Branch-Selective Intermolecular Hydroacylation: Hydrogen-Mediated Coupling of Anhydrides to Styrenes and Activated Olefins
Vorliebe für Verzweigungen: Die Hydrierung symmetrischer oder gemischter Carbonsäureanhydride in Gegenwart von Styrolen oder aktivierten Olefinen ergibt die Produkte der intermolekularen Hydroacylierung. Mit kationischen Rhodium‐Triphenylarsan‐Katalysatoren entstehen die verzweigten Kupplungsprodukt...
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| Published in | Angewandte Chemie Vol. 118; no. 41; pp. 7039 - 7042 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English German |
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Weinheim
WILEY-VCH Verlag
20.10.2006
WILEY‐VCH Verlag |
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| Abstract | Vorliebe für Verzweigungen: Die Hydrierung symmetrischer oder gemischter Carbonsäureanhydride in Gegenwart von Styrolen oder aktivierten Olefinen ergibt die Produkte der intermolekularen Hydroacylierung. Mit kationischen Rhodium‐Triphenylarsan‐Katalysatoren entstehen die verzweigten Kupplungsprodukte regiospezifisch in hohen Ausbeuten (siehe Schema; cod=Cycloocta‐1,5‐dien, ArF=3,5‐(CF3)2C6H3). |
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| AbstractList | Vorliebe für Verzweigungen: Die Hydrierung symmetrischer oder gemischter Carbonsäureanhydride in Gegenwart von Styrolen oder aktivierten Olefinen ergibt die Produkte der intermolekularen Hydroacylierung. Mit kationischen Rhodium‐Triphenylarsan‐Katalysatoren entstehen die verzweigten Kupplungsprodukte regiospezifisch in hohen Ausbeuten (siehe Schema; cod=Cycloocta‐1,5‐dien, ArF=3,5‐(CF3)2C6H3). |
| Author | Hong, Young-Taek Barchuk, Andriy Krische, Michael J. |
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| Snippet | Vorliebe für Verzweigungen: Die Hydrierung symmetrischer oder gemischter Carbonsäureanhydride in Gegenwart von Styrolen oder aktivierten Olefinen ergibt die... |
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| SubjectTerms | Alkene Homogene Katalyse Hydrierungen Hydroacylierungen Rhodium |
| Title | Branch-Selective Intermolecular Hydroacylation: Hydrogen-Mediated Coupling of Anhydrides to Styrenes and Activated Olefins |
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