Cathodic dehalogenation with dimerization. Dimerization in the course of reduction of butyl iodide
Electrochemical reduction of butyl iodide in methanol with a sodium methylate supporting electrolyte was studied. The yield of the dimeric product, octane, largely depends on the cathode material, with copper and iron (St.3 steel) being the most active. At a current density of 0.03-0.10 A cm(-2), 0d...
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| Published in | Russian journal of general chemistry Vol. 71; no. 7; pp. 1099 - 1101 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
NEW YORK
MAIK NAUKA/INTERPERIODICA
01.07.2001
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| Subjects | |
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| Abstract | Electrochemical reduction of butyl iodide in methanol with a sodium methylate supporting electrolyte was studied. The yield of the dimeric product, octane, largely depends on the cathode material, with copper and iron (St.3 steel) being the most active. At a current density of 0.03-0.10 A cm(-2), 0degreesC, and 0.005 M CH3ONa, the yield of octane, based on butyl iodide, is as high as 83-84%. |
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| AbstractList | Electrochemical reduction of butyl iodide in methanol with a sodium methylate supporting electrolyte was studied. The yield of the dimeric product, octane, largely depends on the cathode material, with copper and iron (St.3 steel) being the most active. At a current density of 0.03-0.10 A cm(-2), 0degreesC, and 0.005 M CH3ONa, the yield of octane, based on butyl iodide, is as high as 83-84%. |
| Author | Tomilov, AP |
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| DOI | 10.1023/A:1013170124535 |
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| References | BRAND R (WOS:000173333600024.4) 1939; 72 KYRIACOU D (WOS:000173333600024.7) 1994 Brand, K (WOS:000201199200065) 1913; 46 PLUMP R (WOS:000173333600024.8) 1938; 23 Brand, K (WOS:000202012100080) 1910; 16 TOMILOV AP (WOS:000173333600024.10) 1982 ANDRYUSHCHENKO KV (WOS:000173333600024.1) 1962; 28 CHIPRIS D (WOS:000173333600024.5) 1978; 8 TOMILOV AP (WOS:000173333600024.9) 1999; 72 VATSURO KV (WOS:000173333600024.11) 1976 FEOKTISTOV LG (WOS:000173333600024.6) 1965; 1 |
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| Snippet | Electrochemical reduction of butyl iodide in methanol with a sodium methylate supporting electrolyte was studied. The yield of the dimeric product, octane,... |
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| Title | Cathodic dehalogenation with dimerization. Dimerization in the course of reduction of butyl iodide |
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