A Zn II -Based Metal–Organic Framework with a Rare tcj Topology as a Turn-On Fluorescent Sensor for Acetylacetone

A Zn -based metal-organic framework (MOF) with a rare tcj topology has been solvothermally synthesized and displays relatively good thermal and chemical stabilities. Interestingly, the MOF can sensitively and selectively sense acetylacetone (acac) via a fluorescence enhancement effect with a detecti...

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Published inInorganic chemistry Vol. 58; no. 6; pp. 3578 - 3581
Main Authors Yao, Shu-Li, Liu, Sui-Jun, Tian, Xue-Mei, Zheng, Teng-Fei, Cao, Chen, Niu, Chun-Yuan, Chen, Yong-Qiang, Chen, Jing-Lin, Huang, Haiping, Wen, He-Rui
Format Journal Article
LanguageEnglish
Published United States 18.03.2019
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Summary:A Zn -based metal-organic framework (MOF) with a rare tcj topology has been solvothermally synthesized and displays relatively good thermal and chemical stabilities. Interestingly, the MOF can sensitively and selectively sense acetylacetone (acac) via a fluorescence enhancement effect with a detection limit of 0.10 ppm and good reusability, which demonstrates the first example of a MOF-based turn-on fluorescent sensor for acac.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.8b03316