Synthesis of dihydrocarvone over dendritic ZSM-5 Zeolite: A comprehensive study of experimental, kinetics, and computational insights

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 498; p. 155377
• Main Authors: Gallego-Villada, Luis A., Perez-Sena, Wander Y., Sánchez-Velandia, Julián E., Cueto, Jennifer, del Mar Alonso-Doncel, María, Wärmå, Johan, Mäki-Arvela, Päivi, Alarcón, Edwin A., Serrano, David P., Murzin, Dmitry Yu
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.10.2024
• Subjects: Dendritic zeolite; Density Functional Theory (DFT); Dihydrocarvone; Kinetic modeling; Limonene epoxide; ZSM-5; Dihydrocarvone; Dendritic zeolite; Limonene epoxide; Kinetic modeling; Density Functional Theory (DFT); ZSM-5

[Display omitted] •Kinetics and mechanism of limonene-1,2-epoxide isomerization.•Dendritic ZSM-5 zeolite is highly selective for formation of dihydrocarvone.•Kinetic modeling based on the reaction network with eight parallel reactions.•Adequate description of kinetics with statistically reliable par...