Photoelectron Spectroscopy of Mass‐Selected Copper‐Water Cluster Negative Ions
Negative‐ion photoelectron spectroscopy has been applied in order to obtain size dependent information about the electronic structure of clusters of metal atoms solvated with polar molecules. In the present paper we have investigated the photoelectron spectra of Cu 2 - , cluster ions with 2 = 0–4 an...
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| Published in | Laser chemistry Vol. 15; no. 2-4; pp. 195 - 207 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
01.01.1995
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| Online Access | Get full text |
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| Abstract | Negative‐ion photoelectron spectroscopy has been applied in order to obtain size dependent information about the electronic structure of clusters of metal atoms solvated with polar molecules. In the present paper we have investigated the photoelectron spectra of Cu 2 - , cluster ions with 2 = 0–4 and also those of Cu 2 - , with n = 0 and 1. In the spectra of Cu 2 - , the lowest energy bands were assigned to the electron detachment from the CuOH - , which were produced in the source together with the above cluster ions. The observed bands for Cu 2 - were all assigned to the transitions to the states originating in the ground 2 S and first excited 2 D states of the Cu atom. The stepwise hydration for Cu - and Cu 2 - was discussed from the observed spectral shifts. |
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| AbstractList | Negative‐ion photoelectron spectroscopy has been applied in order to obtain size dependent information about the electronic structure of clusters of metal atoms solvated with polar molecules. In the present paper we have investigated the photoelectron spectra of Cu 2 - , cluster ions with 2 = 0–4 and also those of Cu 2 - , with n = 0 and 1. In the spectra of Cu 2 - , the lowest energy bands were assigned to the electron detachment from the CuOH - , which were produced in the source together with the above cluster ions. The observed bands for Cu 2 - were all assigned to the transitions to the states originating in the ground 2 S and first excited 2 D states of the Cu atom. The stepwise hydration for Cu - and Cu 2 - was discussed from the observed spectral shifts. |
| Author | Tsukamato, Keizo Sanekata, Masaomi Fuke, Kiyokazu Misaizu, Fuminori |
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| CitedBy_id | crossref_primary_10_1016_S0009_2614_98_00538_7 crossref_primary_10_1021_jp901231q crossref_primary_10_1021_jp9832948 crossref_primary_10_1063_1_1782191 crossref_primary_10_1016_j_cplett_2004_11_117 crossref_primary_10_1021_jp202497x crossref_primary_10_1002_qua_22498 crossref_primary_10_1063_1_4813631 crossref_primary_10_1063_1_1836759 crossref_primary_10_1021_jp803086v crossref_primary_10_1063_1_1516796 crossref_primary_10_1063_1_1305819 crossref_primary_10_1016_S0368_2048_99_00071_7 crossref_primary_10_1021_ja0117579 crossref_primary_10_1016_j_ccr_2019_213052 crossref_primary_10_1063_1_3515425 crossref_primary_10_3389_fchem_2021_637750 crossref_primary_10_1021_jp9629654 crossref_primary_10_1063_1_1782176 crossref_primary_10_1016_0009_2614_96_00619_7 crossref_primary_10_1021_jp212287j |
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