Catalytic activity of cerium-doped Ru/Al2O3 during ozonation of dimethyl phthalate

In this paper, factors influencing the mineralization of dimethyl phthalate (DMP) during catalytic ozonation with a cerium-doped Ru/Al 2 O 3 catalyst were studied. The catalytic contribution was calculated through the results of a comparison experiment. It showed that doping cerium significantly enh...

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Published inFrontiers of environmental science & engineering Vol. 2; no. 3; pp. 354 - 357
Main Authors Zhou, Yunrui, Zhu, Wanpeng, Chen, Xun
Format Journal Article
LanguageEnglish
Published Heidelberg SP Higher Education Press 01.09.2008
Springer Nature B.V
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Abstract In this paper, factors influencing the mineralization of dimethyl phthalate (DMP) during catalytic ozonation with a cerium-doped Ru/Al 2 O 3 catalyst were studied. The catalytic contribution was calculated through the results of a comparison experiment. It showed that doping cerium significantly enhanced catalytic activity. The total organic carbon (TOC) removal over the doped catalyst at 100 min reached 75.1%, 61.3% using Ru/Al 2 O 3 catalyst and only 14.0% using ozone alone. Catalytic activity reached the maximum when 0.2% of ruthenium and 1.0% of cerium were simultaneously loaded onto Al 2 O 3 support. Results of experiments on oxidation by ozone alone, adsorption of the catalyst, Ce ion’s and heterogeneous catalytic ozonation confirmed that the contribution of heterogeneous catalytic ozonation was about 50%, which showed the obvious effect of Ru-Ce/Al 2 O 3 on catalytic activity.
AbstractList In this paper, factors influencing the mineralization of dimethyl phthalate (DMP) during catalytic ozonation with a cerium-doped Ru/Al 2 O 3 catalyst were studied. The catalytic contribution was calculated through the results of a comparison experiment. It showed that doping cerium significantly enhanced catalytic activity. The total organic carbon (TOC) removal over the doped catalyst at 100 min reached 75.1%, 61.3% using Ru/Al 2 O 3 catalyst and only 14.0% using ozone alone. Catalytic activity reached the maximum when 0.2% of ruthenium and 1.0% of cerium were simultaneously loaded onto Al 2 O 3 support. Results of experiments on oxidation by ozone alone, adsorption of the catalyst, Ce ion’s and heterogeneous catalytic ozonation confirmed that the contribution of heterogeneous catalytic ozonation was about 50%, which showed the obvious effect of Ru-Ce/Al 2 O 3 on catalytic activity.
In this paper, factors influencing the mineralization of dimethyl phthalate (DMP) during catalytic ozonation with a cerium-doped Ru/Al2O3 catalyst were studied. The catalytic contribution was calculated through the results of a comparison experiment. It showed that doping cerium significantly enhanced catalytic activity. The total organic carbon (TOC) removal over the doped catalyst at 100 min reached 75.1%, 61.3% using Ru/Al2O3 catalyst and only 14.0% using ozone alone. Catalytic activity reached the maximum when 0.2% of ruthenium and 1.0% of cerium were simultaneously loaded onto Al2O3 support. Results of experiments on oxidation by ozone alone, adsorption of the catalyst, Ce ion’s and heterogeneous catalytic ozonation confirmed that the contribution of heterogeneous catalytic ozonation was about 50%, which showed the obvious effect of Ru-Ce/Al2O3 on catalytic activity.
Author Zhou, Yunrui
Chen, Xun
Zhu, Wanpeng
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Cites_doi 10.1016/j.apcatb.2003.07.007
10.1016/S0043-1354(99)00091-3
10.1016/0926-860X(95)00247-2
10.1016/j.cattod.2004.04.032
10.1021/ie020999u
10.1016/0043-1354(81)90054-3
10.1016/S0920-5861(99)00103-0
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10.1039/b204336j
10.1016/S0045-6535(02)00761-0
10.1016/j.apcatb.2003.12.019
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Issue 3
Keywords ozonation
Ru-Ce/Al
doped cerium
catalytic oxidation
ozone
O
Language English
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Snippet In this paper, factors influencing the mineralization of dimethyl phthalate (DMP) during catalytic ozonation with a cerium-doped Ru/Al 2 O 3 catalyst were...
In this paper, factors influencing the mineralization of dimethyl phthalate (DMP) during catalytic ozonation with a cerium-doped Ru/Al2O3 catalyst were...
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StartPage 354
SubjectTerms Aluminum oxide
Catalysts
Catalytic activity
Cerium
Earth and Environmental Science
Environment
Mineralization
Organic carbon
Oxidation
Ozonation
Ozone
Phthalates
Research Article
Ruthenium
Total organic carbon
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Title Catalytic activity of cerium-doped Ru/Al2O3 during ozonation of dimethyl phthalate
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