Spectroscopic Investigation of a Metal-Metal-Bonded Fe 6 Single-Molecule Magnet with an Isolated S = 19 / 2 Giant-Spin Ground State

• Published in: Inorganic chemistry Vol. 60; no. 7; pp. 4610 - 4622
• Main Authors: Nehrkorn, Joscha, Greer, Samuel M, Malbrecht, Brian J, Anderton, Kevin J, Aliabadi, Azar, Krzystek, J, Schnegg, Alexander, Holldack, Karsten, Herrmann, Carmen, Betley, Theodore A, Stoll, Stefan, Hill, Stephen
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society (ACS) 05.04.2021
• Subjects: Chemistry

The metal-metal-bonded molecule [Bu N][( L) Fe (dmf) ] (Fe ) was previously shown to possess a thermally isolated spin = / ground state and found to exhibit slow magnetization relaxation below a blocking temperature of ∼5 K [ , , 13949-13956]. Here, we present a comprehensive spectroscopic investiga...