Bulk high-impact polystyrene process, 1 partitions of tert-butyl peroctoate and styrene in blends containing polystyrene and a rubber

In relation to the bulk high‐impact polystyrene process, this work investigates the partition between phases of styrene and an initiator: tert‐ butyl peroctoate. A Flory‐Huggins model was applied for predicting the phase separation point and the partitions of styrene and tert‐ butyl peroctoate. For...

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Published inMacromolecular theory and simulations Vol. 16; no. 7; pp. 703 - 710
Main Authors LUCIANI, Carla V, ESTENOZ, Diana A, MEIRA, Gregorio R, GARCIA, Nancy L, OLIVA, Haydée M
Format Journal Article
LanguageEnglish
Published Weinheim Wiley 25.09.2007
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Abstract In relation to the bulk high‐impact polystyrene process, this work investigates the partition between phases of styrene and an initiator: tert‐ butyl peroctoate. A Flory‐Huggins model was applied for predicting the phase separation point and the partitions of styrene and tert‐ butyl peroctoate. For blends of styrene, polystyrene, and a styrene‐butadiene diblock copolymer, the model provides reasonable predictions of a ternary equilibrium diagram. For blends of styrene, polystyrene, polybutadiene, and tert‐ butyl peroctoate, the partition of tert‐ butyl peroctoate was measured at 25 °C. At emulated conversions of 13% or lower, equilibrium was reached after 1 h of mixing time. For the higher molar masses and conversion of 16%, equilibrium was not reached after 24 h of mixing time. To fit the equilibrium measurements, the solubility parameter of tert‐ butyl peroctoate was adjusted. magnified image
AbstractList In relation to the bulk high‐impact polystyrene process, this work investigates the partition between phases of styrene and an initiator: tert‐ butyl peroctoate. A Flory‐Huggins model was applied for predicting the phase separation point and the partitions of styrene and tert‐ butyl peroctoate. For blends of styrene, polystyrene, and a styrene‐butadiene diblock copolymer, the model provides reasonable predictions of a ternary equilibrium diagram. For blends of styrene, polystyrene, polybutadiene, and tert‐ butyl peroctoate, the partition of tert‐ butyl peroctoate was measured at 25 °C. At emulated conversions of 13% or lower, equilibrium was reached after 1 h of mixing time. For the higher molar masses and conversion of 16%, equilibrium was not reached after 24 h of mixing time. To fit the equilibrium measurements, the solubility parameter of tert‐ butyl peroctoate was adjusted. magnified image
Author GARCIA, Nancy L
LUCIANI, Carla V
ESTENOZ, Diana A
MEIRA, Gregorio R
OLIVA, Haydée M
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Issue 7
Keywords partition coefficients
Partition coefficient
Experimental study
Modeling
high-impact polystyrène
Radical catalyst
Free radical polymerization
phase separation
High impact styrene polymer
Butadiene polymer
heterogeneous polymers
Perester
Styrene
tert-butyl peroctoate
Phase partition
Monomer
Language English
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SubjectTerms Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
Title Bulk high-impact polystyrene process, 1 partitions of tert-butyl peroctoate and styrene in blends containing polystyrene and a rubber
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