Catalyzed substitutions on cationic palladium(II) complexes. III. Mercury(II) catalyzed displacement of coordinated thiocyanate and selenocyanate linkage isomers

A kinetic study of Hg 2+ catalyzed solvolysis of linkage isomers [Pd(AAA)XCN/NCX] + (AAA = 1,1,7,7-tetraethyldiethylenetriamine (Et 4dien) and 4-methyl-1,1,7,7-tetraethydiethylenetriamine (MeEt 4dien); X = S, Se) has been carried out in methanol at 25 °C. The kinetic results show that the catalytic...

Full description

Saved in:
Bibliographic Details
Published inInorganica Chimica Acta Vol. 30; pp. 29 - 34
Main Authors Cusumano, M., Guglielmo, G., Marricchi, P., Ricevuto, V.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1978
Online AccessGet full text

Cover

Abstract A kinetic study of Hg 2+ catalyzed solvolysis of linkage isomers [Pd(AAA)XCN/NCX] + (AAA = 1,1,7,7-tetraethyldiethylenetriamine (Et 4dien) and 4-methyl-1,1,7,7-tetraethydiethylenetriamine (MeEt 4dien); X = S, Se) has been carried out in methanol at 25 °C. The kinetic results show that the catalytic efficiency of mercury(II) in removing the thiocyanate or selenocyanate ligands is greater in the PdXCN substrates than in the PdNCX ones, depending on whether the sulfur or selenium atom on which the attack by Hg 2+ takes place, is bonded directly to palladium(II). The kinetic data for the isomerization and substitution reactions are also reported.
AbstractList A kinetic study of Hg 2+ catalyzed solvolysis of linkage isomers [Pd(AAA)XCN/NCX] + (AAA = 1,1,7,7-tetraethyldiethylenetriamine (Et 4dien) and 4-methyl-1,1,7,7-tetraethydiethylenetriamine (MeEt 4dien); X = S, Se) has been carried out in methanol at 25 °C. The kinetic results show that the catalytic efficiency of mercury(II) in removing the thiocyanate or selenocyanate ligands is greater in the PdXCN substrates than in the PdNCX ones, depending on whether the sulfur or selenium atom on which the attack by Hg 2+ takes place, is bonded directly to palladium(II). The kinetic data for the isomerization and substitution reactions are also reported.
Author Guglielmo, G.
Cusumano, M.
Ricevuto, V.
Marricchi, P.
Author_xml – sequence: 1
  givenname: M.
  surname: Cusumano
  fullname: Cusumano, M.
– sequence: 2
  givenname: G.
  surname: Guglielmo
  fullname: Guglielmo, G.
– sequence: 3
  givenname: P.
  surname: Marricchi
  fullname: Marricchi, P.
– sequence: 4
  givenname: V.
  surname: Ricevuto
  fullname: Ricevuto, V.
  organization: Istituto di Chimica Generale, Università di Messina, 98100 Messina, Italy
BookMark eNqFkMtOwzAQRS0EEm3hE5C8bBcpdty47gqhikekIhbA2nLsCRgSu7JdRPgb_pSmRd2ymue9MzpDdOy8A4QuKJlSQvnlEyE5yShfsDEhE7EglGbiCA2omLOM5UVxjAaHlVM0jPGdEEY4KwboZ6mSarpvMDhuqphs2iTrXcTeYa361Gq8Vk2jjN2047KcYO3bdQNfEKe4LMspfoCgN6Hbzw5uxsZ1ozS04BL29Vblg7FOpe0svVmvO9UXWLntZWjAHTqNdR_qFbCNvoUQz9BJrZoI539xhF5ub56X99nq8a5cXq8yned5yoDPaFEUxrB6XoucAV9oYsy84pobxpVWlahqQ7nITS3Eghd8xoFpYTivKBNshIq9rw4-xgC1XAfbqtBJSmTPWe44yx6iJETuOMted7XXwfa5TwtBRm3BaTA2gE7SePuPwy8n9IrY
CitedBy_id crossref_primary_10_1002_chin_197850321
crossref_primary_10_1007_BF01022335
crossref_primary_10_1007_s11243_014_9805_1
crossref_primary_10_1016_j_poly_2012_12_009
crossref_primary_10_1021_ic000320j
crossref_primary_10_1016_0010_8545_85_80033_3
Cites_doi 10.1021/ja00965a013
10.1021/ic50063a019
10.1021/ja00959a063
10.1021/ic50056a011
10.1021/ic50119a030
10.1021/ja01029a009
10.1021/ic50038a041
10.1021/ic50029a044
10.1016/S0020-1693(00)81955-6
10.1021/ic50096a001
10.1039/J19670001884
10.1016/S0020-1693(00)85734-5
10.1016/S0020-1693(00)85697-2
10.1016/S0020-1693(00)89877-1
10.1016/S0020-1693(00)91702-X
10.1021/ja01018a017
10.1021/ic50063a014
10.1021/ic50087a003
10.1021/ic50047a013
10.1021/ic50115a022
10.1021/ic50086a008
10.1016/S0010-8545(00)80009-0
ContentType Journal Article
Copyright 1978
Copyright_xml – notice: 1978
DBID AAYXX
CITATION
DOI 10.1016/S0020-1693(00)89011-8
DatabaseName CrossRef
DatabaseTitle CrossRef
DatabaseTitleList
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1873-3255
EndPage 34
ExternalDocumentID 10_1016_S0020_1693_00_89011_8
S0020169300890118
GroupedDBID AAYXX
CITATION
ID FETCH-LOGICAL-c222t-e641555dd3f7f823e69c0dd7b6c6d36acab8bfd1682df88965646e3c8d66b1383
ISSN 0020-1693
IngestDate Fri Aug 23 02:47:55 EDT 2024
Thu Aug 18 14:38:49 EDT 2022
IsPeerReviewed true
IsScholarly true
Language English
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-c222t-e641555dd3f7f823e69c0dd7b6c6d36acab8bfd1682df88965646e3c8d66b1383
PageCount 6
ParticipantIDs crossref_primary_10_1016_S0020_1693_00_89011_8
elsevier_sciencedirect_doi_10_1016_S0020_1693_00_89011_8
PublicationCentury 1900
PublicationDate 1978
1978-1-00
PublicationDateYYYYMMDD 1978-01-01
PublicationDate_xml – year: 1978
  text: 1978
PublicationDecade 1970
PublicationTitle Inorganica Chimica Acta
PublicationYear 1978
Publisher Elsevier B.V
Publisher_xml – name: Elsevier B.V
References Roulet, Gray (BIB23) 1972; 11
Cusumano, Guglielmo, Ricevuto, Romeo, Trozzi (BIB8) 1976; 17
Burmeister, Gysling, Lim (BIB11) 1969; 91
Burmeister, Lim (BIB16) 1968
Orhanovic, Sutin (BIB20) 1968; 90
Buckingam, Olsen, Sargeson (BIB6) 1967; 6
Burmeister, Gysling (BIB12) 1967
Hewkin, Pëo (BIB15) 1967
Johnson, Lim, Burmeister (BIB22) 1973; 12
Espenson, Hubbard (BIB2) 1966; 5
Geary (BIB17) 1971; 7
Singh, Khan (BIB21) 1975; 14
Birk (BIB4) 1970; 9
Palmer, Kelm (BIB25) 1975; 14
Cusumano, Guglielmo, Ricevuto, Romeo, Trozzi (BIB9) 1976; 16
Dolbear, Taube (BIB7) 1967; 6
Burmeister, Haasel, Johnson, Lim (BIB14) 1974; 9
Goddard, Basolo (BIB24) 1968; 7
Candlin, Halpern (BIB1) 1965; 4
Falk, Linck (BIB5) 1971; 10
Basolo, Baddley, Weldenbaum (BIB10) 1966; 88
Baddley, Basolo (BIB13) 1966; 88
Bifano, Linck (BIB3) 1968; 7
Coleman, P. Varga, Mastin (BIB19) 1970; 9
Goddard, Basolo (BIB18) 1968; 7
Orhanovic (10.1016/S0020-1693(00)89011-8_BIB20) 1968; 90
Hewkin (10.1016/S0020-1693(00)89011-8_BIB15) 1967
Falk (10.1016/S0020-1693(00)89011-8_BIB5) 1971; 10
Burmeister (10.1016/S0020-1693(00)89011-8_BIB12) 1967
Burmeister (10.1016/S0020-1693(00)89011-8_BIB14) 1974; 9
Roulet (10.1016/S0020-1693(00)89011-8_BIB23) 1972; 11
Burmeister (10.1016/S0020-1693(00)89011-8_BIB11) 1969; 91
Dolbear (10.1016/S0020-1693(00)89011-8_BIB7) 1967; 6
Buckingam (10.1016/S0020-1693(00)89011-8_BIB6) 1967; 6
Coleman (10.1016/S0020-1693(00)89011-8_BIB19) 1970; 9
Bifano (10.1016/S0020-1693(00)89011-8_BIB3) 1968; 7
Goddard (10.1016/S0020-1693(00)89011-8_BIB24) 1968; 7
Cusumano (10.1016/S0020-1693(00)89011-8_BIB8) 1976; 17
Candlin (10.1016/S0020-1693(00)89011-8_BIB1) 1965; 4
Basolo (10.1016/S0020-1693(00)89011-8_BIB10) 1966; 88
Johnson (10.1016/S0020-1693(00)89011-8_BIB22) 1973; 12
Palmer (10.1016/S0020-1693(00)89011-8_BIB25) 1975; 14
Goddard (10.1016/S0020-1693(00)89011-8_BIB18) 1968; 7
Espenson (10.1016/S0020-1693(00)89011-8_BIB2) 1966; 5
Birk (10.1016/S0020-1693(00)89011-8_BIB4) 1970; 9
Singh (10.1016/S0020-1693(00)89011-8_BIB21) 1975; 14
Baddley (10.1016/S0020-1693(00)89011-8_BIB13) 1966; 88
Geary (10.1016/S0020-1693(00)89011-8_BIB17) 1971; 7
Cusumano (10.1016/S0020-1693(00)89011-8_BIB9) 1976; 16
Burmeister (10.1016/S0020-1693(00)89011-8_BIB16) 1968
References_xml – start-page: 543
  year: 1967
  ident: BIB12
  publication-title: Chem. Comm.
  contributor:
    fullname: Gysling
– volume: 88
  start-page: 2944
  year: 1966
  ident: BIB13
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Basolo
– volume: 7
  start-page: 2457
  year: 1968
  ident: BIB24
  publication-title: Inorg. Chem.
  contributor:
    fullname: Basolo
– volume: 9
  start-page: 23
  year: 1974
  ident: BIB14
  publication-title: Inorg. Chim. Acta
  contributor:
    fullname: Lim
– volume: 5
  start-page: 686
  year: 1966
  ident: BIB2
  publication-title: Inorg. Chem.
  contributor:
    fullname: Hubbard
– volume: 10
  start-page: 215
  year: 1971
  ident: BIB5
  publication-title: Inorg. Chem.
  contributor:
    fullname: Linck
– volume: 4
  start-page: 1086
  year: 1965
  ident: BIB1
  publication-title: Inorg. Chem.
  contributor:
    fullname: Halpern
– start-page: 1884
  year: 1967
  ident: BIB15
  publication-title: J. Chem. Soc. A
  contributor:
    fullname: Pëo
– volume: 17
  start-page: 45
  year: 1976
  ident: BIB8
  publication-title: Inorg. Chim. Acta
  contributor:
    fullname: Trozzi
– volume: 7
  start-page: 908
  year: 1968
  ident: BIB3
  publication-title: Inorg. Chem.
  contributor:
    fullname: Linck
– volume: 90
  start-page: 4286
  year: 1968
  ident: BIB20
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Sutin
– volume: 14
  start-page: 143
  year: 1975
  ident: BIB21
  publication-title: Inorg. Chim. Acta
  contributor:
    fullname: Khan
– volume: 16
  start-page: 135
  year: 1976
  ident: BIB9
  publication-title: Inorg. Chim. Acta
  contributor:
    fullname: Trozzi
– volume: 6
  start-page: 60
  year: 1967
  ident: BIB7
  publication-title: Inorg. Chem.
  contributor:
    fullname: Taube
– volume: 91
  start-page: 44
  year: 1969
  ident: BIB11
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Lim
– volume: 14
  start-page: L27
  year: 1975
  ident: BIB25
  publication-title: Inorg. Chim. Acta
  contributor:
    fullname: Kelm
– volume: 9
  start-page: 1015
  year: 1970
  ident: BIB19
  publication-title: Inorg. Chem.
  contributor:
    fullname: Mastin
– volume: 9
  start-page: 735
  year: 1970
  ident: BIB4
  publication-title: Inorg. Chem.
  contributor:
    fullname: Birk
– volume: 6
  start-page: 1807
  year: 1967
  ident: BIB6
  publication-title: Inorg. Chem.
  contributor:
    fullname: Sargeson
– volume: 7
  start-page: 936
  year: 1968
  ident: BIB18
  publication-title: Inorg. Chem.
  contributor:
    fullname: Basolo
– volume: 12
  start-page: 124
  year: 1973
  ident: BIB22
  publication-title: Inorg. Chem.
  contributor:
    fullname: Burmeister
– start-page: 1346
  year: 1968
  ident: BIB16
  publication-title: Chem. Comm.
  contributor:
    fullname: Lim
– volume: 88
  start-page: 576
  year: 1966
  ident: BIB10
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Weldenbaum
– volume: 11
  start-page: 2101
  year: 1972
  ident: BIB23
  publication-title: Inorg. Chem.
  contributor:
    fullname: Gray
– volume: 7
  start-page: 81
  year: 1971
  ident: BIB17
  publication-title: Coordination Chem. Rev.
  contributor:
    fullname: Geary
– volume: 88
  start-page: 2944
  year: 1966
  ident: 10.1016/S0020-1693(00)89011-8_BIB13
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00965a013
  contributor:
    fullname: Baddley
– volume: 7
  start-page: 936
  year: 1968
  ident: 10.1016/S0020-1693(00)89011-8_BIB18
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50063a019
  contributor:
    fullname: Goddard
– volume: 88
  start-page: 576
  year: 1966
  ident: 10.1016/S0020-1693(00)89011-8_BIB10
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00959a063
  contributor:
    fullname: Basolo
– volume: 6
  start-page: 1807
  year: 1967
  ident: 10.1016/S0020-1693(00)89011-8_BIB6
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50056a011
  contributor:
    fullname: Buckingam
– volume: 12
  start-page: 124
  year: 1973
  ident: 10.1016/S0020-1693(00)89011-8_BIB22
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50119a030
  contributor:
    fullname: Johnson
– volume: 91
  start-page: 44
  year: 1969
  ident: 10.1016/S0020-1693(00)89011-8_BIB11
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja01029a009
  contributor:
    fullname: Burmeister
– volume: 5
  start-page: 686
  year: 1966
  ident: 10.1016/S0020-1693(00)89011-8_BIB2
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50038a041
  contributor:
    fullname: Espenson
– start-page: 543
  year: 1967
  ident: 10.1016/S0020-1693(00)89011-8_BIB12
  publication-title: Chem. Comm.
  contributor:
    fullname: Burmeister
– volume: 7
  start-page: 2457
  year: 1968
  ident: 10.1016/S0020-1693(00)89011-8_BIB24
  publication-title: Inorg. Chem.
  contributor:
    fullname: Goddard
– volume: 4
  start-page: 1086
  year: 1965
  ident: 10.1016/S0020-1693(00)89011-8_BIB1
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50029a044
  contributor:
    fullname: Candlin
– volume: 17
  start-page: 45
  year: 1976
  ident: 10.1016/S0020-1693(00)89011-8_BIB8
  publication-title: Inorg. Chim. Acta
  doi: 10.1016/S0020-1693(00)81955-6
  contributor:
    fullname: Cusumano
– volume: 10
  start-page: 215
  year: 1971
  ident: 10.1016/S0020-1693(00)89011-8_BIB5
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50096a001
  contributor:
    fullname: Falk
– start-page: 1884
  year: 1967
  ident: 10.1016/S0020-1693(00)89011-8_BIB15
  publication-title: J. Chem. Soc. A
  doi: 10.1039/J19670001884
  contributor:
    fullname: Hewkin
– volume: 14
  start-page: 143
  year: 1975
  ident: 10.1016/S0020-1693(00)89011-8_BIB21
  publication-title: Inorg. Chim. Acta
  doi: 10.1016/S0020-1693(00)85734-5
  contributor:
    fullname: Singh
– volume: 14
  start-page: L27
  year: 1975
  ident: 10.1016/S0020-1693(00)89011-8_BIB25
  publication-title: Inorg. Chim. Acta
  doi: 10.1016/S0020-1693(00)85697-2
  contributor:
    fullname: Palmer
– volume: 9
  start-page: 23
  year: 1974
  ident: 10.1016/S0020-1693(00)89011-8_BIB14
  publication-title: Inorg. Chim. Acta
  doi: 10.1016/S0020-1693(00)89877-1
  contributor:
    fullname: Burmeister
– volume: 16
  start-page: 135
  year: 1976
  ident: 10.1016/S0020-1693(00)89011-8_BIB9
  publication-title: Inorg. Chim. Acta
  doi: 10.1016/S0020-1693(00)91702-X
  contributor:
    fullname: Cusumano
– volume: 90
  start-page: 4286
  year: 1968
  ident: 10.1016/S0020-1693(00)89011-8_BIB20
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja01018a017
  contributor:
    fullname: Orhanovic
– volume: 7
  start-page: 908
  year: 1968
  ident: 10.1016/S0020-1693(00)89011-8_BIB3
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50063a014
  contributor:
    fullname: Bifano
– volume: 9
  start-page: 1015
  year: 1970
  ident: 10.1016/S0020-1693(00)89011-8_BIB19
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50087a003
  contributor:
    fullname: Coleman
– volume: 6
  start-page: 60
  year: 1967
  ident: 10.1016/S0020-1693(00)89011-8_BIB7
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50047a013
  contributor:
    fullname: Dolbear
– volume: 11
  start-page: 2101
  year: 1972
  ident: 10.1016/S0020-1693(00)89011-8_BIB23
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50115a022
  contributor:
    fullname: Roulet
– start-page: 1346
  year: 1968
  ident: 10.1016/S0020-1693(00)89011-8_BIB16
  publication-title: Chem. Comm.
  contributor:
    fullname: Burmeister
– volume: 9
  start-page: 735
  year: 1970
  ident: 10.1016/S0020-1693(00)89011-8_BIB4
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50086a008
  contributor:
    fullname: Birk
– volume: 7
  start-page: 81
  year: 1971
  ident: 10.1016/S0020-1693(00)89011-8_BIB17
  publication-title: Coordination Chem. Rev.
  doi: 10.1016/S0010-8545(00)80009-0
  contributor:
    fullname: Geary
SSID ssj0030635
ssj0000182
Score 1.2560984
Snippet A kinetic study of Hg 2+ catalyzed solvolysis of linkage isomers [Pd(AAA)XCN/NCX] + (AAA = 1,1,7,7-tetraethyldiethylenetriamine (Et 4dien) and...
SourceID crossref
elsevier
SourceType Aggregation Database
Publisher
StartPage 29
Title Catalyzed substitutions on cationic palladium(II) complexes. III. Mercury(II) catalyzed displacement of coordinated thiocyanate and selenocyanate linkage isomers
URI https://dx.doi.org/10.1016/S0020-1693(00)89011-8
Volume 30
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9QwELaW7QEuiKcoL_nAoVWUJe91jqsV0FAtQqWF3qLEdtRINKm6WUT7b_gl_DVmbMdJ1QpBL1F24thS5lt73kPIG16VTJR-6iYV6KpRITyXSR66cSxhK4QTJ1DV9Vefkr2j6ONxfDyZ_B5FLW26csYvb8wruQ1XgQZ8xSzZ_-CsnRQIcA_8hStwGK7_xOMl2l4uLkFmXMP_Xzn9dVxb42hLXM2dM7SUixrbGbMsQyOAiiKXP0FDdrIsmzkrec6VN71_bmcV9VrFbPUBA7wFVbVuCpRSu5O65RcF_lAOCOza1FgK-oUxGqhet6cmxr4XgbNGd5LiBcaBYLUCZ8G7IWBos0a_grLgrmY2PAjE_Fp-P1XkD5a8KtCAyVVjYuezJR_A7vdjoxpEOV9ng2HDT3UjH21nu5ZrY_IOPBdLx-iTS2_XbB66YaAL_fb7ufHzmA05HR3t2mx67dDQ9osvdgH43tghO2WYluuy4aS08YtqLA4FCUrl7t4hWwHsdPGUbC32D77tjyqYMVvODLQz3fC1X2jIKHs7rL7jebtm5ZtlpZH8c_iA3DeKC11oFD4kE9k8IneXfb_Ax-SXRSO9gkbaNrRHI7Vo3MmyXTogkSISqUGifmZnG6OQthUdoZCOUEgBhfQKCqlBITUofEKO3r87XO65pgGIy0Fs7VyZoLgbCxFW84oFoUxS7gkxLxOeiDApeFGyshJ-wgJRMZaCbhIlMuRMJEnphyx8SqZN28hnhM7LAos9pn4VsSgqwtL3ZJTGMNCreCjKbTLrP3V-puu85EMAJPAmR97knpcr3uRsm7CeIbkRVrUQmgOs_v7q89u_-oLc81VNbLQBviTT7nwjX4FU3JWvDfL-AKHptXk
link.rule.ids 315,783,787,4031,27935,27936,27937
linkProvider Library Specific Holdings
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Catalyzed+substitutions+on+cationic+palladium%28II%29+complexes.+III.+Mercury%28II%29+catalyzed+displacement+of+coordinated+thiocyanate+and+selenocyanate+linkage+isomers&rft.jtitle=Inorganica+Chimica+Acta&rft.au=Cusumano%2C+M.&rft.au=Guglielmo%2C+G.&rft.au=Marricchi%2C+P.&rft.au=Ricevuto%2C+V.&rft.date=1978&rft.pub=Elsevier+B.V&rft.issn=0020-1693&rft.eissn=1873-3255&rft.volume=30&rft.spage=29&rft.epage=34&rft_id=info:doi/10.1016%2FS0020-1693%2800%2989011-8&rft.externalDocID=S0020169300890118
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0020-1693&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0020-1693&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0020-1693&client=summon