Improved electrochemical performance of CuS@ graphitic carbon nitride composite for supercapacitor applications

Researchers have focused on fabricating energy storage equipment to tackle global energy concerns. The energy storage systems including capacitors and batteries have several limitation because of their poor electrochemical performance. The electrode material’s suitability for supercapacitor depends...

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Published in	Journal of materials science. Materials in electronics Vol. 35; no. 20; p. 1415
Main Authors	Ali, Mahmood, Alotaibi, B. M., Alrowaily, Albandari W., Alyousef, Haifa A., Alotiby, Mohammed F., Abdullah, Muhammad, Farid, Hafiz Muhammad Tahir, Al-Sehemi, Abdullah G., Henaish, A. M. A.
Format	Journal Article
Language	English
Published	New York Springer US 01.07.2024 Springer Nature B.V
Subjects	Carbon nitride Characterization and Evaluation of Materials Charge materials Charge transfer Chemistry and Materials Science Copper sulfides Electrochemical analysis Electrode materials Energy storage Materials Science Nyquist plots Optical and Electronic Materials Stability Storage equipment Storage systems Supercapacitors Transition metals
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Abstract	Researchers have focused on fabricating energy storage equipment to tackle global energy concerns. The energy storage systems including capacitors and batteries have several limitation because of their poor electrochemical performance. The electrode material’s suitability for supercapacitor depends on its ability to improve electrochemical performance and stability. In this work, CuS@g-CN (graphitic carbon nitride) composite was developed via a hydrothermal approach. Several analytical techniques were utilized to determine performance of the prepared CuS@g-CN composite. The specific capacitance of CuS@g-CN composite was 996 F/g which displayed stability after 10,000th cycles with a retention of 93% calculated from galvanostatic charge–discharge profiles. A charge transfer resistance of 1.18 Ω of CuS@g-CN composite was found relatively lower than individual materials calculated from the Nyquist plot. The nitrogen-rich structure of g-CN permits rapid ion transportation and the presence of multiple transition metals led to improved electrochemical effectiveness. The enhanced characteristics of CuS@g-CN composite render it suitable for incorporation into future energy storage devices.
AbstractList	Researchers have focused on fabricating energy storage equipment to tackle global energy concerns. The energy storage systems including capacitors and batteries have several limitation because of their poor electrochemical performance. The electrode material’s suitability for supercapacitor depends on its ability to improve electrochemical performance and stability. In this work, CuS@g-CN (graphitic carbon nitride) composite was developed via a hydrothermal approach. Several analytical techniques were utilized to determine performance of the prepared CuS@g-CN composite. The specific capacitance of CuS@g-CN composite was 996 F/g which displayed stability after 10,000th cycles with a retention of 93% calculated from galvanostatic charge–discharge profiles. A charge transfer resistance of 1.18 Ω of CuS@g-CN composite was found relatively lower than individual materials calculated from the Nyquist plot. The nitrogen-rich structure of g-CN permits rapid ion transportation and the presence of multiple transition metals led to improved electrochemical effectiveness. The enhanced characteristics of CuS@g-CN composite render it suitable for incorporation into future energy storage devices. Researchers have focused on fabricating energy storage equipment to tackle global energy concerns. The energy storage systems including capacitors and batteries have several limitation because of their poor electrochemical performance. The electrode material’s suitability for supercapacitor depends on its ability to improve electrochemical performance and stability. In this work, CuS@g-CN (graphitic carbon nitride) composite was developed via a hydrothermal approach. Several analytical techniques were utilized to determine performance of the prepared CuS@g-CN composite. The specific capacitance of CuS@g-CN composite was 996 F/g which displayed stability after 10,000th cycles with a retention of 93% calculated from galvanostatic charge–discharge profiles. A charge transfer resistance of 1.18 Ω of CuS@g-CN composite was found relatively lower than individual materials calculated from the Nyquist plot. The nitrogen-rich structure of g-CN permits rapid ion transportation and the presence of multiple transition metals led to improved electrochemical effectiveness. The enhanced characteristics of CuS@g-CN composite render it suitable for incorporation into future energy storage devices.
ArticleNumber	1415
Author	Farid, Hafiz Muhammad Tahir Al-Sehemi, Abdullah G. Alotiby, Mohammed F. Henaish, A. M. A. Abdullah, Muhammad Ali, Mahmood Alrowaily, Albandari W. Alyousef, Haifa A. Alotaibi, B. M.
Author_xml	– sequence: 1 givenname: Mahmood surname: Ali fullname: Ali, Mahmood organization: Centre of Excellence in Solid State Physics, University of the Punjab – sequence: 2 givenname: B. M. surname: Alotaibi fullname: Alotaibi, B. M. organization: Department of Physics, College of Science, Princess Nourah bint Abdulrahman University – sequence: 3 givenname: Albandari W. surname: Alrowaily fullname: Alrowaily, Albandari W. organization: Department of Physics, College of Science, Princess Nourah bint Abdulrahman University – sequence: 4 givenname: Haifa A. surname: Alyousef fullname: Alyousef, Haifa A. organization: Department of Physics, College of Science, Princess Nourah bint Abdulrahman University – sequence: 5 givenname: Mohammed F. surname: Alotiby fullname: Alotiby, Mohammed F. organization: King Abdulaziz City for Science & Technology (KACST), Nuclear Technologies Institute (NTI) – sequence: 6 givenname: Muhammad surname: Abdullah fullname: Abdullah, Muhammad organization: Department of Chemistry, Government College University Lahore – sequence: 7 givenname: Hafiz Muhammad Tahir orcidid: 0000-0002-4232-7939 surname: Farid fullname: Farid, Hafiz Muhammad Tahir email: tahirfaridbzu@gmail.com organization: Department of Physics, Government Graduate College – sequence: 8 givenname: Abdullah G. surname: Al-Sehemi fullname: Al-Sehemi, Abdullah G. organization: Research Center for Advanced Materials Science (RCAMS), King Khalid University, Department of Chemistry, College of Science, King Khalid University – sequence: 9 givenname: A. M. A. surname: Henaish fullname: Henaish, A. M. A. organization: Physics Department, Faculty of Science, Tanta University, NANOTECH Center, Ural Federal University
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Snippet	Researchers have focused on fabricating energy storage equipment to tackle global energy concerns. The energy storage systems including capacitors and...
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SubjectTerms	Carbon nitride Characterization and Evaluation of Materials Charge materials Charge transfer Chemistry and Materials Science Copper sulfides Electrochemical analysis Electrode materials Energy storage Materials Science Nyquist plots Optical and Electronic Materials Stability Storage equipment Storage systems Supercapacitors Transition metals
Title	Improved electrochemical performance of CuS@ graphitic carbon nitride composite for supercapacitor applications
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