Innovative bio-based bamboo adhesive: Performance breakthrough through the host-guest interaction of cyclodextrin and adamantane
Recently, the use of agricultural, forestry, and fishery residues and wastes to develop green and environmentally friendly bio-based adhesives has gradually become the industry development trend and is an effective technical path to implement energy saving, environmental protection, and achieve sust...
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Published in | Colloids and surfaces. A, Physicochemical and engineering aspects Vol. 716; p. 136765 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
05.07.2025
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Subjects | |
Online Access | Get full text |
ISSN | 0927-7757 |
DOI | 10.1016/j.colsurfa.2025.136765 |
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Abstract | Recently, the use of agricultural, forestry, and fishery residues and wastes to develop green and environmentally friendly bio-based adhesives has gradually become the industry development trend and is an effective technical path to implement energy saving, environmental protection, and achieve sustainable development. The present work cleverly leverages the unique advantages of bio-based chitosan and 1-adamantane carboxylic acid to develop an innovative adamantane-chitosan bamboo adhesive through an amidation reaction. Meanwhile, sulfhydryl-functionalized cyclodextrins were prepared, and the cyclodextrin host molecules were successfully anchored to the bamboo surface through bridging 3-mercaptopropyltrimethoxysilane. During the bonding process, the adamantane guest molecules on the adhesive and the cyclodextrin host molecules on the bamboo surface were subject-guest recognized, resulting in the construction of a host-guest chemical bonding interface to achieve a breakthrough in bonding performance. The dry, hot, and boiling water strength of the bamboo bonded specimens without the formation of supramolecular bonding interface were 7.8, 6.4, and 4.9 MPa, respectively. After constructing the supramolecular bonding interface, the dry, hot, and boiling water strengths were enhanced by 37.2 %, 12.5 %, and 30.6 % to 10.7 MPa, 7.2 MPa, and 6.4 MPa, respectively. The results demonstrated that the host-guest recognition in the supramolecular bonding interface effectively enhanced the bonding performance. The present work utilizes biomass materials and supramolecular forces to achieve high-performance bonding of substrates, breaking the bonding performance enhancement mechanism of traditional adhesives and providing a new way for technological innovation in the field of bonding.
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•Host-guest recognition was applied to the bonding technology field.•Development of a supramolecular bonding interface (SBI).•Bonding performance realized breakthrough by constructing SBI.•The strategy of building SBI to enhance performance is universally applicable.•This work provides idea for the innovative development of bonding technology. |
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AbstractList | Recently, the use of agricultural, forestry, and fishery residues and wastes to develop green and environmentally friendly bio-based adhesives has gradually become the industry development trend and is an effective technical path to implement energy saving, environmental protection, and achieve sustainable development. The present work cleverly leverages the unique advantages of bio-based chitosan and 1-adamantane carboxylic acid to develop an innovative adamantane-chitosan bamboo adhesive through an amidation reaction. Meanwhile, sulfhydryl-functionalized cyclodextrins were prepared, and the cyclodextrin host molecules were successfully anchored to the bamboo surface through bridging 3-mercaptopropyltrimethoxysilane. During the bonding process, the adamantane guest molecules on the adhesive and the cyclodextrin host molecules on the bamboo surface were subject-guest recognized, resulting in the construction of a host-guest chemical bonding interface to achieve a breakthrough in bonding performance. The dry, hot, and boiling water strength of the bamboo bonded specimens without the formation of supramolecular bonding interface were 7.8, 6.4, and 4.9 MPa, respectively. After constructing the supramolecular bonding interface, the dry, hot, and boiling water strengths were enhanced by 37.2 %, 12.5 %, and 30.6 % to 10.7 MPa, 7.2 MPa, and 6.4 MPa, respectively. The results demonstrated that the host-guest recognition in the supramolecular bonding interface effectively enhanced the bonding performance. The present work utilizes biomass materials and supramolecular forces to achieve high-performance bonding of substrates, breaking the bonding performance enhancement mechanism of traditional adhesives and providing a new way for technological innovation in the field of bonding.
[Display omitted]
•Host-guest recognition was applied to the bonding technology field.•Development of a supramolecular bonding interface (SBI).•Bonding performance realized breakthrough by constructing SBI.•The strategy of building SBI to enhance performance is universally applicable.•This work provides idea for the innovative development of bonding technology. Recently, the use of agricultural, forestry, and fishery residues and wastes to develop green and environmentally friendly bio-based adhesives has gradually become the industry development trend and is an effective technical path to implement energy saving, environmental protection, and achieve sustainable development. The present work cleverly leverages the unique advantages of bio-based chitosan and 1-adamantane carboxylic acid to develop an innovative adamantane-chitosan bamboo adhesive through an amidation reaction. Meanwhile, sulfhydryl-functionalized cyclodextrins were prepared, and the cyclodextrin host molecules were successfully anchored to the bamboo surface through bridging 3-mercaptopropyltrimethoxysilane. During the bonding process, the adamantane guest molecules on the adhesive and the cyclodextrin host molecules on the bamboo surface were subject-guest recognized, resulting in the construction of a host-guest chemical bonding interface to achieve a breakthrough in bonding performance. The dry, hot, and boiling water strength of the bamboo bonded specimens without the formation of supramolecular bonding interface were 7.8, 6.4, and 4.9 MPa, respectively. After constructing the supramolecular bonding interface, the dry, hot, and boiling water strengths were enhanced by 37.2 %, 12.5 %, and 30.6 % to 10.7 MPa, 7.2 MPa, and 6.4 MPa, respectively. The results demonstrated that the host-guest recognition in the supramolecular bonding interface effectively enhanced the bonding performance. The present work utilizes biomass materials and supramolecular forces to achieve high-performance bonding of substrates, breaking the bonding performance enhancement mechanism of traditional adhesives and providing a new way for technological innovation in the field of bonding. |
ArticleNumber | 136765 |
Author | Liu, Tongda Li, Jun Lu, Tonghua Yang, Long Wei, Renzhong Liu, Rong Ran, Xin Xue, Weibing Zhao, Rui Du, Guanben |
Author_xml | – sequence: 1 givenname: Weibing surname: Xue fullname: Xue, Weibing organization: Yunnan Province Key Lab of Wood Adhesives and Glued Products, International Joint Research Center for Biomass Materials, School of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China – sequence: 2 givenname: Rui surname: Zhao fullname: Zhao, Rui organization: Yunnan Province Key Lab of Wood Adhesives and Glued Products, International Joint Research Center for Biomass Materials, School of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China – sequence: 3 givenname: Tongda surname: Liu fullname: Liu, Tongda email: tongdaliu@sufu.edu.cn organization: Yunnan Province Key Lab of Wood Adhesives and Glued Products, International Joint Research Center for Biomass Materials, School of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China – sequence: 4 givenname: Xin surname: Ran fullname: Ran, Xin organization: Yunnan Province Key Lab of Wood Adhesives and Glued Products, International Joint Research Center for Biomass Materials, School of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China – sequence: 5 givenname: Rong surname: Liu fullname: Liu, Rong organization: Yunnan Province Key Lab of Wood Adhesives and Glued Products, International Joint Research Center for Biomass Materials, School of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China – sequence: 6 givenname: Tonghua surname: Lu fullname: Lu, Tonghua organization: Treezo New Material Science and Technology Group Co., Ltd., Hangzhou, Zhejiang 311100, China – sequence: 7 givenname: Renzhong surname: Wei fullname: Wei, Renzhong organization: Treezo New Material Science and Technology Group Co., Ltd., Hangzhou, Zhejiang 311100, China – sequence: 8 givenname: Guanben surname: Du fullname: Du, Guanben organization: Yunnan Province Key Lab of Wood Adhesives and Glued Products, International Joint Research Center for Biomass Materials, School of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China – sequence: 9 givenname: Jun surname: Li fullname: Li, Jun email: lijun@swfu.edu.cn organization: Yunnan Province Key Lab of Wood Adhesives and Glued Products, International Joint Research Center for Biomass Materials, School of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China – sequence: 10 givenname: Long surname: Yang fullname: Yang, Long email: lyang@swfu.edu.cn organization: Yunnan Province Key Lab of Wood Adhesives and Glued Products, International Joint Research Center for Biomass Materials, School of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China |
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SubjectTerms | bamboos Bio-based adhesive biomass Bonding performance breakthrough carboxylic acids chitosan cyclodextrins energy environmental protection fisheries forestry Host-guest recognition Supramolecular bonding interface sustainable development technology |
Title | Innovative bio-based bamboo adhesive: Performance breakthrough through the host-guest interaction of cyclodextrin and adamantane |
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