Influence of the Mode of Water Coordination on the Electronic Structure of the [V(OH2)6]3+ Cation

• Published in: Journal of solid state chemistry Vol. 145; no. 2; pp. 460 - 470
• Main Authors: Tregenna-Piggott, Philip L.W., Best, Stephen P., Güdel, Hans U., Weihe, Høgni, Wilson, Chick C.
• Format: Journal Article
• Language: English
• Published: San Diego, CA Elsevier Inc 01.07.1999; Elsevier
• Subjects: Condensed matter: electronic structure, electrical, magnetic, and optical properties; Crystal and ligand fields; Electron density of states and band structure of crystalline solids; Electron states; Exact sciences and technology; Level splitting and interactions; Other inorganic compounds; Physics; Raman spectra; Inorganic compounds; Vanadium sulfates; ESR; Transition element compounds; Stereochemistry; Lattice vibrations; Experimental study; Gallium sulfates; Rubidium sulfates; Electronic structure; Ligand field; Absorption spectra; Hydrates

The correlation between the stereochemistry and electronic structure of the [V(OH2)6]3+] cation has been examined using a variety of physical techniques in conjunction with angular overlap model calculations. The experimental data includes the first reported high-field, high-frequency EPR study of a...