Helically chiral Pd() complexes containing intramolecular Pd Pd metallophilicity as circularly polarized molecular phosphors
Carbon-centred chirality of the pincer-type cyclometalated ligands is transferred to the helical chirality of dinuclear and tetranuclear Pd( ii ) arylacetylide complexes, and hence phosphorescence with quantum yields up to 50% and dissymmetry factors in the 10 −3 scale from the metal-metal-to-ligand...
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Published in | Chemical communications (Cambridge, England) Vol. 57; no. 13; pp. 1627 - 163 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Cambridge
Royal Society of Chemistry
17.02.2021
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Subjects | |
Online Access | Get full text |
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