Atomically Dispersed Pentacoordinated‐Zirconium Catalyst with Axial Oxygen Ligand for Oxygen Reduction Reaction
Single‐atom catalysts (SACs), as promising alternatives to Pt‐based catalysts, suffer from the limited choice of center metals and low single‐atom loading. Here, we report a pentacoordinated Zr‐based SAC with nontrivial axial O ligands (denoted O−Zr−N−C) for oxygen reduction reaction (ORR). The O li...
Saved in:
| Published in | Angewandte Chemie Vol. 134; no. 36 |
|---|---|
| Main Authors | , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
Wiley Subscription Services, Inc
05.09.2022
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Single‐atom catalysts (SACs), as promising alternatives to Pt‐based catalysts, suffer from the limited choice of center metals and low single‐atom loading. Here, we report a pentacoordinated Zr‐based SAC with nontrivial axial O ligands (denoted O−Zr−N−C) for oxygen reduction reaction (ORR). The O ligand downshifts the d‐band center of Zr and confers Zr sites with stable local structure and proper adsorption capability for intermediates. Consequently, the ORR performance of O−Zr−N−C prominently surpasses that of commercial Pt/C, achieving a half‐wave potential of 0.91 V vs. reversible hydrogen electrode and outstanding durability (92 % current retention after 130‐hour operation). Moreover, the Zr site shows good resistance towards aggregation, enabling the synthesis of Zr‐based SAC with high loading (9.1 wt%). With the high‐loading catalyst, the zinc‐air battery (ZAB) delivers a record‐high power density of 324 mW cm−2 among those of SAC‐based ZABs.
The first Zr‐based single‐atom catalyst with a stable pentacoordinated structure and high single‐atom Zr loading is discovered. With the high‐loading catalyst, the assembled zinc–air battery delivers a record‐high power density among those of single‐atom catalyst‐based zinc–air batteries. |
|---|---|
| AbstractList | Single‐atom catalysts (SACs), as promising alternatives to Pt‐based catalysts, suffer from the limited choice of center metals and low single‐atom loading. Here, we report a pentacoordinated Zr‐based SAC with nontrivial axial O ligands (denoted O−Zr−N−C) for oxygen reduction reaction (ORR). The O ligand downshifts the d‐band center of Zr and confers Zr sites with stable local structure and proper adsorption capability for intermediates. Consequently, the ORR performance of O−Zr−N−C prominently surpasses that of commercial Pt/C, achieving a half‐wave potential of 0.91 V vs. reversible hydrogen electrode and outstanding durability (92 % current retention after 130‐hour operation). Moreover, the Zr site shows good resistance towards aggregation, enabling the synthesis of Zr‐based SAC with high loading (9.1 wt%). With the high‐loading catalyst, the zinc‐air battery (ZAB) delivers a record‐high power density of 324 mW cm−2 among those of SAC‐based ZABs.
The first Zr‐based single‐atom catalyst with a stable pentacoordinated structure and high single‐atom Zr loading is discovered. With the high‐loading catalyst, the assembled zinc–air battery delivers a record‐high power density among those of single‐atom catalyst‐based zinc–air batteries. Abstract Single‐atom catalysts (SACs), as promising alternatives to Pt‐based catalysts, suffer from the limited choice of center metals and low single‐atom loading. Here, we report a pentacoordinated Zr‐based SAC with nontrivial axial O ligands (denoted O−Zr−N−C) for oxygen reduction reaction (ORR). The O ligand downshifts the d‐band center of Zr and confers Zr sites with stable local structure and proper adsorption capability for intermediates. Consequently, the ORR performance of O−Zr−N−C prominently surpasses that of commercial Pt/C, achieving a half‐wave potential of 0.91 V vs. reversible hydrogen electrode and outstanding durability (92 % current retention after 130‐hour operation). Moreover, the Zr site shows good resistance towards aggregation, enabling the synthesis of Zr‐based SAC with high loading (9.1 wt%). With the high‐loading catalyst, the zinc‐air battery (ZAB) delivers a record‐high power density of 324 mW cm −2 among those of SAC‐based ZABs. Single‐atom catalysts (SACs), as promising alternatives to Pt‐based catalysts, suffer from the limited choice of center metals and low single‐atom loading. Here, we report a pentacoordinated Zr‐based SAC with nontrivial axial O ligands (denoted O−Zr−N−C) for oxygen reduction reaction (ORR). The O ligand downshifts the d‐band center of Zr and confers Zr sites with stable local structure and proper adsorption capability for intermediates. Consequently, the ORR performance of O−Zr−N−C prominently surpasses that of commercial Pt/C, achieving a half‐wave potential of 0.91 V vs. reversible hydrogen electrode and outstanding durability (92 % current retention after 130‐hour operation). Moreover, the Zr site shows good resistance towards aggregation, enabling the synthesis of Zr‐based SAC with high loading (9.1 wt%). With the high‐loading catalyst, the zinc‐air battery (ZAB) delivers a record‐high power density of 324 mW cm−2 among those of SAC‐based ZABs. |
| Author | Heine, Thomas Kuc, Agnieszka Liu, Yannan Qi, Haoyuan Li, Tao Feng, Xinliang An, Yun Yu, Minghao Wang, Xia Fang, Lingzhe Zhang, Jiaxu Liu, Lifeng |
| Author_xml | – sequence: 1 givenname: Xia surname: Wang fullname: Wang, Xia organization: Max-Planck-Institute for Chemical Physics of Solids – sequence: 2 givenname: Yun surname: An fullname: An, Yun organization: Helmholtz-Zentrum Dresden-Rossendorf – sequence: 3 givenname: Lifeng surname: Liu fullname: Liu, Lifeng organization: International Iberian Nanotechnology Laboratory (INL) – sequence: 4 givenname: Lingzhe surname: Fang fullname: Fang, Lingzhe organization: Northern Illinois University – sequence: 5 givenname: Yannan surname: Liu fullname: Liu, Yannan organization: Technische Universität Dresden – sequence: 6 givenname: Jiaxu surname: Zhang fullname: Zhang, Jiaxu organization: Technische Universität Dresden – sequence: 7 givenname: Haoyuan surname: Qi fullname: Qi, Haoyuan organization: University of Ulm – sequence: 8 givenname: Thomas surname: Heine fullname: Heine, Thomas organization: Yonsei University – sequence: 9 givenname: Tao surname: Li fullname: Li, Tao organization: Argonne National Laboratory – sequence: 10 givenname: Agnieszka orcidid: 0000-0002-9458-4136 surname: Kuc fullname: Kuc, Agnieszka email: a.kuc@hzdr.de organization: Helmholtz-Zentrum Dresden-Rossendorf – sequence: 11 givenname: Minghao orcidid: 0000-0002-0211-0778 surname: Yu fullname: Yu, Minghao email: minghao.yu@tu-dresden.de organization: Technische Universität Dresden – sequence: 12 givenname: Xinliang orcidid: 0000-0003-3885-2703 surname: Feng fullname: Feng, Xinliang email: xinliang.feng@tu-dresden.de organization: Max Planck Institute of Microstructure Physics |
| BookMark | eNqFkLtOwzAUhi1UJEphZY7EnGI7FztjVEpBqihCsLBYru0UV6nd2o7abDwCz8iTkFIuI9P5dfT95_Kfgp6xRgFwgeAQQYivuFmoIYYYw4Kk-RHoowyjOCEZ6YE-hGkaU5wWJ-DU-yWEMMek6INNGexKC17XbXSt_Vo5r2T0oEzgwlonteFByY-39xfthDW6WUUjHnjd-hBtdXiNyp3mdTTbtQtloqlecCOjyrqfzqOSjQja7hX_EmfguOK1V-ffdQCeb8ZPo9t4OpvcjcppLLof8jiTFOGE07TikhYCJggrqlBKJO1OF6LASmYS5UklZD6v6BwmuUIUyhSLQtIsGYDLw9y1s5tG-cCWtnGmW8kwgSSjOUFJRw0PlHDWe6cqtnZ6xV3LEGT7WNk-VvYba2coDoatrlX7D83K-8n4z_sJq7WAdA |
| CitedBy_id | crossref_primary_10_1002_advs_202403865 crossref_primary_10_1016_j_cej_2023_145129 crossref_primary_10_1002_adma_202312117 crossref_primary_10_1039_D3QM00096F crossref_primary_10_1002_adfm_202409064 |
| Cites_doi | 10.1021/jacs.9b09234 10.1021/jacs.9b11852 10.1002/ange.201702473 10.1021/acs.chemrev.5b00462 10.1038/s41467-019-09666-0 10.1002/anie.202012798 10.1002/smll.202001384 10.1016/0039-6028(89)90156-8 10.1038/s41560-019-0402-6 10.1021/jacs.1c09498 10.1002/anie.202105186 10.1021/jacs.8b07294 10.1038/s41560-021-00824-7 10.1039/C8EE02679C 10.1002/anie.201702473 10.1002/ange.201803262 10.1002/ange.202105186 10.1002/ange.201902109 10.1002/adma.201706216 10.1002/anie.202102053 10.1021/jacs.9b09352 10.1016/0169-4332(95)00032-1 10.1002/adma.202008752 10.1002/aenm.202101242 10.1021/ja3030565 10.1126/science.aaf9050 10.1038/s41563-019-0535-9 10.1002/anie.201803262 10.1002/adma.202008151 10.1073/pnas.1006652108 10.1038/376238a0 10.1002/ange.202102053 10.1038/s41467-020-16848-8 10.1038/s41563-020-0717-5 10.1021/jacs.8b13543 10.1038/s41467-019-09394-5 10.1021/cr9003902 10.1038/s41467-017-01100-7 10.1021/jacs.8b11129 10.1002/ange.202012798 10.1002/anie.201902109 10.1038/nmat3087 10.1038/s41557-021-00734-x |
| ContentType | Journal Article |
| Copyright | 2022 The Authors. Angewandte Chemie published by Wiley-VCH GmbH 2022. This article is published under http://creativecommons.org/licenses/by-nc-nd/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. |
| Copyright_xml | – notice: 2022 The Authors. Angewandte Chemie published by Wiley-VCH GmbH – notice: 2022. This article is published under http://creativecommons.org/licenses/by-nc-nd/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. |
| DBID | 24P WIN AAYXX CITATION 7SR 7U5 8BQ 8FD JG9 L7M |
| DOI | 10.1002/ange.202209746 |
| DatabaseName | Wiley-Blackwell Open Access Collection Wiley Free Archive CrossRef Engineered Materials Abstracts Solid State and Superconductivity Abstracts METADEX Technology Research Database Materials Research Database Advanced Technologies Database with Aerospace |
| DatabaseTitle | CrossRef Materials Research Database Engineered Materials Abstracts Solid State and Superconductivity Abstracts Technology Research Database Advanced Technologies Database with Aerospace METADEX |
| DatabaseTitleList | CrossRef Materials Research Database |
| Database_xml | – sequence: 1 dbid: 24P name: Wiley-Blackwell Open Access Collection url: https://authorservices.wiley.com/open-science/open-access/browse-journals.html sourceTypes: Publisher |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1521-3757 |
| EndPage | n/a |
| ExternalDocumentID | 10_1002_ange_202209746 ANGE202209746 |
| Genre | article |
| GrantInformation_xml | – fundername: Horizon 2020 funderid: GrapheneCore3 881603 – fundername: Deutsche Forschungsgemeinschaft funderid: CRC 1415, 417590517 – fundername: Sächsisches Staatsministerium für Wissenschaft und Kunst funderid: Sonderzuweisung zur Unterstützung profilbestimmender Struktureinheiten |
| GroupedDBID | -~X .3N .GA 05W 0R~ 10A 1L6 1OB 1OC 1ZS 24P 33P 3SF 3WU 4.4 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 5VS 66C 6P2 702 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHHS AANLZ AAONW AAXRX AAZKR ABCQN ABCUV ABDBF ABEML ABIJN ABJNI ABLJU ABPVW ACAHQ ACCFJ ACCUC ACCZN ACGFS ACIWK ACNCT ACPOU ACPRK ACSCC ACXBN ACXQS ADBBV ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN ADZOD AEEZP AEIGN AEIMD AEQDE AEUQT AEUYR AFBPY AFFPM AFGKR AFPWT AFRAH AHBTC AITYG AIURR AIWBW AJBDE AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALUQN AMBMR AMYDB ATUGU AUFTA AZBYB AZVAB BAFTC BFHJK BHBCM BMNLL BMXJE BNHUX BROTX BRXPI BY8 CS3 D-E D-F DCZOG DPXWK DR2 DRFUL DRSTM EBS F00 F01 F04 F5P G-S G.N GNP GODZA H.T H.X HGLYW HHY HHZ HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LITHE LOXES LP6 LP7 LUTES LYRES MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ O66 O9- OIG P2W P2X P4D Q.N Q11 QB0 QRW R.K RGC ROL RWI RX1 RYL SUPJJ TN5 TUS UB1 UPT V2E W8V W99 WBFHL WBKPD WIH WIK WIN WJL WOHZO WQJ WRC WXSBR WYISQ XG1 XV2 Y6R ZZTAW ~IA ~WT AAYXX CITATION 7SR 7U5 8BQ 8FD JG9 L7M |
| ID | FETCH-LOGICAL-c2026-5d8123a84fad89c0312e8e147d8062cc92ed5d163fcd6bf8b036e180d42c9d853 |
| IEDL.DBID | 24P |
| ISSN | 0044-8249 |
| IngestDate | Thu Oct 10 17:35:31 EDT 2024 Fri Aug 23 01:48:53 EDT 2024 Sat Aug 24 00:54:15 EDT 2024 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 36 |
| Language | English |
| License | Attribution-NonCommercial-NoDerivs |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c2026-5d8123a84fad89c0312e8e147d8062cc92ed5d163fcd6bf8b036e180d42c9d853 |
| Notes | These authors contributed equally to this work. |
| ORCID | 0000-0002-0211-0778 0000-0003-3885-2703 0000-0002-9458-4136 |
| OpenAccessLink | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fange.202209746 |
| PQID | 2707586713 |
| PQPubID | 866336 |
| PageCount | 8 |
| ParticipantIDs | proquest_journals_2707586713 crossref_primary_10_1002_ange_202209746 wiley_primary_10_1002_ange_202209746_ANGE202209746 |
| PublicationCentury | 2000 |
| PublicationDate | September 5, 2022 |
| PublicationDateYYYYMMDD | 2022-09-05 |
| PublicationDate_xml | – month: 09 year: 2022 text: September 5, 2022 day: 05 |
| PublicationDecade | 2020 |
| PublicationPlace | Weinheim |
| PublicationPlace_xml | – name: Weinheim |
| PublicationTitle | Angewandte Chemie |
| PublicationYear | 2022 |
| Publisher | Wiley Subscription Services, Inc |
| Publisher_xml | – name: Wiley Subscription Services, Inc |
| References | 2017; 8 2021; 6 2019; 4 2018; 140 1989; 218 2012 2020; 142 2019; 10 2019; 12 2020; 16 2011; 10 2020; 11 1995; 376 2021; 143 2017 2017; 56 129 2019; 141 2019 2019; 58 131 2020; 19 2021; 13 2011; 108 2012; 134 2021; 33 2021; 11 2018 2018; 57 130 1995; 89 2010; 110 2016; 354 2021 2021; 60 133 2018; 30 2016; 116 e_1_2_7_5_1 e_1_2_7_3_2 e_1_2_7_9_1 e_1_2_7_7_2 e_1_2_7_19_2 e_1_2_7_17_2 e_1_2_7_15_1 e_1_2_7_1_1 e_1_2_7_13_2 e_1_2_7_41_2 e_1_2_7_11_2 e_1_2_7_43_2 e_1_2_7_45_1 e_1_2_7_45_2 e_1_2_7_47_2 e_1_2_7_26_2 e_1_2_7_28_1 e_1_2_7_49_2 e_1_2_7_25_3 e_1_2_7_25_2 e_1_2_7_23_2 e_1_2_7_31_2 e_1_2_7_31_3 e_1_2_7_33_1 e_1_2_7_21_2 e_1_2_7_37_2 e_1_2_7_39_1 e_1_2_7_4_2 Greenwood N. N. (e_1_2_7_35_1) 2012 e_1_2_7_2_2 e_1_2_7_8_2 e_1_2_7_6_2 e_1_2_7_18_2 e_1_2_7_16_1 e_1_2_7_14_2 e_1_2_7_40_2 e_1_2_7_40_3 e_1_2_7_42_1 e_1_2_7_12_2 e_1_2_7_44_2 e_1_2_7_10_1 e_1_2_7_46_1 e_1_2_7_48_2 e_1_2_7_27_2 e_1_2_7_27_3 e_1_2_7_29_2 e_1_2_7_29_3 e_1_2_7_30_2 e_1_2_7_24_1 e_1_2_7_22_2 e_1_2_7_32_2 e_1_2_7_34_1 e_1_2_7_20_1 e_1_2_7_36_1 e_1_2_7_38_2 |
| References_xml | – volume: 141 start-page: 19800 year: 2019 end-page: 19806 publication-title: J. Am. Chem. Soc. – volume: 110 start-page: 3767 year: 2010 end-page: 3804 publication-title: Chem. Rev. – volume: 141 start-page: 20118 year: 2019 end-page: 20126 publication-title: J. Am. Chem. Soc. – volume: 58 131 start-page: 7035 7109 year: 2019 2019 end-page: 7039 7113 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 4 start-page: 512 year: 2019 end-page: 518 publication-title: Nat. Energy – volume: 8 start-page: 957 year: 2017 publication-title: Nat. Commun. – volume: 116 start-page: 3594 year: 2016 end-page: 3657 publication-title: Chem. Rev. – volume: 142 start-page: 2404 year: 2020 end-page: 2412 publication-title: J. Am. Chem. Soc. – volume: 60 133 start-page: 3212 3249 year: 2021 2021 end-page: 3221 3258 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 10 start-page: 780 year: 2011 end-page: 786 publication-title: Nat. Mater. – volume: 134 start-page: 9082 year: 2012 end-page: 9085 publication-title: J. Am. Chem. Soc. – volume: 6 start-page: 475 year: 2021 end-page: 486 publication-title: Nat. Energy – volume: 141 start-page: 6254 year: 2019 end-page: 6262 publication-title: J. Am. Chem. Soc. – volume: 19 start-page: 282 year: 2020 end-page: 286 publication-title: Nat. Mater. – year: 2012 – volume: 140 start-page: 11594 year: 2018 end-page: 11598 publication-title: J. Am. Chem. Soc. – volume: 57 130 start-page: 8525 8661 year: 2018 2018 end-page: 8529 8665 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 89 start-page: 263 year: 1995 end-page: 269 publication-title: Appl. Surf. Sci. – volume: 13 start-page: 887 year: 2021 end-page: 894 publication-title: Nat. Chem. – volume: 376 start-page: 238 year: 1995 end-page: 240 publication-title: Nature – volume: 16 year: 2020 publication-title: Small – volume: 10 start-page: 1392 year: 2019 publication-title: Nat. Commun. – volume: 33 year: 2021 publication-title: Adv. Mater. – volume: 30 year: 2018 publication-title: Adv. Mater. – volume: 12 start-page: 727 year: 2019 end-page: 738 publication-title: Energy Environ. Sci. – volume: 141 start-page: 2035 year: 2019 end-page: 2045 publication-title: J. Am. Chem. Soc. – volume: 60 133 start-page: 19262 19411 year: 2021 2021 end-page: 19271 19420 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 11 year: 2021 publication-title: Adv. Energy Mater. – volume: 60 133 start-page: 14005 14124 year: 2021 2021 end-page: 14012 14131 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 10 start-page: 1711 year: 2019 publication-title: Nat. Commun. – volume: 11 start-page: 3049 year: 2020 publication-title: Nat. Commun. – volume: 56 129 start-page: 6937 7041 year: 2017 2017 end-page: 6941 7045 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 218 start-page: 331 year: 1989 end-page: 345 publication-title: Surf. Sci. – volume: 108 start-page: 937 year: 2011 end-page: 943 publication-title: Proc. Natl. Acad. Sci. USA – volume: 19 start-page: 1215 year: 2020 end-page: 1223 publication-title: Nat. Mater. – volume: 143 start-page: 18854 year: 2021 end-page: 18858 publication-title: J. Am. Chem. Soc. – volume: 354 start-page: 1414 year: 2016 end-page: 1419 publication-title: Science – ident: e_1_2_7_47_2 doi: 10.1021/jacs.9b09234 – ident: e_1_2_7_20_1 – ident: e_1_2_7_18_2 doi: 10.1021/jacs.9b11852 – ident: e_1_2_7_45_2 doi: 10.1002/ange.201702473 – volume-title: Chemistry of the Elements year: 2012 ident: e_1_2_7_35_1 contributor: fullname: Greenwood N. N. – ident: e_1_2_7_6_2 doi: 10.1021/acs.chemrev.5b00462 – ident: e_1_2_7_13_2 doi: 10.1038/s41467-019-09666-0 – ident: e_1_2_7_40_2 doi: 10.1002/anie.202012798 – ident: e_1_2_7_22_2 doi: 10.1002/smll.202001384 – ident: e_1_2_7_39_1 – ident: e_1_2_7_43_2 doi: 10.1016/0039-6028(89)90156-8 – ident: e_1_2_7_5_1 – ident: e_1_2_7_10_1 – ident: e_1_2_7_14_2 doi: 10.1038/s41560-019-0402-6 – ident: e_1_2_7_16_1 – ident: e_1_2_7_19_2 doi: 10.1021/jacs.1c09498 – ident: e_1_2_7_25_2 doi: 10.1002/anie.202105186 – ident: e_1_2_7_17_2 doi: 10.1021/jacs.8b07294 – ident: e_1_2_7_34_1 doi: 10.1038/s41560-021-00824-7 – ident: e_1_2_7_24_1 – ident: e_1_2_7_46_1 – ident: e_1_2_7_37_2 doi: 10.1039/C8EE02679C – ident: e_1_2_7_45_1 doi: 10.1002/anie.201702473 – ident: e_1_2_7_29_3 doi: 10.1002/ange.201803262 – ident: e_1_2_7_25_3 doi: 10.1002/ange.202105186 – ident: e_1_2_7_31_3 doi: 10.1002/ange.201902109 – ident: e_1_2_7_30_2 doi: 10.1002/adma.201706216 – ident: e_1_2_7_27_2 doi: 10.1002/anie.202102053 – ident: e_1_2_7_12_2 doi: 10.1021/jacs.9b09352 – ident: e_1_2_7_44_2 doi: 10.1016/0169-4332(95)00032-1 – ident: e_1_2_7_4_2 doi: 10.1002/adma.202008752 – ident: e_1_2_7_26_2 doi: 10.1002/aenm.202101242 – ident: e_1_2_7_28_1 – ident: e_1_2_7_7_2 doi: 10.1021/ja3030565 – ident: e_1_2_7_2_2 doi: 10.1126/science.aaf9050 – ident: e_1_2_7_8_2 doi: 10.1038/s41563-019-0535-9 – ident: e_1_2_7_1_1 – ident: e_1_2_7_29_2 doi: 10.1002/anie.201803262 – ident: e_1_2_7_15_1 doi: 10.1002/adma.202008151 – ident: e_1_2_7_36_1 – ident: e_1_2_7_49_2 doi: 10.1073/pnas.1006652108 – ident: e_1_2_7_48_2 doi: 10.1038/376238a0 – ident: e_1_2_7_27_3 doi: 10.1002/ange.202102053 – ident: e_1_2_7_21_2 doi: 10.1038/s41467-020-16848-8 – ident: e_1_2_7_41_2 doi: 10.1038/s41563-020-0717-5 – ident: e_1_2_7_11_2 doi: 10.1021/jacs.8b13543 – ident: e_1_2_7_23_2 doi: 10.1038/s41467-019-09394-5 – ident: e_1_2_7_9_1 doi: 10.1021/cr9003902 – ident: e_1_2_7_32_2 doi: 10.1038/s41467-017-01100-7 – ident: e_1_2_7_38_2 doi: 10.1021/jacs.8b11129 – ident: e_1_2_7_42_1 – ident: e_1_2_7_40_3 doi: 10.1002/ange.202012798 – ident: e_1_2_7_31_2 doi: 10.1002/anie.201902109 – ident: e_1_2_7_3_2 doi: 10.1038/nmat3087 – ident: e_1_2_7_33_1 doi: 10.1038/s41557-021-00734-x |
| SSID | ssj0006279 |
| Score | 2.2485273 |
| Snippet | Single‐atom catalysts (SACs), as promising alternatives to Pt‐based catalysts, suffer from the limited choice of center metals and low single‐atom loading.... Abstract Single‐atom catalysts (SACs), as promising alternatives to Pt‐based catalysts, suffer from the limited choice of center metals and low single‐atom... |
| SourceID | proquest crossref wiley |
| SourceType | Aggregation Database Publisher |
| SubjectTerms | Catalysts Chemical reduction Chemistry Durability Heavy metals High Single-Atom Loading Intermediates Ligands Metal air batteries Oxygen Oxygen Reduction Reaction Oxygen reduction reactions Pentacoordinated Configuration Single atom catalysts Zinc-Air Battery Zinc-oxygen batteries Zirconium |
| Title | Atomically Dispersed Pentacoordinated‐Zirconium Catalyst with Axial Oxygen Ligand for Oxygen Reduction Reaction |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fange.202209746 https://www.proquest.com/docview/2707586713 |
| Volume | 134 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3NSsNAEF60HvQi_mK1yh4ET6HbdZNujqE_FtFaioXiJWx2NxLQVJsU2puP4DP6JM4mTdqeBA8Jm8AGMjuz880w8y1C14IHLoHLUlpTi9GGslwZOpYtCBWBGypBTO_wY9_pjdj92B6vdfHn_BBlws1YRrZfGwMXQVJfkYaa2nuI7yglAImdbbQD2IYbvaZsUO7FDs3Z9ghjFodIo6BtJLS-OX_TLa2w5jpizVxO9wDtL7Ei9vLFPURbOj5Cu63iiLZj9Omlk6zd_22B25Hh_E60wgNTDi4nEFVGMSBJ9fP1_RJNIe6NZu-4ZdI1iyTFJgGLvTmoH36aL0CN8EP0KmKFAcUWb4aG19WsHIzyBogTNOp2nls9a3mGgiXh30DmCjz4reAsFIq7EkyYaq4brKk4CEdKl2plKwBloVROEPIAPJpucKIYla4CX36KKvEk1mcIKwB3jg5ZaPLIAC2EHVItYbNsOrCoDqmim0KE_kdOleHnpMjUN8L2S2FXUa2QsL80mcSnTUAvhm3vtopoJvU_vuJ7_btO-XT-n0kXaM-Ms5oxu4Yq6XSmLwFkpMFVpkdwbw_pL4jozKk |
| link.rule.ids | 315,786,790,1382,11589,27955,27956,46085,46327,46509,46751 |
| linkProvider | Wiley-Blackwell |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1NT8JAEN0oHvBi_Iwo6h5MPDWUZVvaY4MgKiAxkBgvzXZ3a5poUSgJ3PwJ_kZ_iTMtBTmZeGjSbtImfbuz82Yy85aQS-EErgmXobRmBmdVZbgytA1LmEwEbqiEib3D3Z7dHvK7JyuvJsRemEwfYplwQ8tI92s0cExIV1aqoVh8DwEeYyZwYnuTbHFUg0NxZ95fbsY2y-T2TM4NB0KNXLfRZJX199f90ops_qasqc9p7ZKdBVmkXja7e2RDx_uk2MjPaDsgH14ySvv9X-f0OkLR74lWtI_14HIEYWUUA5VU359fz9EYAt9o-kYbmK-ZTxKKGVjqzWD90YfZHNYR7UQvIlYUaGw-8ojCrjh1cJd1QBySYas5aLSNxSEKhoR_A9AVuPCacHgolONKsGGmHV3ldeUAOFK6TCtLASsLpbKD0AnApemqYyrOpKvAmR-RQjyK9TGhCtidrUMeYiIZuIWwQqYl7JZ1G2bVNkvkKofQf8-0MvxMFZn5CLa_BLtEyjnC_sJmJj6rA31Bub1aibAU9T--4nu9m-by6eQ_L12QYnvQ7fid2979KdnG8bSAzCqTQjKe6jNgHElwnq6pH8WGzyg |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1bS8MwFA46QX0RrzidmgfBp7IuS7P2sezi1DmHOBi-lDYXKWg3tw62N3-Cv9Ff4km7dtuT4EMhDaTQLzk53znkfEHo2rcDx4THEFISg5KKMByumGH5JvEDRwnf1LXDj13W7tP7gTVYqeJP9SHyhJu2jGS_1gY-Eqq8FA3VZ-8hviPEBErMNtEWZUAftLYz7eV7MSOp2p5JqWFDpJHJNpqkvD5-3S0tueYqY01cTmsf7S24InbTyT1AGzI6RDv17Iq2I_TpxsOk3P99jhuh1vyeSIF7-jg4H0JUGUbAJMXP1_drOIa4N5x-4LpO18wnMdYJWOzOYPnhp9kclhHuhG9-JDCw2KznWeu66pmDVloAcYz6reZLvW0s7lAwOPwbYC7Ag1d9mypf2A4HEybSlhVaEzaAw7lDpLAEkDLFBQuUHYBHkxXbFJRwR4AvP0GFaBjJU4QFkDsmFVU6jwzUwrcUkRw2yxqDSWVmEd1kEHqjVCrDS0WRiafB9nKwi6iUIewtTGbikRqwF622Vy0ikqD-x1c8t3vbzN_O_jPoCm33Gi2vc9d9OEe7ujs5PmaVUCEeT-UF8I04uEyW1C-jKM5R |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Atomically+Dispersed+Pentacoordinated%E2%80%90Zirconium+Catalyst+with+Axial+Oxygen+Ligand+for+Oxygen+Reduction+Reaction&rft.jtitle=Angewandte+Chemie&rft.au=Wang%2C+Xia&rft.au=An%2C+Yun&rft.au=Liu%2C+Lifeng&rft.au=Fang%2C+Lingzhe&rft.date=2022-09-05&rft.issn=0044-8249&rft.eissn=1521-3757&rft.volume=134&rft.issue=36&rft.epage=n%2Fa&rft_id=info:doi/10.1002%2Fange.202209746&rft.externalDBID=10.1002%252Fange.202209746&rft.externalDocID=ANGE202209746 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0044-8249&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0044-8249&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0044-8249&client=summon |