The origin, composition, and applications of industrial humins - a review

Humins are side-products derived from the acid-catalysed conversion of carbohydrate-containing biomass, including sugars ( e.g. glucose, fructose, sucrose), oligosaccharides, polysaccharides, and lignocellulosic feedstocks into hydroxymethylfurfural (HMF), furfural, and levulinic acid. Until recentl...

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Published inGreen chemistry : an international journal and green chemistry resource : GC Vol. 27; no. 12; pp. 3136 - 3166
Main Authors de Jong, Ed, Mascal, Mark, Constant, Sandra, Claessen, Tom, Tosi, Pierluigi, Mija, Alice
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 17.03.2025
Subjects
Carbohydrates
Composition
Furfural
Hydroxymethylfurfural
Levulinic acid
Lignocellulose
Oligosaccharides
Polysaccharides
Saccharides
Sucrose
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Abstract Humins are side-products derived from the acid-catalysed conversion of carbohydrate-containing biomass, including sugars ( e.g. glucose, fructose, sucrose), oligosaccharides, polysaccharides, and lignocellulosic feedstocks into hydroxymethylfurfural (HMF), furfural, and levulinic acid. Until recently, humins were primarily burned as a power and heat source, but now several higher value applications for humins are within reach. This review covers the history, state of the art, and future outlook on the subject of industrial humins, including their origin, production conditions, compositions, characterisation, and proposed structures. Current opinion on humin formation mechanisms, kinetic studies, ways to minimise their production, established valorisation routes, and novel applications are also discussed. Humins are side-products derived from the acid-catalysed conversion of carbohydrate-containing biomass, including sugars ( e.g. glucose, fructose, sucrose), oligo-, polysaccharides, and lignocellulosic feedstocks into HMF, furfural and levulinic acid.
AbstractList Humins are side-products derived from the acid-catalysed conversion of carbohydrate-containing biomass, including sugars (e.g. glucose, fructose, sucrose), oligosaccharides, polysaccharides, and lignocellulosic feedstocks into hydroxymethylfurfural (HMF), furfural, and levulinic acid. Until recently, humins were primarily burned as a power and heat source, but now several higher value applications for humins are within reach. This review covers the history, state of the art, and future outlook on the subject of industrial humins, including their origin, production conditions, compositions, characterisation, and proposed structures. Current opinion on humin formation mechanisms, kinetic studies, ways to minimise their production, established valorisation routes, and novel applications are also discussed.
Humins are side-products derived from the acid-catalysed conversion of carbohydrate-containing biomass, including sugars ( e.g. glucose, fructose, sucrose), oligosaccharides, polysaccharides, and lignocellulosic feedstocks into hydroxymethylfurfural (HMF), furfural, and levulinic acid. Until recently, humins were primarily burned as a power and heat source, but now several higher value applications for humins are within reach. This review covers the history, state of the art, and future outlook on the subject of industrial humins, including their origin, production conditions, compositions, characterisation, and proposed structures. Current opinion on humin formation mechanisms, kinetic studies, ways to minimise their production, established valorisation routes, and novel applications are also discussed. Humins are side-products derived from the acid-catalysed conversion of carbohydrate-containing biomass, including sugars ( e.g. glucose, fructose, sucrose), oligo-, polysaccharides, and lignocellulosic feedstocks into HMF, furfural and levulinic acid.
Author Claessen, Tom
Mascal, Mark
Constant, Sandra
Tosi, Pierluigi
Mija, Alice
de Jong, Ed
AuthorAffiliation Department of Chemistry
Université Côte d'Azur
Avantium Renewable Polymers B.V
Institut de Chimie de Nice
UMR CNRS 7272
University of California Davis
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Snippet Humins are side-products derived from the acid-catalysed conversion of carbohydrate-containing biomass, including sugars ( e.g. glucose, fructose, sucrose),...
Humins are side-products derived from the acid-catalysed conversion of carbohydrate-containing biomass, including sugars ( e.g. glucose, fructose, sucrose),...
Humins are side-products derived from the acid-catalysed conversion of carbohydrate-containing biomass, including sugars (e.g. glucose, fructose, sucrose),...
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SubjectTerms Carbohydrates
Composition
Furfural
Hydroxymethylfurfural
Levulinic acid
Lignocellulose
Oligosaccharides
Polysaccharides
Saccharides
Sucrose
Title The origin, composition, and applications of industrial humins - a review
URI https://www.proquest.com/docview/3177737065
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