Innentitelbild: Controlled Reducibility of a Metal-Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption (Angew. Chem. 34/2010)
Die steuerbare Reduzierbarkeit koordinativ ungesättigter Eisenzentren in MIL‐100(Fe), [Fe3O(H2O)2F0.81(OH)0.19{C6H3(CO2)3}2]⋅14.5 H2O, wird von J.‐S. Chang et al. in der Zuschrift auf S. 6085 ff. beschrieben. Durch thermische Aktivierung von MIL‐100(Fe) entstehen koordinativ ungesättigte Zentren mit...
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| Published in | Angewandte Chemie Vol. 122; no. 34; p. 5940 |
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| Main Authors | , , , , , , , , , , , , , , , |
| Format | Journal Article |
| Language | German English |
| Published |
Weinheim
WILEY-VCH Verlag
09.08.2010
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
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| Abstract | Die steuerbare Reduzierbarkeit koordinativ ungesättigter Eisenzentren in MIL‐100(Fe), [Fe3O(H2O)2F0.81(OH)0.19{C6H3(CO2)3}2]⋅14.5 H2O, wird von J.‐S. Chang et al. in der Zuschrift auf S. 6085 ff. beschrieben. Durch thermische Aktivierung von MIL‐100(Fe) entstehen koordinativ ungesättigte Zentren mit gemischtvalentem FeII/FeIII, was zu einer Sorptionsselektivität für ungesättigte Gasmoleküle wie Propylen führt. |
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| AbstractList | Die steuerbare Reduzierbarkeit koordinativ ungesättigter Eisenzentren in MIL‐100(Fe), [Fe3O(H2O)2F0.81(OH)0.19{C6H3(CO2)3}2]⋅14.5 H2O, wird von J.‐S. Chang et al. in der Zuschrift auf S. 6085 ff. beschrieben. Durch thermische Aktivierung von MIL‐100(Fe) entstehen koordinativ ungesättigte Zentren mit gemischtvalentem FeII/FeIII, was zu einer Sorptionsselektivität für ungesättigte Gasmoleküle wie Propylen führt. |
| Author | Llewellyn, Philip L. Férey, Gérard Horcajada, Patricia Chang, Jong-San Grenèche, Jean-Marc Bloch, Emily Yoon, Ji Woong Leclerc, Hervé Rodrigues, Alirio E. Vimont, Alexandre Wuttke, Stefan Bazin, Philippe Seo, You-Kyong Hwang, Young Kyu Daturi, Marco Serre, Christian |
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| Snippet | Die steuerbare Reduzierbarkeit koordinativ ungesättigter Eisenzentren in MIL‐100(Fe), [Fe3O(H2O)2F0.81(OH)0.19{C6H3(CO2)3}2]⋅14.5 H2O, wird von J.‐S. Chang et... |
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| SubjectTerms | Chemistry Eisen Gassorption Metall-organische Gerüste Poröse Materialien Reduzierbarkeit |
| Title | Innentitelbild: Controlled Reducibility of a Metal-Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption (Angew. Chem. 34/2010) |
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