Synthesis, Structure, and Tungsten NMR Characterization of {SbW9O33}9-{Mo2O2S2}2+ Sandwich-Like Polyoxothiometalates

• Published in: European journal of inorganic chemistry Vol. 2013; no. 10-11; pp. 1726 - 1730
• Main Authors: Pilette, Marie-Anne, Floquet, Sébastien, Marrot, Jérôme, Sécheresse, Francis, Cadot, Emmanuel
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 01.04.2013; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Subjects: Antimony; Molybdenum; NMR; Nuclear magnetic resonance; Polyoxometalates; Self-assembly; Sulfur; Tungsten

The reaction of {SbW9O33}9– with {Mo2O2S2}2+ has been studied. The {SbW9O33}{Mo2O2S2} products are labile in solution and very sensitive to experimental conditions. Two new hybrids, {Mo2O2S2}‐containing tungstoantimonate anions, namely [(SbW9O33)2(Mo2O2S2)3]12– and [K(SbW9O33)2(Mo2O2S2)WO(H2O)]11–,...