High-performance non-doped near ultraviolet OLEDs with the EQE ∼ 6 % and CIEy ∼ 0.03 from high-lying reverse intersystem crossing
•A near ultraviolet material mP2MPC is constructed based on the “coupling hardness with softness” design strategy.•The non-doped near ultraviolet organic light-emitting diode exhibits the CIE coordinates of (0.163, 0.028).•The forward-viewing EQE is 6.09 %, and keeps as high as 5.56 % at the practic...
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Published in | Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 450; p. 138339 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
15.12.2022
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Abstract | •A near ultraviolet material mP2MPC is constructed based on the “coupling hardness with softness” design strategy.•The non-doped near ultraviolet organic light-emitting diode exhibits the CIE coordinates of (0.163, 0.028).•The forward-viewing EQE is 6.09 %, and keeps as high as 5.56 % at the practical luminance of 1000 cd m−2.•The green and red phosphorescent devices with mP2MPC as host show the EQEs exceeding 21.5%.
Developing high-performance organic fluorophors with short-wavelength emission is both significant and challenging subject in the application of organic light-emitting diodes (OLEDs). In this work, we proposes a “coupling hardness with distortion” design concept to construct an efficient near ultraviolet (NUV) fluorophor mP2MPC with 1,4-dimethyl-2,5-diphenylbenzene as a rotatable bridge via the meta-positons linking rigid and bulky phenanthroimidazole and carbazole groups. As a result, the non-doped OLED with it as emitter not only exhibits an emission peak at 395 nm with the Commission Internationale de l’éclairage coordinates of (0.163, 0.028), but also realizes a high forward-viewing external quantum efficiency of 6.09 % due to the high-lying reverse intersystem crossing. The value still keeps as high as 5.56 % at 1000 cd m−2, showing a small efficiency roll-off. This is one of the highest efficiencies among the non-doped devices with the electroluminescence peak below 400 nm. Moreover, the green and red phosphorescent OLEDs with mP2MPC as host can also show excellent electroluminescence performance with the forward-viewing external quantum efficiencies over 21.5 %, illustrating that mP2MPC should be a prospective material for OLEDs. |
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AbstractList | •A near ultraviolet material mP2MPC is constructed based on the “coupling hardness with softness” design strategy.•The non-doped near ultraviolet organic light-emitting diode exhibits the CIE coordinates of (0.163, 0.028).•The forward-viewing EQE is 6.09 %, and keeps as high as 5.56 % at the practical luminance of 1000 cd m−2.•The green and red phosphorescent devices with mP2MPC as host show the EQEs exceeding 21.5%.
Developing high-performance organic fluorophors with short-wavelength emission is both significant and challenging subject in the application of organic light-emitting diodes (OLEDs). In this work, we proposes a “coupling hardness with distortion” design concept to construct an efficient near ultraviolet (NUV) fluorophor mP2MPC with 1,4-dimethyl-2,5-diphenylbenzene as a rotatable bridge via the meta-positons linking rigid and bulky phenanthroimidazole and carbazole groups. As a result, the non-doped OLED with it as emitter not only exhibits an emission peak at 395 nm with the Commission Internationale de l’éclairage coordinates of (0.163, 0.028), but also realizes a high forward-viewing external quantum efficiency of 6.09 % due to the high-lying reverse intersystem crossing. The value still keeps as high as 5.56 % at 1000 cd m−2, showing a small efficiency roll-off. This is one of the highest efficiencies among the non-doped devices with the electroluminescence peak below 400 nm. Moreover, the green and red phosphorescent OLEDs with mP2MPC as host can also show excellent electroluminescence performance with the forward-viewing external quantum efficiencies over 21.5 %, illustrating that mP2MPC should be a prospective material for OLEDs. |
ArticleNumber | 138339 |
Author | Huo, Yumiao Ma, Dongge Ying, Shian Yan, Shouke Peng, Ling Lv, Jichen Xiao, Shu Liu, Yuchao |
Author_xml | – sequence: 1 givenname: Ling surname: Peng fullname: Peng, Ling organization: Key Laboratory of Rubber-Plastics, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, PR China – sequence: 2 givenname: Jichen surname: Lv fullname: Lv, Jichen organization: Key Laboratory of Rubber-Plastics, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, PR China – sequence: 3 givenname: Shu surname: Xiao fullname: Xiao, Shu organization: Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, PR China – sequence: 4 givenname: Yumiao surname: Huo fullname: Huo, Yumiao organization: Key Laboratory of Rubber-Plastics, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, PR China – sequence: 5 givenname: Yuchao surname: Liu fullname: Liu, Yuchao organization: Key Laboratory of Rubber-Plastics, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, PR China – sequence: 6 givenname: Dongge surname: Ma fullname: Ma, Dongge organization: Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, PR China – sequence: 7 givenname: Shian surname: Ying fullname: Ying, Shian email: shian0610@126.com organization: Key Laboratory of Rubber-Plastics, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, PR China – sequence: 8 givenname: Shouke surname: Yan fullname: Yan, Shouke email: skyan@mail.buct.edu.cn organization: Key Laboratory of Rubber-Plastics, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, PR China |
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