Treatment of textile wastewater by sulfate radical based advanced oxidation processes

[Display omitted] •Generation of SO4•- via different methods, their mechanisms and oxidative pathways.•Systematically reviewed the SR-AOPs based treatments of textile wastewater.•Comparison of the performance of SR-AOPs and other •OH radicals based AOPs.•Studies on the pilot-scale and the full-scale...

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Published inSeparation and purification technology Vol. 293; p. 121115
Main Authors Nidheesh, P.V., Divyapriya, G., Ezzahra Titchou, Fatima, Hamdani, Mohamed
Format Journal Article
LanguageEnglish
Published Elsevier B.V 15.07.2022
Subjects
Advanced oxidation processes
Oxidation of dye molecules
Peroxymonosulfate activation
Persulfate activation
Sulfate radical
Textile wastewater treatment
Advanced oxidation processes
Textile wastewater treatment
Sulfate radical
Persulfate activation
Peroxymonosulfate activation
Oxidation of dye molecules
Online AccessGet full text
ISSN1383-5866
1873-3794
DOI10.1016/j.seppur.2022.121115

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Abstract [Display omitted] •Generation of SO4•- via different methods, their mechanisms and oxidative pathways.•Systematically reviewed the SR-AOPs based treatments of textile wastewater.•Comparison of the performance of SR-AOPs and other •OH radicals based AOPs.•Studies on the pilot-scale and the full-scale applications of SR-AOPs are summarized. The global textile industry is an ever-growing market, and the multi-stage operations of the textile manufacturing process produce an enormous quantity of wastewater encompassing refractory organic chemicals, necessitating the efficient, scalable, and economically viable advanced treatment methodologies. Among other advanced oxidation processes (AOPs), sulfate radicals based AOPs (SR-AOPs) gaining much attention in removing wide range of persistent organics in recent years, owing to its efficacy, adaptability, and versatility. SR-AOPs possess series of advantages over •OH radicals based AOPs such as high reactivity in wider pH range, selectivity towards contaminants, and numerous methods to activate its precursors persulfate (PS, S2O82−) and peroxymonosulfate (PMS, HSO5−) to produce sulfate radicals (SO4•-). In this review, the following aspects of the SR-AOPs are discussed for treating the textile wastewaters. (a) different methods and its mechanisms of PS and PMS activation including (i) homogenous and heterogenous metal activated processes such as metal ions, zero valent metals, metal oxides/ sulfides, and, metal organic frameworks, (ii) energy activated processes such as radiation (ultraviolet (UV), ultrasound (US) and microwave), and thermal activation, (iii) electrochemical based activation and (iv) carbocatalysis are discussed, (b) various reactive molecules and radicals species formed during the activation of PS and PMS, and its oxidative pathways and reactivities are elaborated, (c) performance of various SR-AOPs in treating textile wastewaters under different operating conditions, wastewater compositions and other influencing factors are deliberated, (d) comparison of the performances of SR-AOPs over HO• radicals based AOPs is discussed in treating the textile wastewaters and, (e) studies on the pilot-scale and the full-scale applications of SR-AOPs are summarized.
AbstractList [Display omitted] •Generation of SO4•- via different methods, their mechanisms and oxidative pathways.•Systematically reviewed the SR-AOPs based treatments of textile wastewater.•Comparison of the performance of SR-AOPs and other •OH radicals based AOPs.•Studies on the pilot-scale and the full-scale applications of SR-AOPs are summarized. The global textile industry is an ever-growing market, and the multi-stage operations of the textile manufacturing process produce an enormous quantity of wastewater encompassing refractory organic chemicals, necessitating the efficient, scalable, and economically viable advanced treatment methodologies. Among other advanced oxidation processes (AOPs), sulfate radicals based AOPs (SR-AOPs) gaining much attention in removing wide range of persistent organics in recent years, owing to its efficacy, adaptability, and versatility. SR-AOPs possess series of advantages over •OH radicals based AOPs such as high reactivity in wider pH range, selectivity towards contaminants, and numerous methods to activate its precursors persulfate (PS, S2O82−) and peroxymonosulfate (PMS, HSO5−) to produce sulfate radicals (SO4•-). In this review, the following aspects of the SR-AOPs are discussed for treating the textile wastewaters. (a) different methods and its mechanisms of PS and PMS activation including (i) homogenous and heterogenous metal activated processes such as metal ions, zero valent metals, metal oxides/ sulfides, and, metal organic frameworks, (ii) energy activated processes such as radiation (ultraviolet (UV), ultrasound (US) and microwave), and thermal activation, (iii) electrochemical based activation and (iv) carbocatalysis are discussed, (b) various reactive molecules and radicals species formed during the activation of PS and PMS, and its oxidative pathways and reactivities are elaborated, (c) performance of various SR-AOPs in treating textile wastewaters under different operating conditions, wastewater compositions and other influencing factors are deliberated, (d) comparison of the performances of SR-AOPs over HO• radicals based AOPs is discussed in treating the textile wastewaters and, (e) studies on the pilot-scale and the full-scale applications of SR-AOPs are summarized.
ArticleNumber 121115
Author Divyapriya, G.
Nidheesh, P.V.
Hamdani, Mohamed
Ezzahra Titchou, Fatima
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– sequence: 2
  givenname: G.
  surname: Divyapriya
  fullname: Divyapriya, G.
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  givenname: Fatima
  surname: Ezzahra Titchou
  fullname: Ezzahra Titchou, Fatima
  organization: Ibn Zohr University, Faculty of Sciences, Chemical department, BO 8106 –Dakhla district, Agadir, Morocco
– sequence: 4
  givenname: Mohamed
  surname: Hamdani
  fullname: Hamdani, Mohamed
  organization: Ibn Zohr University, Faculty of Sciences, Chemical department, BO 8106 –Dakhla district, Agadir, Morocco
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IngestDate Tue Jul 01 00:32:58 EDT 2025
Thu Apr 24 22:57:07 EDT 2025
Fri Feb 23 02:41:45 EST 2024
IsPeerReviewed true
IsScholarly true
Keywords Advanced oxidation processes
Textile wastewater treatment
Sulfate radical
Persulfate activation
Peroxymonosulfate activation
Oxidation of dye molecules
Language English
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elsevier_sciencedirect_doi_10_1016_j_seppur_2022_121115
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  year: 2022
  text: 2022-07-15
  day: 15
PublicationDecade 2020
PublicationTitle Separation and purification technology
PublicationYear 2022
Publisher Elsevier B.V
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Snippet [Display omitted] •Generation of SO4•- via different methods, their mechanisms and oxidative pathways.•Systematically reviewed the SR-AOPs based treatments of...
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SubjectTerms Advanced oxidation processes
Oxidation of dye molecules
Peroxymonosulfate activation
Persulfate activation
Sulfate radical
Textile wastewater treatment
Title Treatment of textile wastewater by sulfate radical based advanced oxidation processes
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