Stereochemistry of β-diketone complexes of cobalt(III). XI. Synthesis and properties of some cyano bis(acetylacetonato)cobalt(III) complexes

K {cis[Co acac 2CN) 2]}, [PPh 4]{cis[Co acac 2(CN 2]}, trans and cis[Co acac 2py(CN)] have been synthesized and characterized. The complex cis[Co acac 2(CN) 2] − does not show any isomerization or solvolysis in chloroform or dimethylsulfoxide or water. The complexes cis and trans[Co acac 2py(CN)] ca...

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Published inInorganica Chimica Acta Vol. 11; pp. 123 - 126
Main Authors Boucher, L.J., Coe, C.G., Herrington, D.R.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1974
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Abstract K {cis[Co acac 2CN) 2]}, [PPh 4]{cis[Co acac 2(CN 2]}, trans and cis[Co acac 2py(CN)] have been synthesized and characterized. The complex cis[Co acac 2(CN) 2] − does not show any isomerization or solvolysis in chloroform or dimethylsulfoxide or water. The complexes cis and trans[Co acac 2py(CN)] cannot be interconverted in refluxing chloroform or benzene. Although no isomerization is noted in dimethylsulfoxide solution for either isomer, the trans isomer does undergo solvolysis with partial loss of pyridine.
AbstractList K {cis[Co acac 2CN) 2]}, [PPh 4]{cis[Co acac 2(CN 2]}, trans and cis[Co acac 2py(CN)] have been synthesized and characterized. The complex cis[Co acac 2(CN) 2] − does not show any isomerization or solvolysis in chloroform or dimethylsulfoxide or water. The complexes cis and trans[Co acac 2py(CN)] cannot be interconverted in refluxing chloroform or benzene. Although no isomerization is noted in dimethylsulfoxide solution for either isomer, the trans isomer does undergo solvolysis with partial loss of pyridine.
Author Boucher, L.J.
Herrington, D.R.
Coe, C.G.
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CitedBy_id crossref_primary_10_1002_chin_197503394
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crossref_primary_10_1021_ic980970b
crossref_primary_10_1080_00945718808059508
crossref_primary_10_1246_bcsj_55_149
crossref_primary_10_1246_bcsj_57_3580
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10.1021/ic50114a008
10.1039/c39720000923
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10.1021/ic50033a011
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Title Stereochemistry of β-diketone complexes of cobalt(III). XI. Synthesis and properties of some cyano bis(acetylacetonato)cobalt(III) complexes
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