Effects of redox potential on chalcopyrite leaching: An overview

Chalcopyrite is a prime, plentiful and widely distributed form of copper-bearing mineral. Compared with the traditional pyrometallurgy process, biohydrometallurgy has environmental and economic advantages, and is thus considered to be a promising mineral-processing technology. However, the dissoluti...

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Published inMinerals engineering Vol. 172; p. 107135
Main Authors Tian, Zuyuan, Li, Haodong, Wei, Qian, Qin, Wenqing, Yang, Congren
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.10.2021
Subjects
Band theory
Bioleaching
Chalcopyrite
Chemical leaching
Redox potential
Band theory
Bioleaching
Chalcopyrite
Redox potential
Chemical leaching
Online AccessGet full text
ISSN0892-6875
1872-9444
DOI10.1016/j.mineng.2021.107135

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Abstract Chalcopyrite is a prime, plentiful and widely distributed form of copper-bearing mineral. Compared with the traditional pyrometallurgy process, biohydrometallurgy has environmental and economic advantages, and is thus considered to be a promising mineral-processing technology. However, the dissolution kinetics of chalcopyrite in hydrometallurgy are low due to its high lattice energy. Redox potential has a significant role as chalcopyrite dissolves, and the possibility of controlling redox potential to promote chalcopyrite leaching cannot be ignored. In this article, the impact of redox potential on chemical leaching and bioleaching of chalcopyrite, reported in previous publications, are summarized. The effects of ferrous ions, ferric ions and copper ions in chalcopyrite leaching system are discussed, and the leaching behavior of chalcopyrite is explained by the band theory.
AbstractList Chalcopyrite is a prime, plentiful and widely distributed form of copper-bearing mineral. Compared with the traditional pyrometallurgy process, biohydrometallurgy has environmental and economic advantages, and is thus considered to be a promising mineral-processing technology. However, the dissolution kinetics of chalcopyrite in hydrometallurgy are low due to its high lattice energy. Redox potential has a significant role as chalcopyrite dissolves, and the possibility of controlling redox potential to promote chalcopyrite leaching cannot be ignored. In this article, the impact of redox potential on chemical leaching and bioleaching of chalcopyrite, reported in previous publications, are summarized. The effects of ferrous ions, ferric ions and copper ions in chalcopyrite leaching system are discussed, and the leaching behavior of chalcopyrite is explained by the band theory.
ArticleNumber 107135
Author Yang, Congren
Tian, Zuyuan
Wei, Qian
Qin, Wenqing
Li, Haodong
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  surname: Li
  fullname: Li, Haodong
  organization: School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China
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  givenname: Qian
  surname: Wei
  fullname: Wei, Qian
  organization: School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China
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  givenname: Wenqing
  surname: Qin
  fullname: Qin, Wenqing
  organization: School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China
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  givenname: Congren
  orcidid: 0000-0001-7040-2302
  surname: Yang
  fullname: Yang, Congren
  email: yangcongren@csu.edu.cn
  organization: School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China
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Keywords Band theory
Bioleaching
Chalcopyrite
Redox potential
Chemical leaching
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Snippet Chalcopyrite is a prime, plentiful and widely distributed form of copper-bearing mineral. Compared with the traditional pyrometallurgy process,...
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StartPage 107135
SubjectTerms Band theory
Bioleaching
Chalcopyrite
Chemical leaching
Redox potential
Title Effects of redox potential on chalcopyrite leaching: An overview
URI https://dx.doi.org/10.1016/j.mineng.2021.107135
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