Tetraphenyladamantane-based microporous polyaminals for efficient adsorption of CO2, H2 and organic vapors

• Published in: Microporous and mesoporous materials Vol. 323; p. 111206
• Main Authors: Rong, Meng, Yang, Liangrong, Yang, Chao, Yu, Jiemiao, Liu, Huizhou
• Format: Journal Article
• Language: English
• Published: Elsevier Inc 01.08.2021
• Subjects: CO2 adsorption; H2 adsorption; Organic vapor capture; Polyaminal; Tetrapheyladamantane; Tetrapheyladamantane; H2 adsorption; CO2 adsorption; Organic vapor capture; Polyaminal

Herein, a new tetraphenyladamantane-cored triazine-based multiamine (TPADT) was designed and synthesized. Its bulky molecular volume, strong rigidity, and high amine functionality enable it easy to prop up the polymer backbone and form a high hypercrosslinking degree to obtain high microporosity. A...