In situ Raman study of wairakite and dawsonite interaction with water at high P–T parameters
The behavior of wairakite CaAl 2 Si 4 O 12 · 2H 2 O and dawsonite NaAlCO 3 (OH) 2 in a water medium is studied by means of in situ Raman spectroscopy at the simultaneously high temperatures and pressures (up to T = 723 K and P = 1 GPa). After the initial minerals are partially dissolved, phillipsite...
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| Published in | Bulletin of the Russian Academy of Sciences. Physics Vol. 80; no. 5; pp. 522 - 524 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
New York
Allerton Press
01.05.2016
Springer Nature B.V |
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| Abstract | The behavior of wairakite CaAl
2
Si
4
O
12
· 2H
2
O and dawsonite NaAlCO
3
(OH)
2
in a water medium is studied by means of in situ Raman spectroscopy at the simultaneously high temperatures and pressures (up to
T
= 723 K and
P
= 1 GPa). After the initial minerals are partially dissolved, phillipsite forms in the wairakite–water system, and a glass-like phase is generated in the dawsonite–water system. These minerals show no signs of overhydration. The amorphization of the wairakite structure that occurs at high temperatures and pressures was reversible. |
|---|---|
| AbstractList | The behavior of wairakite CaAl
2
Si
4
O
12
· 2H
2
O and dawsonite NaAlCO
3
(OH)
2
in a water medium is studied by means of in situ Raman spectroscopy at the simultaneously high temperatures and pressures (up to
T
= 723 K and
P
= 1 GPa). After the initial minerals are partially dissolved, phillipsite forms in the wairakite–water system, and a glass-like phase is generated in the dawsonite–water system. These minerals show no signs of overhydration. The amorphization of the wairakite structure that occurs at high temperatures and pressures was reversible. The behavior of wairakite CaAl2Si4O12 · 2H2O and dawsonite NaAlCO3(OH)2 in a water medium is studied by means of in situ Raman spectroscopy at the simultaneously high temperatures and pressures (up to T = 723 K and P = 1 GPa). After the initial minerals are partially dissolved, phillipsite forms in the wairakite-water system, and a glass-like phase is generated in the dawsonite-water system. These minerals show no signs of overhydration. The amorphization of the wairakite structure that occurs at high temperatures and pressures was reversible. |
| Author | Likhacheva, A. Yu Krylov, A. S. Vtyurin, A. N. Goryainov, S. V. Prasad, P. S. R. |
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| References_xml | – volume: 75 start-page: 601 year: 1990 ident: 1616_CR13 publication-title: Am. Mineral. contributor: fullname: T.S. Bowers – volume: 17 start-page: 201 issue: 2 year: 2005 ident: 1616_CR5 publication-title: Eur. J. Mineral. doi: 10.1127/0935-1221/2005/0017-0201 contributor: fullname: S.V. Goryainov – volume: 369 start-page: 307 year: 1999 ident: 1616_CR3 publication-title: Dokl. Phys. Chem. contributor: fullname: S.V. Goryainov – volume: 79 start-page: 794 issue: 6 year: 2015 ident: 1616_CR12 publication-title: Bull. Russ. Acad. Sci.: Phys. doi: 10.3103/S1062873815060118 contributor: fullname: S.V. Goryainov – volume: 42 start-page: 113 year: 2001 ident: 1616_CR7 publication-title: Microporous Mesoporous Mater. doi: 10.1016/S1387-1811(00)00314-0 contributor: fullname: N.K. Moroz – volume: 53 start-page: S43 year: 2012 ident: 1616_CR2 publication-title: J. Struct. Chem. doi: 10.1134/S0022476612070062 contributor: fullname: S.V. Rashchenko – volume: 76 start-page: 804 issue: 7 year: 2012 ident: 1616_CR8 publication-title: Bull. Russ. Acad. Sci.: Phys. doi: 10.3103/S1062873812070143 contributor: fullname: S.V. Goryainov – volume: 219 start-page: 1065 year: 1988 ident: 1616_CR6 publication-title: Science doi: 10.1126/science.219.4588.1065 contributor: fullname: R.M. Hazen – volume: 43 start-page: 559 year: 2012 ident: 1616_CR9 publication-title: J. Raman Spectrosc. doi: 10.1002/jrs.3060 contributor: fullname: A.Yu. Likhacheva – volume: 77 start-page: 313 issue: 3 year: 2013 ident: 1616_CR10 publication-title: Bull. Russ. Acad. Sci.: Phys. doi: 10.3103/S106287381303012X contributor: fullname: S.V. Goryainov – volume: 15 start-page: EGU20139391 year: 2013 ident: 1616_CR4 publication-title: Proc. EGU General Assembly contributor: fullname: J. Gönna Von der – volume: 46 start-page: 171 year: 2015 ident: 1616_CR14 publication-title: J. Raman Spectrosc. doi: 10.1002/jrs.4604 contributor: fullname: N.V. Surovtsev – volume: 162 start-page: 1279 year: 2011 ident: 1616_CR1 publication-title: Contrib. Mineral. Petrol. doi: 10.1007/s00410-011-0653-0 contributor: fullname: A.R. Pawley – volume: 171 start-page: 125 year: 2013 ident: 1616_CR11 publication-title: Microporous Mesoporous Mater. doi: 10.1016/j.micromeso.2012.12.033 contributor: fullname: S.V. Goryainov |
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| Snippet | The behavior of wairakite CaAl
2
Si
4
O
12
· 2H
2
O and dawsonite NaAlCO
3
(OH)
2
in a water medium is studied by means of in situ Raman spectroscopy at the... The behavior of wairakite CaAl2Si4O12 · 2H2O and dawsonite NaAlCO3(OH)2 in a water medium is studied by means of in situ Raman spectroscopy at the... |
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| StartPage | 522 |
| SubjectTerms | Amorphization Dawsonite Disorder Hadrons Heavy Ions Minerals Nuclear Physics Physics Physics and Astronomy Proceedings of the International Interdisciplinary Symposium “Ordering in Minerals and Alloys” OMA-18 and Proceedings of the International Interdisciplinary Symposium “Order Raman spectroscopy Spectroscopic analysis the Properties of Oxides” ODPO-18 |
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| Title | In situ Raman study of wairakite and dawsonite interaction with water at high P–T parameters |
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