Atmospheric chemistry of CF3C CH: Kinetics, products, mechanism of gas-phase reaction with OH radicals, and atmospheric implications-an effort for novel ‘class’ of refrigerant

• Published in: Atmospheric environment (1994) Vol. 294; p. 119467
• Main Authors: Zhang, Tongyun, Zhang, Chengping, Ma, Xiaoxun, Quan, Hengdao
• Format: Journal Article
• Language: English
• Published: 01.02.2023
• Subjects: atmospheric chemistry; carbon dioxide; density functional theory; environment; ozone; photochemistry

We use the relative method to first evaluate the atmospheric chemistry of CF₃CCH that would play significant role in novel refrigerant development. We show that rate constant (kOH) for the gas-phase reaction of CF₃CCH with OH radicals at 298 K is measured to be (2.15 ± 0.02) × 10⁻¹³ cm³ molecule⁻¹ s...