Architecture of framework copper(I) halide π-complexes with N-allyl-N,N,N′,N′-tetramethyl-ethylenediaminium and N,N′-diallyl-N,N,N′,N′-tetramethylethylenediaminium: Synthesis and crystal structure of [{C2H4N2(H+)×(CH3)4(C3H5)} Cu4Cl6] and [{C2H4N2(CH3)4(C3H5)2}0.5Cu2Cl1.67Br1.33]

• Published in: Journal of structural chemistry Vol. 53; no. 1; pp. 119 - 124
• Main Authors: Monchak, M. M., Goreshnik, E. A., Mys’kiv, M. G.
• Format: Journal Article
• Language: English
• Published: Dordrecht SP MAIK Nauka/Interperiodica 01.02.2012
• Subjects: Atomic; Atomic/Molecular Structure and Spectra; Chemistry; Chemistry and Materials Science; Inorganic Chemistry; Molecular; Optical and Plasma Physics; Physical Chemistry; Solid State Physics; allyl derivatives of N,N,N′,N′-tetramethylethylenediamine; copper halide fragments; crystal structure; π-complexes; copper(I)

N,N,N′,N′-tetramethylethylenediamine is obtained by the reaction of ethylenediamine with formaldehyde and formic acid (the Eschweiler-Clarke reaction) and then alkylated with allyl chloride (or bromide) in a ratio of 1:1 or 1:2 to obtain N-allyl-N,N,N′,N′-tetramethylethylenediaminium and N,N′-dially...