: F. W. McLafferty, R. Kornfeld, W. F. Haddon, K. Levsen, I. Sakai, P. F. Bente, III, S. -C. Tsai and H. D. R. Schuddemage, J. Am. Chem. Soc., 95, 3886(1973).
– reference: T. Wachs, P. F. Bente, III and F. W. McLafferty, Int. J. Mass Spectrom. Ion Phys., 9, 333(1972).
– reference: 酒井郁男, 第9回有機化合物のマススペクトロメトリー討論会,講演予稿集,p.147,仙台,1974.
– reference: 吉井一男, 横田水江, 酒井郁男, 第12回有機化合物のマススペクトロメトリー討論会講演予稿集,p.82,東京,1977.
– reference: F. W. McLafferty, P. F. Bente, III, R. Kornfeld, S. -C. Tsai and I. Howe, J. Am. Chem. Soc., 95, 2120(1973).
– reference: F. W. McLafferty and I. Sakai, Org. Mass Spectrom., 7, 971(1973).
– reference: 10)例えば(a)F. W. McLafferty, “Advances in Mass Spectrometry”, Vol. 4, Ed. E. Kendrick, London, Institute of Petroleum, 1968. (b)F. W. McLafferty, “Topics in Organic Mass Spectrometry”, Ed. A. L. Burlingame, Wiley-Interscience, New York, 1970. などを参照.
– reference: T. Wachs, P. F. Bente, III, I. Sakai and F. W. McLafferty, The20th Annual Conference on Mass Spectrometry and Allied Topics, Dallas, U. S. A., 1972.
– reference: R. G. Cooks, J. H. Beynon, R. M. Caprioli and G. R. Lester, “Metastable Ions”, Elsevier, Amsterdam, The Netherlands, 1973.
– reference: M. Barber and R. M. Elliott, The12th Annual Conference on Mass Spectrometry and Allied Topics, Montreal, Canada, 1964.
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StartPage 187
SubjectTerms Acetophenon
C8H80+ ion
Collisional activation spectrum
McLafferty rearrangement
Metastable ion spectrum
Reversed geometry mass spectrometer
Valerophenon
Title Measurments of High-Resolution Mass Spectra, Collisional Activation and Metastable Ion Spectra on a “Reversed” Nier-Johnson Geometry Mass Spectrometer
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