Adsorptive abatement of Pb2+ and crystal violet using chitosan-modified coal nanocomposites: A down flow column study

Every moment huge amounts of industrial wastewater are contaminating our surface/groundwater sources by discharging into the environment directly. This crude wastewater is the most problematic subject because it is the matrix of hazardous toxicants, which can drastically damage public health-safety....

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Published inGroundwater for sustainable development Vol. 23; p. 101028
Main Authors Rahman, Md Mahmudur, Maniruzzaman, Mohd, Yeasmin, Mst Sarmina, Gafur, Md Abdul, Shaikh, Md Aftab Ali, Alam, Md Ashraful, Uddin, Md Jasim, Hasan, Mehedi, Bashera, Mahci Al, Chowdhury, Tahmina Akter, Maitra, Bijoy, Naim, Mustafizur Rahman, Rana, G.M. Masud, Saha, Barun Kanti, Quddus, Md Saiful
Format Journal Article
LanguageEnglish
Published 01.11.2023
Subjects
adsorbents
adsorption
class
coal
environmental protection
gentian violet
groundwater
industrial wastewater
industrial wastewater treatment
nanocomposites
reaction kinetics
sorption isotherms
sustainable development
toxic substances
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Abstract Every moment huge amounts of industrial wastewater are contaminating our surface/groundwater sources by discharging into the environment directly. This crude wastewater is the most problematic subject because it is the matrix of hazardous toxicants, which can drastically damage public health-safety. So, it is urgent to purify before discharging/reusing. This study focused on the recent improvement and latent implication of Activated Chitosan-Modified Coal(ACMC) bionanocomposite filter. Here, we briefly described how ACMC was produced and its potential application in the removal of Pb²⁺ and Crystal Violet (CV) effectively from wastewater. However, the influence of different parameters like initial concentration (20–40 ppm), volumetric flow rate (4–6 mL/min) and bed height (0.4–1.0 cm) were investigated appropriately meanwhile the adsorbent amount was (1.0–2.0 g). The adsorption efficiency and removal percent were strongly correlated with inlet concentration, flow rate, and bed height. The highest removal capacity and percentage were found nearly (243.08 and 238.51)mg/g additionally (78.48 and 82.50)% for Pb²⁺ and CV. Finally, three well-known column adsorption models namely Thomas, Yoon-Nelson and Adam-Bohart model were applied for the fitting of experimental data which exhibited a decent agreement with all three models that are also suitable for the description of breakthrough curve (BTC) and supports the Langmuir isotherm by following second-order reversible reaction kinetics. Thus this new class of ACMC nanoadsorbents could be beneficially used for the real-time bulk scale industrial wastewater treatment as a suitable replacement of hazardous fossil-based synthetic ones for sustainable environmental protection.
AbstractList Every moment huge amounts of industrial wastewater are contaminating our surface/groundwater sources by discharging into the environment directly. This crude wastewater is the most problematic subject because it is the matrix of hazardous toxicants, which can drastically damage public health-safety. So, it is urgent to purify before discharging/reusing. This study focused on the recent improvement and latent implication of Activated Chitosan-Modified Coal(ACMC) bionanocomposite filter. Here, we briefly described how ACMC was produced and its potential application in the removal of Pb²⁺ and Crystal Violet (CV) effectively from wastewater. However, the influence of different parameters like initial concentration (20–40 ppm), volumetric flow rate (4–6 mL/min) and bed height (0.4–1.0 cm) were investigated appropriately meanwhile the adsorbent amount was (1.0–2.0 g). The adsorption efficiency and removal percent were strongly correlated with inlet concentration, flow rate, and bed height. The highest removal capacity and percentage were found nearly (243.08 and 238.51)mg/g additionally (78.48 and 82.50)% for Pb²⁺ and CV. Finally, three well-known column adsorption models namely Thomas, Yoon-Nelson and Adam-Bohart model were applied for the fitting of experimental data which exhibited a decent agreement with all three models that are also suitable for the description of breakthrough curve (BTC) and supports the Langmuir isotherm by following second-order reversible reaction kinetics. Thus this new class of ACMC nanoadsorbents could be beneficially used for the real-time bulk scale industrial wastewater treatment as a suitable replacement of hazardous fossil-based synthetic ones for sustainable environmental protection.
ArticleNumber 101028
Author Shaikh, Md Aftab Ali
Bashera, Mahci Al
Chowdhury, Tahmina Akter
Maitra, Bijoy
Naim, Mustafizur Rahman
Maniruzzaman, Mohd
Hasan, Mehedi
Alam, Md Ashraful
Rahman, Md Mahmudur
Gafur, Md Abdul
Uddin, Md Jasim
Rana, G.M. Masud
Saha, Barun Kanti
Yeasmin, Mst Sarmina
Quddus, Md Saiful
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Snippet Every moment huge amounts of industrial wastewater are contaminating our surface/groundwater sources by discharging into the environment directly. This crude...
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StartPage 101028
SubjectTerms adsorbents
adsorption
class
coal
environmental protection
gentian violet
groundwater
industrial wastewater
industrial wastewater treatment
nanocomposites
reaction kinetics
sorption isotherms
sustainable development
toxic substances
Title Adsorptive abatement of Pb2+ and crystal violet using chitosan-modified coal nanocomposites: A down flow column study
URI https://www.proquest.com/docview/3154178259
Volume 23
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