A novel ion exchange-electrodialysis hybrid system to treat rare-earth oxalic precipitation mother liquid: Contamination reduction, efficient Y3+ recovery, and acid separation

A novel ion exchange process combined with selective electrodialysis (SED) process has been demonstrated to not only efficiently recover low concentration rare-earth elements (REEs) and separate hydrochloric acid, but also significantly reduce membrane fouling. Two resins with different functional g...

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Published inDesalination Vol. 565; p. 116815
Main Authors Zhou, Hengcheng, Zheng, Zhi, Chen, Yongjing, Wan, Yinhua, Sun, Jiaxuan, Zhang, Tianci, Chen, Dongdong, Shi, Shaoyuan, Ju, Peihai
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.11.2023
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Abstract A novel ion exchange process combined with selective electrodialysis (SED) process has been demonstrated to not only efficiently recover low concentration rare-earth elements (REEs) and separate hydrochloric acid, but also significantly reduce membrane fouling. Two resins with different functional groups were selected for pretreatment and recovery of Y3+ from Y rare-earth oxalic precipitation (Y REOP) mother liquor. CH-93 resin showed a Y recovery rate of over 94 %, and the Y recovery efficiency remained above 90 % after 5 cycles. The mother liquor treated with resin (R-T) and the untreated mother liquor (W-R-T) were subjected to acid separation via SED, and membrane fouling was systematically evaluated. Compared with W-R-T group, the hydrochloric acid recovery efficiency of R-T group increased by 21.01 % (12 V), and the unit energy consumption decreased by 54.30 % (12 V). The results of 3D fluorescence excitation-emission matrix (3D-EEM) and fluorescent region integration (FRI) showed the dissolved organic matter (DOM) on AEM and CEM in R-T group both decreased by >45 %. The AEM of W-R-T group showed the highest fluorescence intensity ratio in V region (36 %), indicating humic acid-like substances were the main cause of AEM fouling. Generally, this study provides a new approach for the resource utilization of REOP mother liquor. [Display omitted] •Ion exchange combined with SED was confirmed to be efficiently Y element recover and hydrochloric acid separation.•CH-93 resin can significantly reduce unit energy consumption and the membrane fouling of electrodialysis.•32 % of the dissolved organic matter in the Y REOP mother liquor was accounted for humic acid-like substances.•The removal of DOM by resin was quantified via fluorescence regional integration (FRI) method.
AbstractList A novel ion exchange process combined with selective electrodialysis (SED) process has been demonstrated to not only efficiently recover low concentration rare-earth elements (REEs) and separate hydrochloric acid, but also significantly reduce membrane fouling. Two resins with different functional groups were selected for pretreatment and recovery of Y3+ from Y rare-earth oxalic precipitation (Y REOP) mother liquor. CH-93 resin showed a Y recovery rate of over 94 %, and the Y recovery efficiency remained above 90 % after 5 cycles. The mother liquor treated with resin (R-T) and the untreated mother liquor (W-R-T) were subjected to acid separation via SED, and membrane fouling was systematically evaluated. Compared with W-R-T group, the hydrochloric acid recovery efficiency of R-T group increased by 21.01 % (12 V), and the unit energy consumption decreased by 54.30 % (12 V). The results of 3D fluorescence excitation-emission matrix (3D-EEM) and fluorescent region integration (FRI) showed the dissolved organic matter (DOM) on AEM and CEM in R-T group both decreased by >45 %. The AEM of W-R-T group showed the highest fluorescence intensity ratio in V region (36 %), indicating humic acid-like substances were the main cause of AEM fouling. Generally, this study provides a new approach for the resource utilization of REOP mother liquor. [Display omitted] •Ion exchange combined with SED was confirmed to be efficiently Y element recover and hydrochloric acid separation.•CH-93 resin can significantly reduce unit energy consumption and the membrane fouling of electrodialysis.•32 % of the dissolved organic matter in the Y REOP mother liquor was accounted for humic acid-like substances.•The removal of DOM by resin was quantified via fluorescence regional integration (FRI) method.
ArticleNumber 116815
Author Shi, Shaoyuan
Sun, Jiaxuan
Chen, Yongjing
Zheng, Zhi
Wan, Yinhua
Chen, Dongdong
Zhang, Tianci
Ju, Peihai
Zhou, Hengcheng
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Keywords CC
DOM
REEs
Acid separation
REOP
Selective electrodialysis
SED
Ion exchangers
Rare earth recovery
R-T
W-R-T
Membrane fouling
DC
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Snippet A novel ion exchange process combined with selective electrodialysis (SED) process has been demonstrated to not only efficiently recover low concentration...
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StartPage 116815
SubjectTerms Acid separation
Ion exchangers
Membrane fouling
Rare earth recovery
Selective electrodialysis
Title A novel ion exchange-electrodialysis hybrid system to treat rare-earth oxalic precipitation mother liquid: Contamination reduction, efficient Y3+ recovery, and acid separation
URI https://dx.doi.org/10.1016/j.desal.2023.116815
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